Conveyor lubricants including emulsions and methods employing them

1. A method for lubricating the passage of a container along a conveyor, comprising:

applying a lubricating emulsion to at least a portion of a container-contacting surface of the conveyor or to at least a portion of a conveyor-contacting surface of the container, the lubricating emulsion comprising:

(a) a water insoluble oil with viscosity greater than about 300 centipoise;

(b) about 0 to about 0.35 wt-% emulsifier; and

(c) about 99.3 to about 99.99 wt-% water, inclusive of any hydrophilic diluents;

wherein the lubricating emulsion is applied for a period of time and not applied for a period of time and the ratio of not applied:applied time is between 2:1 and 32:1 and the not applied time is from about 30 seconds to 12 minutes.

2. The method of claim 1 , wherein the water insoluble oil comprises from about 0.01% to about 0.35% of a weakly amphipathic compound based on the total weight of the lubricating emulsion.

3. The method of claim 1 , wherein the water insoluble oil has a viscosity of at least about 300 centipoise when measured with a parallel plate rheometer with 20 mm plate diameter and 0.25 mm plate separation at an integrated average shear rate of 5.9 sec −1 .

4. The method of claim 1 , wherein the water insoluble oil is selected from the group consisting of water insoluble unacidified fatty amine compounds, water insoluble phosphate ester compounds, and mixtures thereof.

5. The method of claim 1 , wherein the water insoluble oil is present from about 0.01 to about 0.35 wt. %.

6. The method of claim 1 , wherein the water insoluble oil is emulsified with the emulsifier, and the resulting emulsion has a particle size from about 0.05 to about 5 microns.

7. The method of claim 1 , wherein the applying comprises spraying the composition through a non-energized nozzle.

8. The method of claim 1 , wherein applying comprises applying the lubricating emulsion for a first length of time and not applying it for a second length of time; wherein the ratio of the first length to the second length is about 1 to greater than or equal to about 10.

9. The method of claim 1 , wherein the emulsion further comprises an additional component.

10. The method of claim 1 , wherein the emulsion maintains a coefficient of friction of less than about 0.4 over the entire period of use.

11. The method of claim 1 , wherein the container comprises polyethylene terephthalate, polyethylene naphthalate, polyethylene, polypropylene, paper board, glass, or metal.

12. The method of claim 1 , wherein the lubricant emulsion comprises:

(a) an amine selected from the group consisting of oleyl diamino propane, coco diamino propane, lauryl propyl diamine, dimethyl lauryl amine, and mixtures thereof;

(b) about 0.05 about 15 wt-% emulsifier; and

(c) about 55 to about 97 wt-% water,

wherein the lubricant emulsion has a pH of greater than 12.

13. A method for lubricating the passage of a container along a conveyor comprising:

(a) providing a lubricant concentrate comprising

i) a water insoluble oil with a viscosity greater than about 300 centipoise; and

ii) an emulsifier;

(b) diluting the lubricant concentrate with water to form a lubricant use composition, the lubricant use composition comprising:

i) the water insoluble oil;

ii) from about 0 to about 0.35% of the emulsifier; and

iii) from about 99.3 to about 99.99% water; and

applying the lubricant use composition to at least a portion of the container-contacting surface of the conveyor or to at least a portion of a conveyor-contacting surface of the container, wherein the lubricant use composition is applied for a period of time and not applied for a period of time and the ratio of not applied:applied time is between 2:1 and 32:1 and the not applied time is about 30 seconds to 12 minutes.

14. The method of claim 1 , wherein the water insoluble oil comprises one or more unacidified fatty amine compound selected from the group consisting of oleyl diamino propane, coco diamino propane, lauryl propyl diamine, dimethyl lauryl amine, alkyl C12-C14 oxypropyl diamine, and mixtures thereof.

15. The method of claim 1 , wherein the water insoluble oil comprises one or more phosphate esters selected from the group consisting of oleyl-(EO) 4 OPO 3 H 2 , oleocetyl -(EO) 5 OPO 3 H 2 , and mixtures thereof.

16. The method of claim 1 , wherein the water insoluble oil comprises one or more alkyl ethercarboxylates selected from the group consisting of oleocetyl -(EO) 2 CH 2 COOH, oleocetyl-(EO) 5 CH 2 COOH, and mixtures thereof.

17. The method of claim 1 , wherein the water insoluble oil comprises one or more glycerides selected from the group consisting of monoglycerides, diglycerides, triglycerides, and mixtures thereof.

18. The method of claim 1 , wherein the water insoluble oil comprises one or more glycerides selected from the group consisting esters of caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, eleostearic acid, arachic acid, gadoleic acid, behenic acid, erucic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, erucic acid, and mixtures thereof.

19. The method of claim 1 , wherein the water insoluble oil comprises one or more phospholipids selected from the group consisting of phosphatidic acids, phosphatidyl glycerols, cardiolipins, lecithins, cardiolipins, lysophospholipids, lysoleci thins, plasmalogens, phosphosphingolipids, sphingo myelins, phosphatidyl choline, phosphatidylethanolamine, phosphatidylinositol, N-acylphosphatidylethanolamine, lecithins, and mixtures thereof.

20. The method of claim 1 , wherein the water insoluble oil comprises one or more lanolins or lanolin derivatives.

21. The method of claim 1 , wherein the water insoluble oil comprises one or more long chain fatty acids derived from the saponification of vegetable or animal fat or an oil, wherein the fatty acids comprise more than about 8 carbon atoms.

22. The method of claim 1 , wherein the water insoluble oil comprises one or more compounds selected from alcohol ethoxylates, alcohol propoxylates, alcohol ethoxylate propoxylates, and mixtures thereof.

23. The method of claim 1 , wherein the water insoluble oil comprises one or more sorbitan esters of linear or branched long chain fatty acids, wherein the fatty acids comprise more than about 8 carbon atoms.

24. The method of claim 1 , wherein the water insoluble oil comprises one or more fatty alcohol compounds selected from the group consisting of capryl alcohol, 2-ethyl hexanol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, oleyl alcohol, behenyl alcohol, erucyl alcohol, and mixtures thereof.

25. The method of claim 1 , wherein the water insoluble oil comprises one or more polyol fatty acid polyesters derived from esterification of one or more fatty acids with a polyol, wherein two or more of hydroxyl groups of the polyol are esterified with acid groups of the fatty acids, and wherein the fatty acids comprise more than about 8 carbon atoms.

26. The method of claim 1 , wherein the water insoluble oil comprises one or more esters selected from the group consisting of cetyl palmitate, palmoyl palmitate, cetyl stearate, cetyl isostearate, cetyl oleate, 2- ethyl hexyl palmitate, stearyl stearate, and mixtures thereof.

27. The method of claim 1 , wherein the water insoluble oil comprises one or more fatty alcohol esters selected from the group consisting of C12-C15 alkyl benzoate, dioctyl phthalate, tridecyl trimellitate, trimethylol propane trioleate, trimethylol propane tricaprate/caprylate, and mixtures thereof.

28. The method of claim 1 , wherein the water insoluble oil comprises mineral oil.