Systems and methods for ammonia recovery, acid gas separation, or combination thereof
View Patent ↗The present invention relates to processes and systems for ammonia recovery and/or acid-gas separation. In some embodiments, a system for acid gas separation may be integrated with an ammonia abatement cycle employing a high temperature absorber. In some embodiments, a system for acid gas separation may employ a higher temperature absorber due to the lower energy consumption and cost of the integrated ammonia abatement cycle. Advantageously, heat may be recovered from the absorber to power at least a portion of any acid gas desorption in the process. Reverse osmosis or other membranes may be employed.
1. A process for separating or recovering basic gases comprising:
(a) absorbing ammonia from an ammonia containing gas stream into an ammonia-lean, an ammonia-ultra-lean, or ammonia-free solution, to form an ammonia-rich solution;
(b) enriching said ammonia-rich solution with one or more acid gases to form an ammonia rich, acid gas rich solution; and
(c) concentrating said ammonia rich, acid gas rich solution using one or more membranes to form a retentate and a permeate wherein said permeate is suitable for use as at least a portion of the ammonia-ultra-lean or ammonia-free solution in step (a);
wherein one or more solutions comprise urea.
2. The process of claim 1 further comprising transferring said retentate to one or more further treatment steps.
3. The process of claim 1 wherein said ammonia containing gas stream comprises one or more other basic gases.
4. The process of claim 1 wherein the ammonia containing gas stream further comprises an acid gas.
5. The process of claim 1 further comprising absorbing an acid gas with the ammonia to form an acid gas rich, ammonia-rich solution.
6. The process of claim 5 wherein an acid gas is desorbed from said acid gas rich, ammonia-rich solution to form an acid gas lean, ammonia-rich solution and desorbed acid gas.
7. An integrated process for separating or recovering basic gases comprising:
(1) a first cycle comprising:
absorbing ammonia from an ammonia containing gas stream into an ammonia-lean solution, forming an ammonia-rich solution;
enriching said ammonia rich solution with one or more acid gases;
precipitating one or more ammonia-acid gas salts wherein said precipitating occurs during enriching, after enriching, or a combination thereof; and
separating at least a portion of said precipitate from any remaining liquid; and
(2) a second cycle comprising:
(a) absorbing ammonia from an ammonia containing gas stream into an ammonia-lean, an ammonia-ultra-lean, or ammonia-free solution, to form an ammonia-rich solution;
(b) enriching said ammonia-rich solution with one or more acid gases to form an ammonia-rich, acid gas rich solution; and
(c) concentrating said ammonia-rich, acid gas rich solution using one or more membranes to form a retentate and a permeate wherein said permeate is suitable for use as at least a portion of the ammonia-ultra-lean or ammonia-free solution in step (a) of the second cycle.
8. The process of claim 7 wherein the volume of permeate is greater than the volume of retentate.
9. The process of claim 7 wherein the volume ratio of permeate to retentate is greater than about 3:1.
10. The process of claim 7 which further comprises combining at least a portion of the remaining liquid in the first cycle with at least a portion of the retentate in the second cycle and concentrating the combination using one or more membranes to form a second retentate and a second permeate.
11. The process of claim 10 wherein the volume of the second permeate is less than the volume of the second retentate.
12. The process of claim 10 wherein the volume ratio of second retentate to second permeate is greater than about 2:1.
13. The process of claim 10 wherein said second retentate is suitable for use as the ammonia-lean solution in the first cycle.
14. The process of claim 10 wherein said second permeate is suitable for use as the ammonia-ultra-lean or ammonia-free solution in the second cycle.
15. The process of claim 10 which further comprises recycling at least a portion of said second permeate to be employed as at least a portion of the ammonia-ultra-lean or ammonia-free solution in the second cycle.
16. The process of claim 10 which further comprises recycling at least a portion of said second retentate to be employed as at least a portion of the ammonia-lean solution in the first cycle.
17. The process of claim 16 which further comprises mixing said second retentate with at least a portion of said ammonia-rich solution in the first cycle prior to or while employing said second retentate as said ammonia-lean solution in the first cycle.