IP Library Granted Patent US 10,636,696
Granted Patent B1
US 10,636,696 · App. 16/251,355 · Granted Apr 28, 2020

Methods for forming vias in polymer layers

Inventors: Yu Gu (Singapore, SG); Guan Huei See (Singapore, SG); Peng Suo (Singapore, SG); Prayudi Lianto (Singapore, SG); Arvind Sundarrajan (Singapore, SG)
Assignee: APPLIED MATERIALS, INC.
H01L21/76804H01L21/31138H01L23/5226
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Quick Facts
Patent No.
US 10,636,696
App. No.
16/251,355
Granted
Apr 28, 2020
Kind
B1
Abstract

A method of processing a substrate includes depositing a layer of uncured polymer material atop a substrate to cover an exposed conductive layer on the substrate, exposing at least one area of the layer using a photolithography process, developing the layer in the photolithography process to remove a first portion of uncured polymer material from the at least one area, etching the layer with a dry etch process to remove a second portion of uncured polymer material from the at least one area to expose a top surface of the conductive layer and form a via in the layer, and curing the layer to form a cured polymer material.

Claims (50)

1. A method for forming a via in a substrate, comprising:

depositing a layer of uncured polymer material atop a substrate to cover a conductive layer which is exposed on the substrate;

exposing at least one area of the layer of uncured polymer material using a photolithography process;

developing the layer of uncured polymer material in the photolithography process to remove a first portion of uncured polymer material from the at least one area;

etching the layer of uncured polymer material with a dry etch process to remove a second portion of uncured polymer material from the at least one area to expose a top surface of the conductive layer and form a via in the layer of uncured polymer material; and

curing the layer of uncured polymer material to form a cured polymer material layer.

2. The method of claim 1 , further comprising:

using a plasma based dry etch process to etch the layer of uncured polymer material.

3. The method of claim 2 , further comprising:

etching the layer of uncured polymer material with an oxygen based gas.

4. The method of claim 2 , further comprising:

etching the layer of uncured polymer material with a carbon tetrafluoride based gas.

5. The method of claim 2 , further comprising:

adjusting a bias power to enhance a perpendicular etching aspect of the plasma based dry etch process relative to a top surface of the substrate.

6. The method of claim 2 , further comprising:

adjusting a gas flow to enhance a perpendicular etching aspect of the plasma based dry etch process relative to a top surface of the substrate.

7. The method of claim 2 , further comprising:

blanket etching the substrate with the plasma based dry etching process such that the second portion of uncured polymer material is etched at a higher etch rate than an upper surface of the substrate.

8. The method of claim 1 , further comprising:

forming the via in the layer of uncured polymer material with a size of less than approximately 10 microns.

9. The method of claim 8 , further comprising:

forming the via in the layer of uncured polymer material with a size of less than approximately five microns.

10. The method claim 1 , further comprising:

using an optical mask to expose the at least one area of the layer of uncured polymer material on the substrate in the photolithography process.

11. The method of claim 1 , further comprising:

forming the via with a sidewall profile angle of approximately 80 degrees to approximately 90 degrees.

12. The method of claim 1 , wherein the conductive layer is a copper-based material, an aluminum-based material, a gold-based material, a silver-based material.

13. A method for forming a via in a substrate, comprising:

spin coating a layer of uncured polymer material atop a substrate to cover at least one conductive layer that is exposed on the substrate;

exposing at least one area of the layer of uncured polymer material above the at least one conductive layer with an ultraviolet light;

removing a first portion of uncured polymer material from the at least one area exposed by the ultraviolet light with a solvent wash;

etching the layer of uncured polymer material with an anisotropic dry etch process to remove a second portion of uncured polymer material from the at least one area to expose a top surface of the conductive layer and form a via of less than or equal to approximately 10 microns in the layer of uncured polymer material; and

curing the layer of uncured polymer material to form a cured polymer material layer.

14. The method of claim 13 , further comprising:

using a plasma based dry etch process to etch the layer of uncured polymer material.

15. The method of claim 14 , further comprising:

etching the layer of uncured polymer material with an oxygen based gas or a carbon tetrafluoride based gas.

16. The method of claim 14 , further comprising:

adjusting a bias power to enhance a perpendicular etching aspect of the plasma based dry etch process relative to a top surface of the substrate.

17. The method of claim 14 , further comprising:

adjusting a gas flow to enhance a perpendicular etching aspect of the plasma based dry etch process relative to a top surface of the substrate.

18. The method of claim 13 , further comprising:

curing the layer of uncured polymer material at a temperature of approximately 180° C. to approximately 350° C. to form the cured polymer material layer.

19. A non-transitory computer readable medium having instructions stored thereon that, when executed, cause a method of operating a wafer level processing system to be performed, the method comprising:

spin coating a layer of uncured polymer material atop a substrate to cover at least one conductive layer that is exposed on the substrate;

exposing at least one area of the layer of uncured polymer material above the at least one conductive layer with an ultraviolet light;

removing a first portion of uncured polymer material from the at least one area exposed by the ultraviolet light with a solvent wash;

etching the layer of uncured polymer material with an anisotropic dry etch process to remove a second portion of uncured polymer material from the at least one area to expose a top surface of the conductive layer and form a via of less than or equal to approximately 10 microns in the layer of uncured polymer material; and

curing the layer of uncured polymer material to form a cured polymer material layer.

20. The non-transitory computer readable medium of claim 19 , wherein the via has a width or diameter of less than or equal to approximately five microns.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 5, 2019
From: APPLIED MATERIALS SINGAPORE TECHNOLOGY PTE. LTD.
To: APPLIED MATERIALS, INC.
Reel/Frame 050917/0604 →
CORRECTIVE ASSIGNMENT TO CORRECT THE EXECUTION DATE FOR INVENTOR PRAYUDI LIANTO PREVIOUSLY RECORDED ON REEL 048308 FRAME 0099. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Feb 28, 2019
From: GU, YU; SEE, GUAN HUEI; SUO, PENG; LIANTO, PRAYUDI; SUNDARRAJAN, ARVIND
To: APPLIED MATERIALS SINGAPORE TECHNOLOGY PTE. LTD.
Reel/Frame 048485/0583 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 12, 2019
From: GU, YU; SEE, GUAN HUEI; SUO, PENG; LIANTO, PRAYUDI; SUNDARRAJAN, ARVIND
To: APPLIED MATERIALS SINGAPORE TECHNOLOGY PTE. LTD.
Reel/Frame 048308/0099 →