Systems and methods for active cloud point adjustment and refrigeration cycles
View Patent ↗The present invention pertains to systems, methods, and compositions for liquid phase change, including for active cloud point, e.g., critical solution temperature, adjustment and heating or cooling, e.g., refrigeration, cycles. In some embodiments heat is absorbed, released or both due to phase changes in a liquid system. Advantageously, the phase changes may be controlled by controlling the ingredients or amounts of certain components of the liquid system. Advantages may include lower capital expenditures, lower operating expenses, or both for a diverse and wide range of heating and cooling applications. Such applications include, for example, cooling of data centers, cooled transportation of goods, refrigeration, heat pumps, extractions, ocean thermal energy conversion, and de-icing of roads to name just a few.
1. A liquid phase refrigeration or heat pump cycle process with a liquid system wherein the process comprises:
1) absorbing heat by mixing two or more liquid phases endothermically in a phase transition; and
2) releasing heat exothermically by transforming a liquid phase into two or more liquid phases in a phase transition; and
3) adjusting the phase transition temperature such that the phase transition temperature of step 1) is different than the phase transition temperature of step 2); wherein said adjusting comprises changing a concentration of a reagent.
2. The process of claim 1 wherein said liquid system comprises (1) an absorption solution comprising a critical solution temperature (CST) reagent and a UCST solvent; and (2) a reagent with limited solubility in UCST reagent that is substantially miscible with said absorption solution above an upper critical solution temperature and has limited solubility with said absorption solution below an upper critical solution temperature and wherein said adjusting comprises changing the concentration of said CST reagent with respect to the UCST solvent.
3. The process of claim 1 wherein said adjusting step employs a membrane.
4. The process of claim 2 wherein said CST reagent exhibits decreasing osmotic pressure with increasing temperature in a solution consisting of water and said CST reagent.
5. The process of claim 2 wherein said CST reagent is selected from the group consisting of
Polyethylene Glycol Dimethyl Ether, Polypropylene Glycol, Polyethylene Glycol, Dipropylene Glycol n-Butyl Ether (DPnB), Tri(propylene glycol) butyl ether mixture of isomers (TPnB), Propylene glycol n-butyl ether (PnB), Dipropylene Glycol n-Propyl Ether (DPnP), Diethylene Glycol Monohexyl Ether (D-Hex n-hexyl ether), Propylene glycol propyl ether (PnP), 2-Butoxyethanol (EB Butyl Glycol), PPG 425, PPG 725, PPG 1000, PEGDME 250, PEGDME 500, PEG 1000, PEG 600, PEG 400, PEG 200.
6. The process of claim 1 wherein the process is reversible.
7. The process of claim 1 which further comprises repeating step 1), step 2), step 3) or all steps.
8. A liquid phase refrigeration or heat pump cycle process with a liquid system wherein the process comprises:
1) releasing heat by mixing two or more liquid phases exothermically in a phase transition; and
2) absorbing heat endothermically by transforming a liquid phase into two or more liquid phases in a phase transition; and
3) adjusting the phase transition temperature such that the phase transition temperature of step 1) is different than the phase transition temperature of step 2); wherein said adjusting comprises
changing a concentration of a reagent.
9. The process of claim 8 wherein said phased system comprises a critical solution temperature (CST) reagent, a LCST reducing reagent, and water and wherein said adjusting comprises removing substantially all of said LCST reducing reagent before or during step 1) and introducing said LCST reducing reagent before or during step 2).
10. The process of claim 9 wherein said adjusting step employs a membrane for removing substantially all of said LCST reducing reagent before or during step 1) thereby forming a concentrate suitable for use to introduce LCST reducing reagent before step 2).
11. The process of claim 9 wherein said CST reagent exhibits decreasing osmotic pressure with increasing temperature in a solution consisting of water and said CST reagent.
12. The process of claim 9 wherein said CST reagent is selected from the group consisting of Polyethylene Glycol Dimethyl Ether, Polypropylene Glycol, Polyethylene Glycol, Dipropylene Glycol n-Butyl Ether (DPnB), Tri(propylene glycol) butyl ether mixture of isomers (TPnB), Propylene glycol n-butyl ether (PnB), Dipropylene Glycol n-Propyl Ether (DPnP), Diethylene Glycol Monohexyl Ether (D-Hex n-hexyl ether), Propylene glycol propyl ether (PnP), 2-Butoxyethanol (EB Butyl Glycol), PPG 425, PPG 725, PPG 1000, PEGDME 250, PEGDME 500, PEG 1000, PEG 600, PEG 400, PEG 200.
13. The process of claim 8 wherein the process is reversible.
14. The process of claim 8 which further comprises repeating step 1), step 2), step 3) or all steps.
15. The process of claim 9 which further comprises a binder reagent which is substantially miscible with the CST reagent and has limited solubility in water.
16. The process of claim 15 wherein the binder reagent comprises Ethylene Glycol Diacetate, Propylene Glycol Diacetate, Dipropylene Glycol Dimethyl Ether (DPE), 2-Heptanone, Propylene glycol monomethyl ether acetate, Propylene Carbonate, Cyclohexanone, 1-Octanol, Dipropylene Glycol Methyl Ether Acetate, 1-Methyl-2-pyrrolidinone, Ethylene glycol monohexyl ether, Acetal (1,1-Diethoxyethane), Isoamyl acetate, Dibutyl ether, m-Xylene, Isopropyl acetate, Dimethyl carbonate, Butanone, Methyl tert-butyl ether (MTBE), o-Xylene, Acetylacetone, p-Xylene, Methyl Isobutyl Ketone, Toluene, 3-Pentanone, Propyl acetate, Ethylene glycol monopropyl ether, 2-Methoxyethyl acetate, 5-Methyl-2-hexanone, 4-Methyl-2-pentanone, 3-Pentanone, 2-Pentanone, 2-methyl tetrahydrofuran, or a mixture thereof.
17. The process of claim 1 wherein the UCST solvent is water.
18. The process of claim 9 wherein the LCST reducing agent is selected from a salt, glycerol, urea, and mixtures thereof.