IP Library Granted Patent US 10,833,221
Granted Patent B2
US 10,833,221 · App. 16/294,825 · Granted Nov 10, 2020

Heterostructure and light-emitting device employing the same

Inventors: Jianping Zhang (San Jose, CA); Ying Gao (San Jose, CA); Ling Zhou (San Jose, CA)
Assignee: BOLB INC.
H01L33/06H01L31/03042H01L31/03048H01L31/035236H01L33/325
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Quick Facts
Patent No.
US 10,833,221
App. No.
16/294,825
Granted
Nov 10, 2020
Kind
B2
Abstract

Heterostructures containing one or more sheets of positive charge, or alternately stacked AlGaN barriers and AlGaN wells with specified thickness are provided. Also provided are multiple quantum well structures and p-type contacts. The heterostructures, the multiple quantum well structures and the p-type contacts can be used in light emitting devices and photodetectors.

Claims (42)

1. A multiple quantum well structure for a light emitting device or a photodetector, comprising alternately stacked AlGaN barriers and AlGaN wells, wherein a thickness of each of the AlGaN barriers and the AlGaN wells respectively satisfies:

h

i

-

σ

i

2

ρ

0

i

,

where h i is the thickness of i th AlGaN barrier or well; σ i is sheet charge density of a sheet of charge on a surface of the i th AlGaN barrier or well, the surface being oppositely charged in regard to net activated dopant in the i th AlGaN barrier or well; and

ρ 0i =eN Di −eN Ai is maximal bulk charge density, allowed by applied doping concentration, in a depletion zone of the i th AlGaN barrier or well generated by the sheet of charge, N Di and N Ai are donor and acceptor concentrations, respectively, in the i th AlGaN barrier or well, e is electric elementary charge.

2. The multiple quantum well structure of claim 1 , wherein one or more of the AlGaN wells comprises an n-type doped AlGaN prior-well spacer, an n-type doped AlGaN post-well spacer, and an AlGaN main well sandwiched between the n-type doped AlGaN prior-well spacer and the n-type doped AlGaN post-well spacer, wherein an Al-composition of the n-type doped AlGaN prior-well spacer and an Al-composition of the n-type doped AlGaN post-well spacer are different than an Al-composition of the AlGaN main well, and a thickness of the n-type doped AlGaN prior-well spacer and a thickness of the n-type doped AlGaN post-well spacer are smaller than a thickness of the AlGaN main well and a thickness of adjacent AlGaN barrier.

3. The multiple quantum well structure of claim 2 , wherein the n-type doped AlGaN prior-well spacer and the n-type doped AlGaN post-well spacer are Si-doped with a doping concentration of 1.0×10 18 -8.0×10 18 cm −3 , respectively, the AlGaN main well is undoped or Si-doped with a doping concentration less than 5.0×10 17 cm −3 , at least one of the AlGaN barriers is Si-doped with a doping concentration of 1.0×10 18 -8.0×10 18 cm −3 .

4. The multiple quantum well structure of claim 2 , wherein a thickness of the n-type doped AlGaN prior-well spacer and a thickness of the n-type doped AlGaN post-well spacer are in the range of 0.1 nm to 0.52 nm, respectively.

5. The multiple quantum well structure of claim 2 , wherein the Al-composition of the n-type doped AlGaN prior-well spacer and the Al-composition of the n-type doped AlGaN post-well spacer are higher than an Al-composition of adjacent AlGaN barrier.

6. The multiple quantum well structure of claim 5 , wherein the n-type doped AlGaN prior-well spacer and the n-type doped AlGaN post-well spacer are made of AlN and have a thickness in the range of 0.1-0.52 nm, respectively.

7. The multiple quantum well structure of claim 2 , wherein the Al-composition of the n-type doped AlGaN prior-well spacer and the Al-composition of the n-type doped AlGaN post-well spacer are lower the Al-composition of the AlGaN main well.

8. The multiple quantum well structure of claim 7 , wherein the n-type doped AlGaN prior-well spacer and the n-type doped AlGaN post-well spacer are made of GaN and have a thickness in the range of 0.1-0.52 nm, respectively.

9. The multiple quantum well structure of claim 2 , wherein the Al-composition of the n-type doped prior-well spacer is higher than an Al-composition of adjacent AlGaN barrier and the Al-composition of the n-type doped AlGaN post-well spacer is lower the Al-composition of the AlGaN mail well; or the Al-composition of the n-type doped AlGaN post-well spacer is higher than an Al-composition of the AlGaN barrier and the Al-composition of the AlGaN prior-well spacer is lower the Al-composition of the AlGaN main well.

10. The multiple quantum well structure of claim 9 , wherein one of the n-type doped AlGaN prior-well spacer and the n-type doped AlGaN post-well spacer is made of AlN and the other is made of GaN, and have a thickness in the range of 0.1-0.52 nm, respectively.

11. The multiple quantum well structure of claim 2 , further comprising an undoped AlGaN barrier formed on one of the AlGaN wells on one side and to be in contact with a p-type structure of the light emitting device or photodetector on the other side.

12. The multiple quantum well structure of claim 1 , wherein one or more of the AlGaN barriers contains one or more sheet of positive charge, and a distance between two adjacent sheets of positive charge is larger than a depletion depth of a depletion zone generated by any one of the two adjacent sheets of positive charge.

13. The multiple quantum well structure of claim 12 , wherein the sheets of positive charge are formed via Si-delta doping with a sheet doping density equal to or greater than 10 12 cm −2 .

14. The multiple quantum well structure of claim 12 , wherein each of the AlGaN barriers that contain the sheet of positive charge comprises a Si-doped layer with a doping concentration of 1.0-8.0×10 18 cm −3 and an undoped layer separated by the sheet of positive charge.

15. The multiple quantum well structure of claim 14 , wherein a thickness of the Si-doped layer of each of the AlGaN barriers that contain the sheet of positive charge is in the range of 6-10 nm, respectively, and a thickness of the undoped layer of each of the AlGaN barriers that contain the sheet of positive charge is in the range of 2-4 nm, respectively.

16. The multiple quantum well structure of claim 12 , further comprising an undoped AlGaN barrier formed on one of the AlGaN wells on one side and to be in contact with a p-type structure of the light emitting device or photodetector on the other side.

17. The multiple quantum well structure of claim 12 , wherein one or more of the AlGaN wells comprises an n-type doped AlGaN prior-well spacer, an n-type doped AlGaN post-well spacer, and an AlGaN main well sandwiched between the n-type doped AlGaN prior-well spacer and the n-type doped AlGaN post-well spacer, wherein an Al-composition of the n-type doped AlGaN prior-well spacer and an Al-composition of the n-type doped AlGaN post-well spacer are different than an Al-composition of the AlGaN main well, and a thickness of the n-type doped AlGaN prior-well spacer and a thickness of the n-type doped AlGaN post-well spacer are smaller than a thickness of the AlGaN main well and a thickness of adjacent AlGaN barrier.

18. The multiple quantum well structure of claim 17 , wherein the n-type doped AlGaN prior-well spacer and the n-type doped AlGaN post-well spacer are Si-doped with a doping concentration of 1.0×10 18 -8.0×10 18 cm −3 , respectively, the AlGaN main well is undoped or Si-doped with a doping concentration less than 5.0×10 17 cm −3 , at least one of the AlGaN barriers is Si-doped with a doping concentration of 1.0×10 18 -8.0×10 18 cm −3 .

19. The multiple quantum well structure of claim 17 , wherein a thickness of the n-type doped AlGaN prior-well spacer and a thickness of the n-type doped AlGaN post-well spacer are in the range of 0.1 nm to 0.52 nm, respectively.

20. The multiple quantum well structure of claim 17 , wherein the Al-composition of the n-type doped AlGaN prior-well spacer and the Al-composition of the n-type doped AlGaN post-well spacer are higher than an Al-composition of adjacent AlGaN barrier.

21. The multiple quantum well structure of claim 17 , wherein the Al-composition of the n-type doped AlGaN prior-well spacer and the Al-composition of the n-type doped AlGaN post-well spacer are lower the Al-composition of the AlGaN main well.

22. The multiple quantum well structure of claim 17 , wherein the Al-composition of the n-type doped prior-well spacer is higher than an Al-composition of adjacent AlGaN barrier and the Al-composition of the n-type doped AlGaN post-well spacer is lower the Al-composition of the AlGaN mail well; or the Al-composition of the n-type doped AlGaN post-well spacer is higher than an Al-composition of the AlGaN barrier and the Al-composition of the AlGaN prior-well spacer is lower the Al-composition of the AlGaN main well.

23. A light emitting diode comprising:

an n-type AlGaN structure;

a p-type AlGaN structure; and

an active-region sandwiched between the n-type AlGaN structure and the p-type AlGaN structure,

wherein the active-region comprises the multiple quantum well structure of claim 1 .

Assignments (2)
SECURITY INTEREST Recorded Oct 13, 2021
From: BOLB INC.
To: TRINITY CAPITAL INC.
Reel/Frame 057783/0583 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 6, 2019
From: ZHANG, JIANPING; GAO, YING; ZHOU, LING
To: BOLB INC.
Reel/Frame 048524/0176 →
Continuity (1)
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