Copper-based alloy
A copper-based alloy which includes Cu, Ni, Si, Fe, and Mg, and at least one selected from the group consisting of Mo, W, and V, and in which a content of Mg is 0.02 mass % or more. The copper-based alloy exhibits wear resistance and improved weldability with respect to a substrate.
1. A valve system member comprising:
a substrate formed of a material selected from the group consisting of aluminum, an aluminum-based alloy, iron, an iron-based alloy, copper, and a copper-based alloy; and
a cladding part welded on a surface of the substrate, the cladding part being formed of a copper-based alloy comprising:
Ni: 15.8-17.5 mass %,
Si: 2.08-2.89 mass %,
Fe: 7.03-9.06 mass %,
Mg: 0.02-1.53 mass %,
Mo: 6.55-9.09 mass %,
optionally, Cr: 1.0 mass % to 15.0 mass %, and
remainder Cu and a total of 5 mass % or less of other elements,
wherein the valve system member is for an internal combustion engine or sliding member.
2. The valve system member according to claim 1 , wherein the substrate is formed of an aluminum-based alloy.
3. The valve system member according to claim 1 , wherein the copper-based alloy has a weldability such that a welding lower limit laser output at which deposition efficiency of the copper-based alloy onto an aluminum alloy-based substrate using a laser cladding device is 80% or more is at least 0.86 times less than the welding lower limit laser output at which 80% deposition efficiency is achieved when no Mg is included in the copper-based alloy.
4. The valve system member according to claim 3 , wherein the copper-based alloy has a wear resistance such that a wear amount after rotating at 0.3 m/s while pressing under a load of 9 MPa at 473 K against a heat resistant steel is 6.5 mg or less.
5. The valve system member according to claim 1 , wherein the copper-based alloy has a wear resistance such that a wear amount after rotating at 0.3 m/s while pressing under a load of 9 MPa at 473 K against a heat resistant steel is 6.5 mg or less.
6. The valve system member according to claim 1 , wherein the copper-based alloy does not comprise NbC.
7. The valve system member according to claim 1 , wherein the copper-based alloy comprises Cr: 1.0 mass % to 15.0 mass %.
8. The valve system member according to claim 1 , wherein the remainder of the copper-based alloy is Cu and a total of 2 mass % or less of other elements.
9. The valve system member according to claim 8 , wherein the remainder of the copper-based alloy is Cu and a total of 1 mass % or less of other elements.