High efficiency electrolytes for high voltage battery systems
Disclosed herein are embodiments of an electrolyte that is stable and efficient at high voltages. The electrolyte can be used in combination with certain cathodes that exhibit poor activity at such high voltages with other types of electrolytes and can further be used in combination with a variety of anodes. In some embodiments, the electrolyte can be used in battery systems comprising a lithium cobalt oxide cathode and lithium metal anodes, silicon anodes, silicon/graphite composite anodes, graphite anodes, and the like.
1. A battery, comprising:
an electrolyte, comprising LiFSI, DME, and TTE, wherein the molar ratio of the LiFSI to the DME ranges from 1:0.5 to 1:1.2 and wherein the LiFSI has a concentration in the electrolyte ranging from 0.2 M to 2 M; and
a lithium metal anode, a silicon anode, a silicon/graphite composite anode, or a graphite anode;
wherein the battery is capable of operating at a voltage of 4.5 V or higher to produce a coulombic efficiency of 99% or higher.
2. An electrolyte consisting essentially of LiFSI, DME, and TTE, wherein the molar ratio of the LiFSI to the DME is 1:1.2 or 1:1.
3. The electrolyte of claim 2 , wherein the molar ratio of the LiFSI to the TTE ranges from 1:0.1 to 1:10.
4. An electrolyte, comprising LiFSI, DME, and TTE, wherein the molar ratio of the LiFSI to the DME ranges from 1:0.5 to 1:1.2 and wherein the LiFSI has a concentration in the electrolyte ranging from 0.2 M to 2 M.
5. The electrolyte of claim 4 , wherein the molar ratio of the LiFSI to the TTE ranges from 1:0.1 to 1:10.
6. A battery, comprising:
a cathode comprising a lithium cobalt oxide (LCO) material, a nickel manganese cobalt (NMC) material, or a nickel cobalt transition metal oxide (NC-TM) material;
an anode; and
the electrolyte of claim 2 .
7. The battery of claim 6 , wherein the cathode comprises the LCO material and the anode is a lithium metal anode, a silicon anode, a graphite anode, or a graphite/silicon composite anode.
8. The battery of claim 6 , wherein the cathode comprises the NMC material and the anode is a lithium metal anode, a silicon anode, a graphite anode, or a graphite/silicon composite anode.
9. The battery of claim 6 , wherein the battery exhibits a CE of 99.8% or more when operated at a voltage of 4.5 V or higher.
10. A battery, comprising:
a cathode comprising a lithium cobalt oxide (LCO) material, a nickel manganese cobalt (NMC) material, or a nickel cobalt transition metal oxide (NC-TM) material;
an anode; and
the electrolyte of claim 4 .
11. The battery of claim 10 , wherein the cathode comprises the LCO material and the anode is a lithium metal anode, a silicon anode, a graphite anode, or a graphite/silicon composite anode.
12. The battery of claim 10 , wherein the cathode comprises the NMC material and the anode is a lithium metal anode, a silicon anode, a graphite anode, or a graphite/silicon composite anode.
13. The battery of claim 10 , wherein the battery exhibits a CE of 99.8% or more when operated at a voltage of 4.5 V or higher.
14. A method, comprising:
providing a battery system comprising the battery of claim 1 ; and
applying a voltage of 4.5 V or higher to the battery.
15. A method, comprising:
providing a battery system comprising the battery of claim 6 ; and
applying a voltage of 4.5 V or higher to the battery.
16. A method, comprising:
providing a battery system comprising the battery of claim 10 ; and
applying a voltage of 4.5 V or higher to the battery.
17. The electrolyte of claim 4 , wherein the molar ratio of the LiFSI to the DME is 1:1 to 1:1.2.