Lubricant containing thiadiazole derivatives
The present disclosure describes a lubricating composition including a) a major part of a base oil of lubricating viscosity wherein the base oil is selected from API Group I, II, III, IV, V, or mixtures thereof, b) a total of 0.001 to 0.536 wt. %, based on the total lubricating composition, of one or more monohydrocarbyl-substituted dimercaptothiadiazole derivative(s) according to Formula (I), or a tautomer or salt thereof, below wherein R is methyl or C 2 to C 4 alkyl, wherein the total lubricating composition has a sulfur content of up to 2,500 ppm (wt.), c) less than 0.1 wt % phosphite. The disclosure further describes the use of the lubricating composition for lubricating a driveline, a transmission including a manual or automated transmission, a gear, an automated gear, or an axle, and for enhanced FZG test performance. The disclosure further relates to a method for preparing the lubricating composition.
1. A lubricating composition comprising
a) a major part of a base oil of lubricating viscosity wherein the base oil is selected from the group consisting of API Group I, II, III, IV, V, and mixtures thereof,
b) a total of 0.08 to 0.15 wt. %, based on the total lubricating composition, of one or more monohydrocarbyl-substituted dimercaptothiadiazole derivative(s) according to Formula (I), or a tautomer thereof, below
wherein R is methyl,
wherein the total lubricating composition has a sulfur content of 480 to 940 ppm (wt.), and
c) wherein the lubricating composition is free of phosphite.
2. The lubricating composition according to claim 1 , wherein the one or more monohydrocarbyl-substituted dimercaptothiadiazole derivative(s) comprise 5-(methylthio)-3,4-thiadiazole-2(3H)-thione.
3. The lubricating composition according to claim 1 , wherein the lubricating composition further contains a dispersant.
4. The lubricating composition according to claim 3 wherein the dispersant is present in an amount of 0.001 to 10 wt. %, based on the total lubricating composition, in the lubricating composition.
5. The lubricating composition according to claim 3 wherein the dispersant is selected from the group consisting of ashless dispersants, borated ashless dispersants, ash-containing dispersants, and dispersant viscosity index improvers, and combinations thereof.
6. The lubricating composition according to claim 1 , further comprising one or more additives selected from the group consisting of extreme-pressure agents, anti-wear agents, friction modifiers, metal deactivators, detergents, viscosity index improvers, antioxidants, corrosion inhibitors, foam inhibitors, demulsifiers, pour point depressants, seal swelling agents, and mixtures thereof.
7. The lubricating composition according to claim 1 comprising 0.08 to 0.15 wt. % of the one or more monohydrocarbyl-substituted dimercaptothiadiazoles and 0.05 to 0.20 wt. % of at least one of:
monohydrocarbylthio-substituted dimercaptothiadiazoles of Formula IIa and
bishydrocarbylthio-substituted dimercaptothiadiazoles of Formula II
wherein each R is independently C 5 -C 15 alkyl.
8. A method for lubricating a driveline, a transmission including a manual or automated transmission, a gear, an automated gear, or an axle, the method comprising lubricating the driveline, the transmission, the gear, the automated gear, or the axle with a lubricating composition, the lubricating composition comprising:
a) a major part of a base oil of lubricating viscosity wherein the base oil is selected from the group consisting of API Group I, II, III, IV, V, and mixtures thereof,
b) a total of 0.08 to 0.15 wt. %, based on the total lubricating composition, of one or more monohydrocarbyl-substituted dimercaptothiadiazole derivative(s) according to Formula (I), or a tautomer thereof, below
wherein R is methyl,
wherein the total lubricating composition has a sulfur content of 480 to 940 ppm (wt.), and
c) wherein the lubricating composition is free of phosphite.
9. The method according to claim 8 , wherein the lubricating composition is for enhanced FZG test performance.
10. The method according to claim 8 , wherein the lubricating composition is to enhance the gear scuffing resistance of the lubricating composition.
11. The method according to claim 9 , wherein the enhanced FZG test performance comprises an enhanced Failure Load Stage (FLS) score.
12. A method of preparing a lubricating composition comprising blending a base oil of lubricating viscosity with one or more monohydrocarbyl-substituted dimercaptothiadiazole derivative(s) according to Formula (I) or a tautomer thereof
wherein R is methyl;
wherein the base oil is selected from the group consisting of API Group I, II, III, IV, V, and mixtures thereof;
wherein the lubricating composition has a sulfur content of 480 to 940 ppm (wt.) and is free of phosphite; and
wherein the lubricating composition comprises from 0.08 to 0.15 wt % of the monohydrocarbyl-substituted dimercaptothiadiazole derivative(s).
13. The lubricating composition according to claim 3 wherein the dispersant is an ashless dispersant selected from the group consisting of succinimide dispersants, polyisobutylene dispersants, and ethylene-propylene copolymers, and mixtures thereof.