Liquid crystal composition, liquid crystal display element and liquid crystal display
Disclosed are a liquid crystal composition, a liquid crystal display element, and a liquid crystal display, said liquid crystal composition comprising one or more compounds represented by formula I, one or more compounds represented by formula II, one or more compounds represented by formula III and one or more compounds represented by formula IV, The liquid crystal composition of the present invention has a good stability to light and heat and a lower viscosity, and can attain a wider refractive index and a high clearing point (a wide service temperature range), and in particular, the liquid crystal composition has a high light transmittance, thus allowing a display device to have a high brightness or an energy saving effect.
1. A liquid crystal composition, wherein said liquid crystal composition comprises one or more compounds represented by formula I, one or more compounds represented by formula II, one or more compounds represented by formula III and one or more compounds represented by formula IV2 and IV11,
wherein
R 1 , R 2 , R 3 , R 5 , and R 6 each independently represent an alkyl group having a carbon atom number of 1-10, an alkoxy group having a carbon atom number of 1-10, an alkenyl group having a carbon atom number of 2-10, or an alkenoxy group having a carbon atom number of 3-8, and any one or more non-connected CH 2 in the groups represented by R 1 and R 3 are substituted with cyclopentyl, cyclobutyl, cyclopropyl or —O—;
R 4 represents F, CF 3 , OCF 3 , OCHF 2 or OCH 2 F;
each independently represent
or any fluorobenzene;
each independently represent benzene or any fluorobenzene;
represents
or any fluorobenzene;
m, p and w each independently represent 1, 2 or 3;
n and q each independently represent 0 or 1; and
R 71 represents an alkyl group having a carbon atom number of 1-6 or an alkenyl group having a carbon atom number of 2-6.
2. The liquid crystal composition according to claim 1 , wherein said one or more compounds represented by formula I are selected from the groups consisting of compounds represented by formulas I1 to I14; said one or more compounds represented by formula II are selected from the group consisting of compounds represented by formulas II1 to II14; said one or more compounds represented by formula III are selected from the group consisting of compounds of formulas III1 to III5;
wherein R 11 and R 31 each independently represent an alkyl group having a carbon atom number of 1-6;
(O)R 21 represents an alkyl or alkoxyl having a carbon atom number of 1-5;
R 51 and R 61 each independently represent an alkyl group having a carbon atom number of 1-6, an alkoxy group having a carbon atom number of 1-6, an alkenyl group having a carbon atom number of 2-6 or an alkenyloxy group having a carbon atom number of 3-6.
3. The liquid crystal composition according to claim 1 , wherein in said liquid crystal composition, the total content in mass percentage of said one or more compounds represented by formula I is 1-40%, the total content in mass percentage of said one or more compounds represented by formula II is 1-40%, the total content in mass percentage of said one or more compounds represented by formula III is 1-80%, and the total content in mass percentage of said one or more compounds represented by formula IV is 0.5-30%.
4. The liquid crystal composition according to claim 1 , wherein said liquid crystal composition further comprises one or more compounds represented by formula V,
wherein R 9 represents an alkyl group having a carbon atom number of 1-10, a fluoro-substituted alkyl group having a carbon atom number of 1-10, an alkoxy group having a carbon atom number of 1-10, a fluoro-substituted alkoxy group having a carbon atom number of 1-10, an alkenyl group having a carbon atom number of 2-10, a fluoro-substituted alkenyl group having a carbon atom number of 2-10, an alkenoxy group having a carbon atom number of 3-8 or an fluoro-substituted alkenoxy group having a carbon atom number of 3-8, and any one or more CH 2 in the group represented by R 9 are optionally substituted with cyclopentyl, cyclobutyl or cyclopropyl;
each independently represent
r represents 0, 1, 2 or 3;
Z 1 and Z 2 each independently represent a single bond, —CF 2 O—, —CH 2 CH 2 —or —CH 2 O—; and
Y 2 represents F, a fluoro-substituted alkyl group having a carbon atom number of 1-5, a fluoro-substituted alkoxy group having a carbon atom number of 1-5, a fluoro-substituted alkenyl group having a carbon atom number of 2-5, or a fluoro-substituted alkenoxy group having a carbon atom number of 3-8.
5. The liquid crystal composition according to claim 4 , wherein said one or more compounds represented by formula V are selected from the groups consisting of compounds represented by formulas V0 to V25,
wherein R 9 represents an alkyl group having a carbon atom number of 1-10, a fluoro-substituted alkyl group having a carbon atom number of 1-10, an alkoxy group having a carbon atom number of 1-10, a fluoro-substituted alkoxy group having a carbon atom number of 1-10, an alkenyl group having a carbon atom number of 2-10, a fluoro-substituted alkenyl group having a carbon atom number of 2-10, an alkenoxy group having a carbon atom number of 3-8 or a fluoro-substituted alkenoxy group having a carbon atom number of 3-8, and any one or more CH 2 in the group represented R 9 are substituted with cyclopentyl, cyclobutyl or cyclopropyl;
(F) each independently represents H or F; and
in formula V23, X 1 and X 2 each independently represent H or F, Y 2 represents F, a fluoro-substituted alkyl group having a carbon atom number of 1-5, a fluoro-substituted alkoxy group having a carbon atom number of 1-5, a fluoro-substituted alkenyl group having a carbon atom number of 2-5 or a fluoro-substituted alkenoxy group having a carbon atom number of 3-8.
6. The liquid crystal composition according to claim 1 , wherein said liquid crystal composition further comprises one or more compounds represented by formula VI,
wherein R 10 and R 12 each independently represent an alkyl group having a carbon atom number of 1-10, fluoro, a fluoro-substituted alkyl group having a carbon atom number of 1-10, an alkoxy group having a carbon atom number of 1-10, a fluoro-substituted alkoxy group having a carbon atom number of 1-10, an alkenyl group having a carbon atom number of 2-10, a fluoro-substituted alkenyl group having a carbon atom number of 2-10, an alkenoxy group having a carbon atom number of 3-8 or a fluoro-substituted alkenoxy group having a carbon atom number of 3-8, and any one or more CH 2 in the groups represented by R 10 and R 12 are optionally substituted with cyclopentyl, cyclobutyl or cyclopropyl;
Z 3 and Z 4 each independently represent a single bond, —CH 2 CH 2 — or —CH 2 O—;
each independently represent
a represents 1, 2 or 3;
b represents 0 or 1.
7. The liquid crystal composition according to claim 6 , wherein said one or more compounds represented by formula VI are selected from the groups consisting of compounds represented by formulas VI1 to VI12,
wherein R 10 and R 12 each independently represent an alkyl group having a carbon atom number of 1-10, fluoro, a fluoro-substituted alkyl group having a carbon atom number of 1-10, an alkoxy group having a carbon atom number of 1-10, a fluoro-substituted alkoxy group having a carbon atom number of 1-10, an alkenyl group having a carbon atom number of 2-10, a fluoro-substituted alkenyl group having a carbon atom number of 2-10, an alkenoxy group having a carbon atom number of 3-8 or a fluoro-substituted alkenoxy group having a carbon atom number of 3-8, and any one or more CH 2 in the groups represented by R 10 and R 12 are optionally substituted with cyclopentyl, cyclobutyl or cyclopropyl.
8. The liquid crystal composition according to claim 1 , wherein said liquid crystal composition further comprises one or more compounds represented by formula VII,
wherein R 13 and R 14 each independently represent an alkyl group having a carbon atom number of 1-10, a fluoro-substituted alkyl group having a carbon atom number of 1-10, an alkoxy group having a carbon atom number of 1-10, a fluoro-substituted alkoxy group having a carbon atom number of 1-10, an alkenyl group having a carbon atom number of 2-10, a fluoro-substituted alkenyl group having a carbon atom number of 2-10, an alkenoxy group having a carbon atom number of 3-8 or a fluoro-substituted alkenoxy group having a carbon atom number of 3-8, and any one or more CH 2 in the groups represented by R 13 and R 14 are optionally substituted with cyclopentyl, cyclobutyl or cyclopropyl; and
W represents —O—, —S— or —CH 2 O—.
9. The liquid crystal composition according to claim 1 , further comprising one or more compounds represented by formula VIII,
wherein R 14 represents an alkyl group having a carbon atom number of 1-5 or an alkenyl group having a carbon atom number of 2-5;
R 15 represents an F atom, an alkyl group having a carbon atom number of 1-5, an alkoxy group having a carbon atom number of 1-5 or an alkenyl group having a carbon atom number of 2-5, and any one or more CH 2 in the groups represented by R 15 and R 16 are optionally substituted with cyclopentyl, cyclobutyl or cyclopropyl;
s represents 0 or 1; and
(F) represents H or F.
10. A liquid crystal display element or liquid crystal display comprising the liquid crystal composition of claim 1 , wherein said liquid crystal display element or liquid crystal display is an active matrix display element or display or a passive matrix display element or display.