Exterior material for power storage device and power storage device
Provided is a packaging material for a power storage device capable of securing excellent formability without causing pinholes and/or cracks even when deep depth forming is performed and also capable of sufficiently preventing delamination even when deep depth forming is performed or even when it is used under severe environments, such as, e.g., high temperature and high humidity. [Solving means] The packaging material for a power storage device has a configuration including a heat resistant resin layer 2 serving as an outer layer, a heat fusible resin layer 3 serving as an inner layer, and a metal foil layer 4 disposed between both the two layers. The heat resistant resin layer 2 is composed of a heat resistant resin film with a hot water shrinkage percentage of 1.5% to 12%. The heat resistant resin layer 2 and the metal foil layer 4 are bonded via an outer adhesive layer 5 composed of a cured film of an electron beam curable resin composition.
1. A packaging material for a power storage device comprising:
a heat resistant resin layer serving as an outer layer wherein the heat resistant resin layer is a biaxially stretched polyamide film;
a heat fusible resin layer serving as an inner layer; and
a metal foil layer disposed between both the layers,
wherein the heat resistant resin layer is a heat resistant resin film with a hot water shrinkage percentage of 1.5% to 12%,
wherein the heat resistant resin layer and the metal foil layer are bonded via an outer adhesive layer, which is a cured film of an ultraviolet light curable resin composition,
wherein the ultraviolet light curable resin composition contains an acrylate resin and a photo-radical polymerization initiator, a silane coupling agent, an acid anhydride having a carbon-carbon double bond, a phosphoric acid-containing (meth) acrylate, one or more resins selected from the group consisting of an epoxy resin, an oxetane resin, and a vinyl ether resin, and a photo-cationic polymerization initiator,
wherein in the ultraviolet light curable resin composition, a content rate of the acrylate resin is 70 mass % to 98 mass %, a content rate of the silane coupling agent is 0.1 mass % to 5 mass %, a content rate of the acid anhydride is 0.1 mass % to 5 mass %, a content rate of phosphoric acid-containing (meth) acrylate is 0.1 mass % to 10 mass %, a content rate of the photo-radical polymerization initiator is 0.1 mass % to 5 mass %, a content rate of one or more resins selected from the group consisting of an epoxy resin, an oxetane resin, and a vinyl ether resin is 1 mass % to 20 mass %, and a content rate of the photo-cationic polymerization initiator is 0.5 mass % to 5 mass %,
wherein a Young's modulus of the cured film is 90 MPa to 400 MPa, and
wherein an adhesive strengthening layer is disposed between the heat resistant resin layer and the outer adhesive layer.
2. A packaging case for a power storage device, wherein the packaging case is made of a formed product of the packaging material as recited in claim 1 .
3. A power storage device comprising:
a power storage device main body; and
a packaging member, which is the packaging case as recited in claim 2 ,
wherein the power storage device main body is packaged with the packaging member.
4. A power storage device comprising:
a power storage device main body; and
a packaging member, which is the packaging material as recited in claim 1 ,
wherein the power storage device main body is packaged with the packaging member.
5. A packaging material for a power storage device comprising:
a heat resistant resin layer serving as an outer layer;
a heat fusible resin layer serving as an inner layer; and
a metal foil layer disposed between both the layers wherein the metal foil layer is aluminum foil and wherein a chemical conversion coating has been formed on both sides of the aluminum foil,
wherein the heat resistant resin layer is a heat resistant resin film with a hot water shrinkage percentage of 1.5% to 12%,
wherein the heat resistant resin layer and the metal foil layer are bonded via an outer adhesive layer, which is a cured film of an ultraviolet light curable resin composition,
wherein the ultraviolet light curable resin composition contains an acrylate resin and a photo-radical polymerization initiator, a silane coupling agent, an acid anhydride having a carbon-carbon double bond, a phosphoric acid-containing (meth) acrylate, one or more resins selected from the group consisting of an epoxy resin, an oxetane resin, and a vinyl ether resin, and a photo-cationic polymerization initiator,
wherein in the ultraviolet light curable resin composition, a content rate of the acrylate resin is 70 mass % to 98 mass %, a content rate of the silane coupling agent is 0.1 mass % to 5 mass %, a content rate of the acid anhydride is 0.1 mass % to 5 mass %, a content rate of phosphoric acid-containing (meth) acrylate is 0.1 mass % to 10 mass %, a content rate of the photo-radical polymerization initiator is 0.1 mass % to 5 mass %, a content rate of one or more resins selected from the group consisting of an epoxy resin, an oxetane resin, and a vinyl ether resin is 1 mass % to 20 mass %, and a content rate of the photo-cationic polymerization initiator is 0.5 mass % to 5 mass %,
wherein a Young's modulus of the cured film is 90 MPa to 400 MPa, and
wherein an adhesive strengthening layer is disposed between the heat resistant resin layer and the outer adhesive layer.
6. A packaging case for a power storage device, wherein the packaging case is made of a formed product of the packaging material as recited in claim 1 .
7. A power storage device comprising:
a power storage device main body; and
a packaging member, which is the packaging case as recited in claim 2 ,
wherein the power storage device main body is packaged with the packaging member.
8. A power storage device comprising:
a power storage device main body; and
a packaging member, which is the packaging material as recited in claim 1 ,
wherein the power storage device main body is packaged with the packaging member.