Antioxidant for electrolyte membrane of fuel cells and method for preparing the same
Disclosed is an antioxidant for an electrolyte membrane of fuel cells. The antioxidant may include a support including silicon dioxide and having a nanotube shape, and a metal oxide supported on the support.
1. An antioxidant for an electrolyte membrane of fuel cells comprising:
a support comprising silicon dioxide and formed in a nanotube shape; and
a metal oxide comprising a metal component and supported on the support,
wherein the support has a length of about 20 nm to 300 nm,
a silicon compound comprising one or more amine group is disposed on the support, and
the metal oxide is supported on the support by a coordinate bond between a metal ion of the metal oxide and amine groups of the silicon compound.
2. The antioxidant of claim 1 , wherein the silicon compound comprises 3-aminopropyl triethoxysilane.
3. The antioxidant of claim 1 , wherein the metal oxide is supported on the support by forming by disposing one or more chelate compounds on the surface of the support, wherein the chelate compound is formed by a coordinate bond between a metal ion of the metal oxide and the silicon compound having two or more amine groups.
4. The antioxidant of claim 3 , wherein the silicon compound comprises one or more selected from the group consisting of N-[3-(trimethoxysilyl)propyl]ethylene diamine, and N-{3-[dimethoxy(methyl)silyl]propyl}-1,2-ethanediamine.
5. The antioxidant of claim 1 , wherein the metal oxide comprises one or more selected from pure cerium oxide (CeO 2 ) and modified cerium oxide.
6. The antioxidant of claim 5 , wherein the modified cerium oxide comprises one or more selected from cerium-zirconium oxide (Ce 1-x Zr x O 2 , in which x is 0.2 to 0.8), cerium-manganese oxide (Ce 1-x Mn x O 2 , in which x is 0.2 to 0.8), cerium oxide-doped yttrium oxide, and cerium oxide-doped zirconium oxide.
7. The antioxidant of claim 1 , wherein the antioxidant comprises the metal oxide in an amount of about 0.1% by weight to 30% by weight, based on the total weight of the antioxidant.
8. An electrolyte membrane for fuel cells comprising:
an antioxidant for an electrolyte membrane of fuel cells of claim 1 ; and
an ionomer.
9. The electrolyte membrane of claim 8 , wherein a content of the metal oxide present is an amount of about 0.01% by weight to 5% by weight, based on the total weight of the ionomer.
10. A fuel cell comprising an antioxidant of claim 1 .
11. A vehicle comprising a fuel cell of claim 10 .