Air pollution sensor to measure major carbon components in the environment
The invention relates to a device for measuring, in near-real-time, the level of black carbon, brown carbon, organic carbon, total carbon and CO 2 in air. The device also provides for a direct calculation of aerosol angstrom coefficient as well as estimation of emissions rates of black carbon or brown carbon from nearby combustion sources.
1. A device for measuring the level of CO 2 , particle phase carbonaceous components, and the absorption angstrom coefficient in indoor and outdoor air, the device comprising:
an inlet for air containing particles to enter the device;
an outlet for air to exit the device;
a vacuum source to draw air into and out of the device;
a first fibrous filter;
a second fibrous filter;
at least one light source;
at least one light detector;
a first heating element in thermal connection with the first fibrous filter and a second heating element in connection with the second fibrous filter;
at least one heated oxidation catalyst; and
a CO 2 detector;
wherein the first fibrous filter and the second fibrous filter are not made of carbonaceous material and are configured to be heated to temperatures up to 1200° C.; the first fibrous filter is configured to collect particulate matter and gas phase organics from the air; the second fibrous filter is configured to collect approximately the same amount of gas phase organics from the air to account for artifact gas phase organics that are collected by the first filter; the first fibrous filter and the second fibrous filter are positioned between the at least one light source and the at least one light detector; air is directed from the inlet through the first fibrous filter, over the at least one oxidation catalyst, through the second fibrous filter, to a CO 2 detector, and through the outlet; the at least one light source directs light at preset wavelengths through the first fibrous filter and the second fibrous filter to the at least one light detector to detect the particle phase carbonaceous components in air.
2. The device of claim 1 , wherein the particle phase carbonaceous components in air measured by the device comprise black carbon, brown carbon, organic carbon and total carbon.
3. The device of claim 2 , wherein the levels of CO 2 , absorption angstrom coefficient, black carbon, and brown carbon, are measured simultaneously.
4. The device of claim 1 , wherein the inlet comprises at least one of a size selective inlet and a light scattering sensor.
5. The device of claim 1 , wherein the first fibrous filter and the second fibrous filter are made of quartz fiber.
6. The device of claim 5 , wherein the first fibrous filter and the second fibrous filter are configured to be regenerated by heating each filter to a temperature from about 500° C. to about 1200° C.
7. The device of claim 6 , wherein the at least one oxidation catalyst comprises two oxidation catalysts, the second oxidation catalyst located so the flow of air is directed to the second oxidation catalyst after passing through the second fibrous filter.
8. The device of claim 7 , wherein carbonaceous gases evolved from regenerative heating of the first fibrous filter and the second fibrous filter pass over at least one heated oxidation catalyst and are converted to CO 2 , and the CO 2 detector measures the evolved CO 2 as an indirect measure of the carbon that was collected on the filters.
9. The device of claim 8 , wherein the device comprises a chamber that encompasses the second fibrous filter and the at least one oxidation chamber, and the walls of the chamber are heated above ambient temperature or are coated with a substance to reduce absorption of the evolved gas phase organics or CO 2 .
10. The device of claim 1 , wherein the CO 2 detector is a nondispersive infrared sensor, a solid-state infrared detector, or MEMS detector.
11. The device of claim 1 , wherein the at least one light source is configured to emit light at a wavelength of from 200 to 1200 nm.
12. The device of claim 11 , wherein the at least one light source is configured to emit light at a wavelength of about 880 nm to measure the level of black carbon.
13. The device of claim 11 , wherein the at least one light source is configured to emit light at a wavelength of about 370 nm to measure the level of brown carbon.
14. The device of claim 1 , further comprising a relative humidity sensor, pressure sensor, and a temperature sensor.
15. The device of claim 14 , wherein the first fibrous filter is configured to filter particulate matter and the second fibrous filter is configured to compensate for changes in temperature, pressure, and relative humidity.
16. The device of claim 1 , wherein the at least one light detector is a photodiode.
17. The device of claim 16 , wherein the photodiode generates electrical voltages that are linearly proportional to the light transmitted through the first filter and the second fibrous filter.
18. The device of claim 1 , wherein the at least one light source is an LED.
19. The device of claim 1 , further comprising a flow measurement and flow control device.
20. The device of claim 17 , further comprising an analog to digital converter (ADC) and a microcontroller unit (MCU), wherein the analog voltage measurements form the photodiodes are digitized using the ADC and processed by the MCU.