Metallization of solar cells with differentiated p-type and n-type region architectures
Methods of fabricating solar cell emitter regions with differentiated P-type and N-type regions architectures, and resulting solar cells, are described. In an example, a back contact solar cell can include a substrate having a light-receiving surface and a back surface. A first polycrystalline silicon emitter region of a first conductivity type is disposed on a first thin dielectric layer disposed on the back surface of the substrate. A second polycrystalline silicon emitter region of a second, different, conductivity type is disposed on a second thin dielectric layer disposed on the back surface of the substrate. A third thin dielectric layer is disposed over an exposed outer portion of the first polycrystalline silicon emitter region and is disposed laterally directly between the first and second polycrystalline silicon emitter regions. A first conductive contact structure is disposed on the first polycrystalline silicon emitter region. A second conductive contact structure is disposed on the second polycrystalline silicon emitter region. Metallization methods, include etching techniques for forming a first and second conductive contact structure are also described.
1. A solar cell, comprising:
a substrate having a light-receiving surface and a back surface;
a first thin dielectric layer disposed on the back surface of the substrate;
a first polycrystalline silicon emitter region of a first conductivity type disposed on the first thin dielectric layer, the first polycrystalline silicon emitter region having an exposed outer top portion, wherein the first thin dielectric layer is directly contacting the back surface of the substrate and the first polycrystalline silicon emitter region;
a second polycrystalline silicon emitter region of a second, different, conductivity type disposed on a second thin dielectric layer disposed on the back surface of the substrate;
a third thin dielectric layer disposed directly on the exposed outer top portion of the first polycrystalline silicon emitter region and disposed laterally directly between the first and second polycrystalline silicon emitter regions, wherein a lateral region of the third thin dielectric layer is directly contacting the first and second polycrystalline silicon emitter regions;
a first conductive contact structure disposed over the first polycrystalline silicon emitter region;
a second conductive contact structure disposed over the second polycrystalline silicon emitter region; and
an insulator layer disposed on and in direct contact with the first polycrystalline silicon emitter region, wherein the first conductive contact structure is disposed through the insulator layer, and wherein a portion of the second polycrystalline silicon emitter region overlaps and is directly on the insulator layer but is not touching the first conductive contact structure.
2. The solar cell of claim 1 , wherein the insulator layer comprises an oxynitride or a nitride.
3. The solar cell of claim 1 ,
wherein the first conductive contact structure is disposed through another portion of the second polycrystalline silicon layer of the second conductivity type.
4. The solar cell of claim 1 , wherein the substrate is an N-type monocrystalline silicon substrate, the first conductivity type is P-type, and the second conductivity type is N-type.
5. The solar cell of claim 1 , wherein all of the first, second and third thin dielectric layers comprise silicon dioxide.
6. The solar cell of claim 1 , wherein the second polycrystalline silicon emitter region is disposed on a portion of the third thin dielectric layer disposed over the exposed outer portion of the first polycrystalline silicon emitter region.
7. The solar cell of claim 1 , wherein the third thin dielectric layer comprises silicon and oxygen.
8. The solar cell of claim 1 , wherein the first and second conductive contact structure each comprise a metal directly on the first and second polycrystalline silicon emitter regions, respectively.
9. A solar cell, comprising:
a substrate having a light-receiving surface and a back surface;
a first thin dielectric layer disposed on the back surface of the substrate;
a first polycrystalline silicon emitter region of a first conductivity type disposed on the first thin dielectric layer, the first polycrystalline silicon emitter region having an exposed outer top portion, wherein the first thin dielectric layer is directly contacting the back surface of the substrate and the first polycrystalline silicon emitter region;
a second polycrystalline silicon emitter region of a second, different, conductivity type disposed on a second thin dielectric layer disposed on the back surface of the substrate;
a third thin dielectric layer disposed directly on the exposed outer top portion of the first polycrystalline silicon emitter region and disposed laterally directly between the first and second polycrystalline silicon emitter regions, wherein a lateral region of the third thin dielectric layer is directly contacting the first and second polycrystalline silicon emitter regions;
a first conductive contact structure disposed over the first polycrystalline silicon emitter region;
a second conductive contact structure disposed over the second polycrystalline silicon emitter region, wherein the first and second conductive contact structures each comprise a metal foil disposed on a metal seed layer disposed on the first and second polycrystalline silicon emitter regions, respectively; and
an insulator layer disposed on and in direct contact with the first polycrystalline silicon emitter region, wherein the first conductive contact structure is disposed through the insulator layer, and wherein a portion of the second polycrystalline silicon emitter region overlaps and is directly on the insulator layer but is not touching the first conductive contact structure.
10. The solar cell of claim 9 , wherein the insulator layer comprises an oxynitride or a nitride.
11. The solar cell of claim 9 ,
wherein the first conductive contact structure is disposed through another portion of the second polycrystalline silicon layer of the second conductivity type.
12. The solar cell of claim 9 , wherein the substrate is an N-type monocrystalline silicon substrate, the first conductivity type is P-type, and the second conductivity type is N-type.
13. The solar cell of claim 9 , wherein all of the first, second and third thin dielectric layers comprise silicon dioxide.
14. The solar cell of claim 9 , wherein the second polycrystalline silicon emitter region is disposed on a portion of the third thin dielectric layer disposed over the exposed outer portion of the first polycrystalline silicon emitter region.
15. A solar cell, comprising:
a substrate having a light-receiving surface and a back surface;
a first thin dielectric layer disposed on the back surface of the substrate;
a N-type emitter region disposed on a first thin dielectric layer, the N-type emitter region having an exposed outer top portion, wherein the first thin dielectric layer is directly contacting the substrate and the N-type emitter region;
an P-type emitter region disposed on a second thin dielectric layer disposed on the back surface of the substrate;
a third thin dielectric layer disposed directly on the exposed outer top portion of the N-type emitter region and disposed laterally directly between the N-type and the P-type emitter regions, wherein a lateral region of the third thin dielectric layer is directly contacting the N-type and the P-type emitter regions;
a first conductive contact structure disposed over the N-type emitter region;
a second conductive contact structure disposed over the P-type emitter region, wherein the first and second conductive contact structure comprise a metal foil; and
an insulator layer disposed on and in direct contact with the N-type emitter region, wherein the first conductive contact structure is disposed through the insulator layer, and wherein a portion of the P-type emitter region overlaps and is directly on the insulator layer but is not touching the first conductive contact structure.
16. The solar cell of claim 15 , wherein the first and second conductive contact structures each comprises a metal seed layer disposed on the N-type and P-type emitter regions, respectively, and the metal foil of each of first and second conductive contact structures is disposed on the respective metal seed layer.
17. The solar cell of claim 15 , wherein the metal foil of each of the first and second conductive contact structures is directly on the N-type and P-type emitter regions, respectively.
18. The solar cell of claim 15 ,
wherein the first conductive contact structure is disposed through another portion of the P-type emitter region.
19. The solar cell of claim 15 , wherein the substrate is an N-type monocrystalline silicon substrate.