Pumpless electrochemical cell
An electrochemical cell and a method of operating the same. In accordance with various embodiments, the cell includes an anode, one or more cathodes opposite the anode defining a pathway there between. Chemical reactions allow the electrolyte to flow through the defined pathway without requiring a pumping device.
1. A metal-water electrochemical cell, the cell comprising:
a metal anode within an enclosure;
at least one cathode with a first surface that is adjacent to the anode and defines a pathway between the cathode and the anode;
a porous or prismatic media within the enclosure; and
an aqueous electrolyte that flows through the defined pathway without pumping, wherein:
the electrolyte flows by at least one of molecular diffusion, a temperature gradient, or a phase gradient and
the porous or prismatic media is configured to expand in a direction away from the anode and the at least one cathode.
2. The cell of claim 1 wherein the porous or prismatic media is in fluidic contact with the defined pathway.
3. The cell of claim 1 wherein the porous or prismatic media is at least one of open cell foam, a repeating structure, a functionalized surface, and an adjacent non-porous media.
4. The cell of claim 1 wherein at least one of the cell and the porous or prismatic media is in an initial compressed state and configured to subsequently expand.
5. The cell of claim 1 wherein the electrolyte includes potassium hydroxide.
6. The cell of claim 5 further comprising:
at least one outlet in the enclosure configured to release the hydrogen from the enclosure; and
at least one inlet in the enclosure configured to allow water to enter the enclosure.
7. The cell of claim 6 wherein the dimensions of the at least one inlet are selected such that water enters the enclosure at a rate that at least partially offsets diffusion of the electrolyte out of the enclosure.
8. The cell of claim 6 wherein the at least one inlet is in a spiral configuration.
9. The cell of claim 6 further comprising at least one of an electric valve device, a mechanical valve device, and a semi-permeable membrane to control the release of hydrogen from the enclosure.
10. The cell of claim 1 wherein the electrolyte flows by at least one of molecular diffusion or a temperature gradient.
11. A method of operating a metal-water electrochemical cell, the method comprising:
providing a metal anode in an enclosure;
providing at least one cathode in the enclosure, wherein the at least one cathode includes a first surface that is adjacent to the anode and defines a pathway between the cathode and the anode; and
flowing an aqueous electrolyte in the enclosure through the pathway without pumping, wherein the electrolyte flows by at least one of molecular diffusion, a temperature gradient, or a phase gradient.
12. The method of claim 11 further comprising providing a porous or prismatic media in fluidic contact with the defined pathway configured to expand in a direction away from the anode and the at least one cathode.
13. The method of claim 12 wherein providing the porous or prismatic media includes providing at least one of an open cell foam, a repeating structure, a functionalized surface, and an adjacent non-porous media.
14. The method of claim 12 further comprising:
providing a compressed porous or prismatic media; and
expanding at least one of the cell and the porous or prismatic media.
15. The method of claim 11 wherein the electrolyte includes potassium hydroxide.
16. The method of claim 15 further comprising:
providing at least one outlet in the enclosure that is configured to release hydrogen from the enclosure; and
providing at least one inlet in the enclosure that is configured to allow water to enter the enclosure.
17. The method of claim 16 wherein providing the at least one inlet includes providing an inlet with dimensions such that water enters the enclosure at a rate that at least partially offsets diffusion of the electrolyte out of the enclosure.
18. The method of claim 16 wherein providing the at least one inlet includes providing an inlet that is in a spiral configuration.
19. The method of claim 16 further comprising providing at least one of an electric valve device, a mechanical valve device, and a semi-permeable membrane to control the release of hydrogen from the enclosure.
20. The method of claim 11 wherein the electrolyte flows by at least one of molecular diffusion or a temperature gradient.