Resin molded article
A resin molded article includes a first resin formed of a polyolefin, reinforcing fibers, a second resin selected from a group consisting of a resin containing at least one of an amide bond and an imide bond, a resin containing an ester bond, and a resin having a linking group containing a sulfur atom, and a compatibilizer. The absolute value of difference in melting temperature between the first resin and the second resin is 130° C. or lower. At least a portion of the second resin forms domains in the first resin. The domains include first domains that do not contain the reinforcing fibers and second domains that contain the reinforcing fibers and that include a coating layer formed of at least a portion of the second resin on the periphery of the reinforcing fibers. The second domains include a second domain A containing one of the reinforcing fibers and a second domain B containing two or more of the reinforcing fibers.
1. A resin molded article comprising:
a first resin formed of a polyolefin;
reinforcing fibers;
a second resin selected from a group consisting of a resin containing at least one of an amide bond and an imide bond, a resin containing an ester bond, and a resin having a linking group containing a sulfur atom, an absolute value of difference in melting temperature between the first resin and the second resin being 130° C. or lower; and
a compatibilizer,
wherein the compatibilizer is a resin that enhances affinity between the first resin and the second resin,
at least a portion of the second resin forms domains in the first resin,
the domains comprise
first domains that do not contain the reinforcing fibers, and
second domains that contain the reinforcing fibers and that include a coating layer formed of at least a portion of the second resin on a periphery of the reinforcing fibers, and
the second domains comprise
a second domain A containing one reinforcing fiber of the reinforcing fibers, and
a second domain B containing two or more reinforcing fibers of the reinforcing fibers.
2. The resin molded article according to claim 1 ,
wherein the first domains have a domain diameter of 0.1 μm or more and 20 μm or less,
the second domain A has a domain diameter of 10 μm or more and 80 μm or less, and
the second domain B has a domain diameter of 80 μm or more and 2,000 μm or less.
3. The resin molded article according to claim 1 ,
wherein the first domains have a domain diameter of 0.1 μm or more and 20 μm or less, and
the area percentage of the first domains is 0.1% or more and 50% or less relative to a total area of the domains formed in the first resin.
4. The resin molded article according to claim 1 , wherein the second resin is at least one resin selected from polyamides and polyesters.
5. The resin molded article according to claim 1 , wherein the reinforcing fibers include at least one type of fiber selected from carbon fibers and glass fibers.
6. The resin molded article according to claim 1 , wherein the reinforcing fibers have a fiber length of 0.1 mm or more and 30 mm or less.
7. The resin molded article according to claim 1 , wherein the compatibilizer is a modified polyolefin, wherein the modified polyolefin includes a polyolefin in which a modified portion having a carboxy group, a carboxylic anhydride residue, a carboxylate residue, an imino group, an amino group, or an epoxy group is introduced.
8. The resin molded article according to claim 1 , wherein an amount of the second resin is 5 parts by mass or more and 50 parts by mass or less relative to 100 parts by mass of the first resin, and an amount of the compatibilizer is 1 part by mass or more and 10 parts by mass or less relative to 100 parts by mass of the first resin.
9. The resin molded article according to claim 1 , wherein an amount of the second resin is 5 mass % or more and 100 mass % or less relative to the mass of the reinforcing fibers.
10. The resin molded article according to claim 1 , wherein an amount of the compatibilizer is 0.1 mass % or more and 30 mass % or less relative to the mass of the reinforcing fibers.
11. The resin molded article according to claim 1 , wherein an amount of the compatibilizer is 0.1 parts by mass or more and 50 parts by mass or less relative to 100 parts by mass of the second resin.
12. A resin molded article comprising:
a first resin formed of a polyolefin;
reinforcing fibers;
a second resin selected from a group consisting of a resin containing at least one of an amide bond and an imide bond, a resin containing an ester bond, and a resin having a linking group containing a sulfur atom, an absolute value of difference in melting temperature between the first resin and the second resin being 130° C. or lower; and
a compatibilizer,
wherein the compatibilizer is a resin that enhances affinity between the first resin and the second resin,
at least a portion of the second resin forms domains in the first resin,
the domains comprise
first domains that do not contain the reinforcing fibers, and
second domains that contain the reinforcing fibers and that include a coating layer formed of at least a portion of the second resin on a periphery of the reinforcing fibers, and
a gel fraction of the resin molded article is 10% or more and 60% or less.
13. The resin molded article according to claim 12 ,
wherein the first domains have a domain diameter of 0.1 μm or more and 20 μm or less,
the second domains comprise a second domain A containing one reinforcing fiber of the reinforcing fibers, and a second domain B containing two or more reinforcing fibers of the reinforcing fibers,
the second domain A has a domain diameter of 10 μm or more and 80 μm or less, and
the second domain B has a domain diameter of 80 μm or more and 2,000 μm.
14. The resin molded article according to claim 12 ,
wherein the first domains have a domain diameter of 0.1 μm or more and 20 μm or less, and
an area percentage of the first domains is 0.1% or more and 50% or less relative to a total area of the domains formed in the first resin.
15. The resin molded article according to claim 12 , wherein the reinforcing fibers have a fiber length of 0.1 mm or more and 30 mm or less.
16. A resin molded article comprising:
a first resin formed of a polyolefin;
reinforcing fibers;
a second resin selected from a group consisting of a resin containing at least one of an amide bond and an imide bond, a resin containing an ester bond, and a resin having a linking group containing a sulfur atom, an absolute value of difference in melting temperature between the first resin and the second resin being 130° C. or lower; and
a compatibilizer,
wherein the compatibilizer is a resin that enhances affinity between the first resin and the second resin,
at least a portion of the second resin forms domains in the first resin,
the domains comprise
first domains that do not contain the reinforcing fibers, and
second domains that contain the reinforcing fibers and that include a coating layer formed of at least a portion of the second resin on a periphery of the reinforcing fibers, and
a frequency distribution curve of distances between adjacent reinforcing fibers of the reinforcing fibers has at least two local maximum values.
17. The resin molded article according to claim 16 ,
wherein the first domains have a domain diameter of 0.1 μm or more and 20 μm or less,
the second domains comprise a second domain A containing one of the reinforcing fibers, and a second domain B containing two or more of the reinforcing fibers,
the second domain A has a domain diameter of 10 μm or more and 80 μm or less, and
the second domain B has a domain diameter of 80 μm or more and 2,000 μm or less.
18. The resin molded article according to claim 16 ,
wherein the first domains have a domain diameter of 0.1 μm or more and 20 μm or less, and
an area percentage of the first domains is 0.1% or more and 50% or less relative to a total area of the domains formed in the first resin.
19. The resin molded article according to claim 16 , wherein the reinforcing fibers have a fiber length of 0.1 mm or more and 30 mm or less.