Structures having selectively metallized regions and methods of manufacturing the same
Methods of manufacturing a structure having at least one plated region and at least one unplated region. The method includes plating a metal on a polymer structure having a first region accepting the metal and a second region unreceptive to the metal plating. The first region may include fully-cured polymer optical waveguides and the second region may include partially-cured polymer optical waveguides. The first region may include a first polymer composition and the second region may include a second polymer composition different than the first polymer composition.
1. A method of manufacturing a structure having at least one plated region and at least one unplated region, the method comprising:
forming a first region of a polymer structure from a first photo-monomer composition;
forming a second region of the polymer structure from a second photo-monomer composition different than the first photo-monomer composition; and
plating a metal on the polymer structure, the first region accepting the metal and the second region being unreceptive to the metal,
wherein the plating of the polymer structure comprises a process selected from the group of processes consisting of a catalyst poisoning method, an inhibition of metal reaction method, an over-etched polymer surface method, an increased etch rate-post process method, an uncured surface inhibition of plating method, an etch resistant polymer-prevention of catalyst deposition method, and combinations thereof.
2. The method of claim 1 , further comprising immersing the polymer structure in a catalyst inhibitor, the catalyst inhibitor depositing onto the second region of the polymer structure and the first region of the polymer structure repelling the catalyst inhibitor.
3. The method of claim 1 , further comprising immersing the polymer structure in a reaction inhibitor, the reaction inhibitor depositing onto the second region of the polymer structure and the first region of the polymer structure repelling the reaction inhibitor.
4. A method of manufacturing a structure having at least one plated region and at least one unplated region, the method comprising:
forming a first region of a polymer structure from a first photo-monomer composition;
forming a second region of the polymer structure from a second photo-monomer composition different than the first photo-monomer composition; and
plating a metal on the polymer structure, the first region accepting the metal and the second region being unreceptive to the metal,
wherein the plating of the polymer structure comprises immersing the polymer structure in a catalyst and/or reaction inhibitor, the catalyst and/or reaction inhibitor depositing onto the second region of the polymer structure and the first region of the polymer structure repelling the catalyst and/or reaction inhibitor.
5. The method of claim 1 , wherein the polymer structure comprises an ordered three-dimensional microstructure.