Compound for organic optoelectronic device, composition for organic optoelectronic device and organic optoelectronic device and display device
Disclosed are the compound for an organic optoelectronic device, the compound being represented by Chemical Formula 1, a composition for an organic optoelectronic device including the compound for an organic optoelectronic device, an organic optoelectronic device, and a display device. In Chemical Formula 1, each substituent is the same as defined in the specification.
1. An organic optoelectronic device, comprising: an anode and a cathode facing each other, and at least one organic layer disposed between the anode and the cathode, wherein the organic layer includes a light emitting layer, and the light emitting layer includes:
a first compound and a second compound, wherein the first compound and the second compound are each a host material for a phosphorescent dopant, wherein:
the first compound is represented by Chemical Formula 1-2, and
the second compound is represented by Chemical Formula 2; or a combination of Chemical Formula 3 and Chemical Formula 4,
wherein in Chemical Formula 1-2,
R 1 to R 4 are each hydrogen,
Ar 1 and Ar 2 are each independently a substituted or unsubstituted C6 to C30 aryl group or a group represented by Chemical Formula A, provided that at least one of Ar 1 and Ar 2 is a group represented by Chemical Formula A:
wherein, in Chemical Formula A,
X 1 is 0 or S,
R 5 to R 7 are each independently hydrogen, deuterium, a substituted or unsubstituted C1 to C6 alkyl group, or a substituted or unsubstituted phenyl group, and
* is a linking point,
wherein, in Chemical Formula 2,
Y 1 and Y 2 are each independently a substituted or unsubstituted C6 to C20 aryl group, or a substituted or unsubstituted C2 to C30 heterocyclic group,
L 1 and L 2 are each independently a single bond, or a substituted or unsubstituted C6 to C20 arylene group,
R a and R 8 to R 11 are each independently hydrogen, deuterium, a cyano group, a substituted or unsubstituted C1 to C10 alkyl group, a substituted or unsubstituted C6 to C20 aryl group, or a substituted or unsubstituted C2 to C30 heterocyclic group, and
m is 0, 1, or 2;
wherein, in Chemical Formulae 3 and 4,
Y 3 and Y 4 are each independently a substituted or unsubstituted C6 to C20 aryl group, or a substituted or unsubstituted C2 to C30 heterocyclic group,
adjacent two *'s of Chemical Formula 3 are C bonded with Chemical Formula 4,
other adjacent two of Chemical Formula 3 not being bonded with Chemical Formula 4 * are each independently C-L a -R b ,
L a , L 3 , and L 4 are each independently a single bond, or a substituted or unsubstituted C6 to C20 arylene group, and
R b and R 12 to R 15 are each independently hydrogen, deuterium, a cyano group, a substituted or unsubstituted C1 to C10 alkyl group, a substituted or unsubstituted C6 to C20 aryl group, or a substituted or unsubstituted C2 to C30 heterocyclic group.
2. The organic optoelectronic device of claim 1 , wherein, in Chemical Formula 1-2, one of Ar 1 and Ar 2 is the group represented by Chemical Formula A and the other of Ar 1 and Ar 2 is a substituted or unsubstituted C6 to C30 aryl group.
3. The composition for an organic optoelectronic device of claim 1 , wherein, in Chemical Formula 1-2, Ar 1 and Ar 2 are each independently a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted naphthyl group, or the group represented by Chemical Formula A.
4. The organic optoelectronic device of claim 1 , wherein, in Chemical Formula 1-2, Ar 1 and Ar 2 are each independently one of groups of Group I:
Wherein, in Group I, * is a linking point.
5. The organic optoelectronic device of claim 1 , wherein the first compound is one of the compounds of Group 1 :
6. The organic optoelectronic device of claim 1 , wherein:
the second compound is represented by Chemical Formula 2, and Chemical Formula 2 is one of structures of Group II in which each * represents a linking point to a * in one of substituents of Group
Wherein, in Group II and Group III, * is a linking point.
7. The organic optoelectronic device of claim 6 , wherein Chemical Formula 2 is Chemical Formula C-8 or Chemical Formula C-17 of Group II in which each represents a linking point to a* in one of the substituents of Group III.
8. The organic optoelectronic device of claim 7 , wherein Chemical Formula 2 is Chemical Formula C-8 or Chemical Formula C-17 of Group II in which each * represents a linking point to a* in one of B-1, B-2, and B-3 of Group III.
9. The organic optoelectronic device of claim 1 , wherein:
the second compound is represented by Chemical Formula 2, and
Chemical Formula 2 is represented by Chemical Formula 2A:
Wherein, in Chemical Formula 2A,
Y 1 and Y 2 are each independently a substituted or unsubstituted C6 to C20 aryl group, or a substituted or unsubstituted C2 to C30 heterocyclic group,
L 1 and L 2 are each independently a single bond, or a substituted or unsubstituted C6 to C20 arylene group,
R 8 to R 11 are each independently hydrogen, deuterium, a cyano group, a substituted or unsubstituted C1 to C10 alkyl group, a substituted or unsubstituted C6 to C20 aryl group, or a substituted or unsubstituted C2 to C30 heterocyclic group.
10. The organic optoelectronic device of claim 1 , wherein:
the second compound is represented by a combination of Chemical Formula 3 and Chemical Formula 4, and
the second compound represented by a combination of Chemical Formula 3 and Chemical Formula 4 is represented by Chemical Formula 3C:
wherein, in Chemical Formula 3C,
Y 3 and Y 4 are each independently a substituted or unsubstituted C6 to C20 aryl group, or a substituted or unsubstituted C2 to C30 heterocyclic group,
L a to La 2 , L 3 and L 4 are each independently a single bond, or a substituted or unsubstituted C6 to C20 arylene group, and
R b1 to R b2 and R 12 to R 15 are each independently hydrogen, deuterium, a cyano group, a substituted or unsubstituted C1 to C10 alkyl group, a substituted or unsubstituted C6 to C20 aryl group, or a substituted or unsubstituted C2 to C30 heterocyclic group.
11. The organic optoelectronic device of claim 10 , wherein:
Y 3 and Y 4 are each independently a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted pyridinyl group, a substituted or unsubstituted carbazolyl group, a substituted or unsubstituted dibenzofuranyl group, or a substituted or unsubstituted dibenzothiophenyl group, and
R b1 to R b2 and R 12 to R 15 are each independently hydrogen, deuterium, a cyano group, a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted pyridinyl group, a substituted or unsubstituted carbazolyl group, a substituted or unsubstituted dibenzofuranyl group, or a substituted or unsubstituted dibenzothiophenyl group.
12. The organic optoelectronic device of claim 10 , wherein Y 3 and Y 4 are each independently selected from substituents cf Group IV:
Wherein in Group IV,
* is a linking point with L 3 and L 4 .
13. The organic optoelectronic device of claim 1 , wherein:
The second compound is represented by Chemical Formula 2A or Chemical Formula 3C:
wherein, in Chemical Formula 2A and Chemical Formula 3C,
Y 1 to Y 4 are each independently a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted pyridinyl group, a substituted or unsubstituted carbazolyl group, a substituted or unsubstituted dibenzofuranyl group, or a substituted or unsubstituted dibenzothiophenyl group,
L 1 to L 4 , L a1 and L a2 are each independently a single bond, or a substituted or unsubstituted C6 to C20 arylene group, and
R b1 , R b2 , and R 8 to R 15 are each independently hydrogen, deuterium, a cyano group, a substituted or unsubstituted phenyl group, a substituted or unsubstituted biphenyl group, a substituted or unsubstituted pyridinyl group, a substituted or unsubstituted carbazolyl group, a substituted or unsubstituted dibenzofuranyl group, or a substituted or unsubstituted dibenzothiophenyl group.
14. A display device comprising the organic optoelectronic device of claim 1 .