Light-driven synthesis of plasmonic nanoparticles and nanomaterials
View Patent ↗In one aspect, the present disclosure pertains to methods of making various noble metal nanoprisms, e.g., gold nanoprisms. In various aspects, the methods can comprise incubating, under dark conditions, a growth solution comprising: (a) a plurality of gold seed structures; (b) a gold precursor, and (c) a photocatalytic intermediary, such that during the incubating step multiply-twinned gold seed structures in the growth solution are preferentially enlarged. The disclosed methods can comprise separating the multiply-twinned gold seed structures from the growth solution based upon the size of the gold seed structures to produce an enriched growth solution. In some aspects, the methods comprise irradiating the enriched growth solution to produce the gold nanoprisms. In some aspects, the disclosed nanoprisms comprise silver.
1. A method of making noble metal nanoprisms, the method comprising:
incubating a growth solution comprising a plurality of seed structures under dark conditions, wherein the seed structures comprise multiply-twinned seed structures, wherein during the incubating step multiply-twinned seed structures in the growth solution are preferentially enlarged, and
separating the multiply-twinned seed structures from the solution based upon the size of the seed structures to produce an enriched growth solution, wherein the size of the seed structure is about 5 to 50 nm;
irradiating the solution comprising the multiply-twinned seed structures, a noble metal precursor, and a photocatalytic intermediary to produce the noble metal nanoprisms having an average thickness of about 10 nm to 30 nm, wherein the photocatalytic intermediary is positively charged.
2. The method of claim 1 , wherein the nanoprisms do not comprise silver.
3. The method of claim 1 , wherein the noble metal is selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium, platinum, gold, mercury, rhenium, copper, and a combination thereof.
4. The method of claim 1 , wherein the noble metal precursor comprises a salt of the noble metal.
5. The method of claim 1 , wherein the incubating step is performed at an elevated temperature from about 30° C. to about 40° C. and wherein the growth solution has a pH of about 3.0 to 6.0.
6. The method of claim 1 , wherein the photocatalytic intermediary comprises a γ-lactam ring.
7. The method of claim 1 , wherein the photocatalytic intermediary comprises n-methyl-2-pyrrolidone.
8. The method of claim 1 , wherein the photocatalytic intermediary comprises polyvinylpyrrolidone.
9. The method of claim 1 , wherein the growth solution further comprises sodium iodide.
10. The method of claim 1 , wherein the nanoprisms have a geometry selected from the group consisting of hexagonal nanoprisms and triangular nanoprisms.
11. The method of claim 1 , wherein the seed structures have an average size of about 5 nm to 15 nm.
12. The method of claim 1 , wherein the irradiating step comprises irradiating with light having a wavelength from about 500 nm to 600 nm, and wherein the nanoprisms have an average edge length of about 400 nm to 600 nm.
13. The method of claim 1 , wherein the irradiating step comprises irradiating with light having a wavelength from about 600 nm to 700 nm, and
wherein the nanoprisms have an average edge length of about 200 nm to 400 nm.
14. The method of claim 1 , wherein the nanoprisms are produced with a yield of at least 80%.
15. A method of making noble metal nanoprisms, the method comprising:
incubating a growth solution comprising a plurality of seed structures under dark conditions, wherein the seed structures comprise multiply-twinned seed structures, wherein during the incubating step multiply-twinned seed structures in the growth solution are preferentially enlarged, and
separating the multiply-twinned seed structures from the solution based upon the size of the seed structures to produce an enriched growth solution, wherein the size of the seed structure is about 5 to 50 nm;
irradiating the solution comprising the multiply-twinned seed structures, a noble metal precursor, and a photocatalytic intermediary to produce the noble metal nanoprisms, wherein the irradiating step comprises irradiating with light having a wavelength from about 500 nm to 600 nm, and
wherein the nanoprisms have an average edge length of about 400 nm to 600 nm.
16. The method of claim 15 , wherein the photocatalytic intermediary is positively charged.
17. The method of claim 15 , wherein the nanoprisms do not comprise silver.
18. The method of claim 15 , wherein the noble metal is selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium, platinum, gold, mercury, rhenium, copper, and a combination thereof.
19. The method of claim 15 , wherein the photocatalytic intermediary comprises a γ-lactam ring, n-methyl-2-pyrrolidone, or polyvinylpyrrolidone.
20. The method of claim 15 , wherein the growth solution further comprises sodium iodide.
21. A method of making noble metal nanoprisms, the method comprising:
incubating a growth solution comprising a plurality of seed structures under dark conditions, wherein the seed structures comprise multiply-twinned seed structures, wherein during the incubating step multiply-twinned seed structures in the growth solution are preferentially enlarged, and
separating the multiply-twinned seed structures from the solution based upon the size of the seed structures to produce an enriched growth solution, wherein the size of the seed structure is about 5 to 50 nm;
irradiating the solution comprising the multiply-twinned seed structures, a noble metal precursor, and a photocatalytic intermediary to produce the noble metal nanoprisms, wherein the irradiating step comprises irradiating with light having a wavelength from about 600 nm to 700 nm, and
wherein the nanoprisms have an average edge length of about 200 nm to 400 nm.
22. The method of claim 21 , wherein the noble metal is selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium, platinum, gold, mercury, rhenium, copper, and a combination thereof.
23. The method of claim 21 , wherein the nanoprisms have a geometry selected from the group consisting of hexagonal nanoprisms and triangular nanoprisms.
24. The method of claim 21 , wherein the seed structures have an average size of about 5 nm to 15 nm.
25. The method of claim 21 , wherein the photocatalytic intermediary comprises a γ-lactam ring, n-methyl-2-pyrrolidone, or polyvinylpyrrolidone.
26. A method of making noble metal nanoprisms, the method comprising:
incubating a growth solution comprising a plurality of seed structures under dark conditions, wherein the seed structures comprise multiply-twinned seed structures, wherein during the incubating step multiply-twinned seed structures in the growth solution are preferentially enlarged, wherein the growth solution has a pH of about 3.0 to 6.0, and
separating the multiply-twinned seed structures from the solution based upon the size of the seed structures to produce an enriched growth solution, wherein the size of the seed structure is about 5 to 50 nm;
irradiating the solution comprising the multiply-twinned seed structures, a noble metal precursor, and a photocatalytic intermediary to produce the noble metal nanoprisms, wherein the photocatalytic intermediary is positively charged.
27. The method of claim 26 , wherein the nanoprisms do not comprise silver.
28. The method of claim 26 , wherein the incubating step is performed at an elevated temperature from about 30° C. to about 40° C. and wherein the growth solution further comprises sodium iodide.
29. The method of claim 26 , wherein seed structures have an average size of about 5 nm to 15 nm, wherein the nanoprisms have an average thickness of about 10 nm to 30 nm.
30. The method of claim 26 , wherein the photocatalytic intermediary comprises a γ-lactam ring, n-methyl-2-pyrrolidone, or polyvinylpyrrolidone.
31. The method of claim 26 , wherein the nanoprisms have a geometry selected from the group consisting of hexagonal nanoprisms and triangular nanoprisms.
32. The method of claim 26 , wherein the irradiating step comprises irradiating with light having a wavelength from about 500 nm to 600 nm, and wherein the nanoprisms have an average edge length of about 400 nm to 600 nm.
33. The method of claim 26 , wherein the irradiating step comprises irradiating with light having a wavelength from about 600 nm to 700 nm, and wherein the nanoprisms have an average edge length of about 200 nm to 400 nm.