Method for producing water-absorbing agent
[Object] To provide a method for efficiently producing a water-absorbing agent having excellent physical properties. [Solution] The method for producing a water-absorbing agent includes a drying step of drying a particulate crosslinked hydrogel polymer containing a drying aid. The drying aid is (a) a compound having a betaine structure and having a long-chain alkyl group having 8 or more carbon atoms, one quaternary nitrogen, and one acid group within a molecule thereof and/or (b) a compound having a long-chain alkyl group having 8 or more carbon atoms, one tertiary nitrogen, and one or more acid groups within a molecule thereof. An addition amount of the drying aid with respect to a gel solid content of the particulate crosslinked hydrogel polymer is 0.001% by mass to 0.5% by mass. In this production method, surface-crosslinking is performed on water-absorbent resin powder obtained through the drying step.
1. A method for producing a water-absorbing agent, the method comprising;
a polymerization step of polymerizing a monomer aqueous solution to obtain a crosslinked hydrogel polymer; and
a drying step of obtaining a particulate dried polymer by drying a particulate crosslinked hydrogel polymer containing a drying aid that is obtained by adding the drying aid to the crosslinked hydrogel polymer after the polymerization step;
the drying step is a material stirring type drying step where adjacent particles are sequentially changed and come into contact with another particle during the stirring type drying step;
the material stirring type drying step is performed by a stirring type drying device,
the stirring type drying device comprising a rotating stirring board and/or a rotating cylinder,
wherein the particulate crosslinked hydrogel polymer is stirred by the rotating stirring board and/or the particulate crosslinked hydrogel polymer is placed in the rotating cylinder and stirred during the material stirring type drying step,
the drying aid is selected from the group consisting of compounds represented by general formulas (1) to (3) below,
wherein, in formulas (1) and (2), R1 is a saturated alkyl group having 8 to 20 carbon atoms or an alkyl group having a hydroxyl group and having 8 to 20 carbon atoms, and “m” is an integer not less than 1 and not greater than 6,
in formula (1), X 1 is NH, NR 4 having an alkyl group R 4 having 1 to 4 carbon atoms, O, or S, “x” is 0 or 1, R 2 and R 3 are each independently an alkyl group having 1 to 4 carbon atoms or an alkyl group having a hydroxyl group at an end thereof and having 1 to 4 carbon atoms, “y” is 0 or 1, Y is COO, SO 3, OPO(OR 5 )O, or P(O)(OR 5 )O, and R 5 is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms,
in formula (2), X 2 and X 3 are each independently a hydrogen atom, an alkali metal, or ammonium (excluding the case where X 2 and X 3 are each a hydrogen atom), and
in formulas (1) and (3), “n” is an integer not less than 1 and not greater than 6,
an addition amount of the drying aid with respect to a gel solid content of the particulate crosslinked hydrogel polymer is 0.001% by mass to 0.5% by mass, and
surface-crosslinking is performed on water-absorbent resin powder obtained through the drying step.
2. The method according to claim 1 , wherein the particulate crosslinked hydrogel polymer to be supplied in the drying step has a particle diameter of not less than 25 μm and not greater than 2000 μm.
3. The method according to claim 1 , further comprising a gel pulverization step of performing gel pulverization on the crosslinked hydrogel polymer before the drying step, wherein
the drying aid is added after the gel pulverization step.
4. The method according to claim 1 , wherein the particulate crosslinked hydrogel polymer to be supplied in the drying step has a polymerization ratio of not less than 70% by mass and has gel Ext of not greater than 20% by mass.
5. The method according to claim 1 , wherein the particulate crosslinked hydrogel polymer to be supplied in the drying step has a particle diameter of not less than 25 μm and not greater than 2000 μm.
6. The method according to claim 1 , further comprising a gel pulverization step of performing gel pulverization on the crosslinked hydrogel polymer before the drying step, wherein
the drying aid is added after the gel pulverization step.
7. The method according to claim 1 , wherein the particulate crosslinked hydrogel polymer to be supplied in the drying step has a polymerization ratio of not less than 70% by mass and has gel Ext of not greater than 20% by mass.
8. The method of claim 1 , wherein the stirring type drying device comprises the rotating stirring board and the particulate crosslinked hydrogel polymer is stirred by the rotating stirring board.
9. The method of claim 1 , wherein the stirring type drying device comprises the rotating cylinder and the particulate crosslinked hydrogel polymer is placed in the rotating cylinder, and stirred by rotation of the rotating cylinder.
10. The method of claim 8 , wherein the particulate crosslinked hydrogel polymer flows through the stirring type drying device by the rotating stirring board.
11. The method of claim 9 , wherein the particulate crosslinked hydrogel polymer flows through the rotating cylinder of the stirring type drying device by rotation of the cylinder.