Electrostatic ink composition
Described herein is a liquid electrostatic ink composition. The composition may comprise: a. a carrier liquid; and b. chargeable particles suspended in the carrier liquid, wherein the chargeable particles comprise a thermoplastic resin formed from the reaction of a first resin and a second resin, wherein i. the first resin comprises a polymer having acidic side groups; and ii. the second resin comprises an epoxy resin component and an elastomeric component, wherein the epoxy resin component has one or more epoxide groups per molecule.
1. A liquid electrostatic ink composition comprising:
a. a carrier liquid; and
b. chargeable particles suspended in the carrier liquid, wherein the chargeable particles comprise a thermoplastic resin formed from the reaction of a first resin and a second resin, wherein
i. the first resin comprises a polymer having acidic side groups; and
ii. the second resin comprises an epoxy resin component and an elastomeric component, wherein the epoxy resin component has one or more epoxide groups per molecule.
2. The liquid electrostatic ink composition according to claim 1 , wherein the second resin comprises 1 wt % to 30 wt % elastomeric component.
3. The liquid electrostatic ink composition according to claim 1 , wherein the first resin constitutes 60 wt % or more of the thermoplastic resin.
4. The liquid electrostatic ink composition according to claim 1 , wherein the epoxy resin component comprises a copolymer of a polyhydric alcohol and an epoxide-containing monomer.
5. The liquid electrostatic ink composition according to claim 1 , wherein the epoxy resin component comprises a copolymer of a bisphenol-containing monomer and an epoxide-containing monomer.
6. The liquid electrostatic ink composition according to claim 1 , wherein the epoxy resin component is selected from bisphenol A epoxy resin or bisphenol F epoxy resin.
7. The liquid electrostatic ink composition according to claim 1 , wherein the elastomeric component of the second resin is a thermoplastic polyurethane or a butadiene-acrylonitrile elastomer.
8. The liquid electrostatic ink composition according to claim 1 , wherein the chargeable particles comprise a colourant.
9. A method for producing a liquid electrostatic ink composition, the method comprising:
suspending in a carrier liquid chargeable particles comprising a thermoplastic resin formed from the reaction of a first resin and a second resin, wherein
the first resin comprises a polymer having acidic side groups; and
the second resin comprises an epoxy resin component and an elastomeric component, wherein the epoxy resin component has one or more epoxide groups per molecule.
10. The method according to claim 9 , wherein the first resin and the second resin are reacted in the carrier liquid.
11. The method according to claim 9 , wherein a colourant is added to the suspension of the thermoplastic resin in the carrier liquid.
12. The method according to claim 10 , wherein the method comprises first combining the first resin with the carrier liquid and subsequently adding the second resin.
13. The method according to claim 10 , wherein the method comprises combining the first resin and the carrier liquid and heating to a temperature above the melting point of the first resin and subsequently adding the second resin.
14. The method according to claim 12 , wherein the second resin is heated to at least 30° C. before it is added to the first resin and the carrier liquid.
15. A method of producing a printed article, the method comprising applying an electrostatic ink composition to a substrate with a liquid electrostatic printer, wherein the electrostatic ink composition comprises
a thermoplastic resin formed from the reaction of a first resin and a second resin, wherein
i. the first resin comprises a polymer having acidic side groups; and
ii. the second resin comprises an epoxy resin component and an elastomeric component, wherein the epoxy resin has one or more epoxide groups per molecule.
16. The method according to claim 15 , wherein the second resin comprises 1 wt % to 30 wt % elastomeric component.
17. The method of claim 1 , wherein the first resin constitutes 60 wt % or more of the thermoplastic resin.
18. The method according to claim 15 , wherein the epoxy resin component comprises a copolymer of a polyhydric alcohol and an epoxide-containing monomer.
19. The method according to claim 15 , wherein the epoxy resin component comprises a copolymer of a bisphenol-containing monomer and an epoxide-containing monomer.
20. The method according to claim 15 , wherein the elastomeric component of the second resin is a thermoplastic polyurethane or a butadiene-acrylonitrile elastomer.