Film and layered body having specified thickness ratios of thermoplastic layers
The present invention is a film having at least one reflection band in which the reflectance is 30% or greater continuously in at least a 100-nm range in a wavelength range of 1200-1800 nm when light is incident from at least one side, the mean transmittance in a wavelength range of 430-600 nm is 70% or greater, and the average value of the axial rigidity of the film in the principal orientation axis direction of the film and in the direction orthogonal thereto is 45 N/m or less.
1. A film having at least one reflection band where a reflectance of 30% or more is maintained over a continuous part covering 100 nm or more in a wavelength range of 1,200 to 1,800 nm for incident light entering at least from one side,
wherein the film has an average transmittance of 70% or more over a wavelength range of 430 to 600 nm, and has an average axial rigidity between the main orientation axis direction of the film and the direction perpendicular thereto of 10 kN/m or more and 45 kN/m or less, wherein:
the film has a lamination unit 1 in which layers (A-layers) containing a thermoplastic resin A as a primary component and layers (B-layers) containing a thermoplastic resin B as a primary component are stacked alternately to meet the requirement (i) described below; and
the film has a lamination unit 2 in which layers (C-layers) containing a thermoplastic resin C as a primary component and layers (D-layers) containing a thermoplastic resin D as a primary component are stacked alternately to meet the requirement (ii) described below:
(i) any A-layer and B-layer located adjacent to each other have a thickness ratio (thickness of A-layer/thickness of B-layer) of 0.7 or more and 1.4 or less;
(ii) compared to the thinnest layer (having a thickness ratio of 1) of three layers located adjacent to each other, one of the other two layers has a thickness ratio of 1.0 or more and 1.4 or less whereas the remaining layer has a thickness ratio of 5 or more and 9 or less.
2. The film as set forth in claim 1 , wherein the average transmittance in a wavelength range of 400 to 800 nm is 80% or more at least for incident light coming through either surface.
3. The film as set forth in claim 1 , wherein the total thickness d1 of the lamination unit 1 is 5 μm or more.
4. The film as set forth in claim 1 , wherein the total thickness d2 of the lamination unit 2 is 20 μm or more.
5. The film as set forth in claim 1 , wherein the thermoplastic resins A and C are crystalline resins and the thermoplastic resins B and D are amorphous resins.
6. The film as set forth in claim 1 , wherein in either the lamination unit 1 or the lamination unit 2 , or both the lamination unit 1 and the lamination unit 2 , the total layer thickness of continuously located six layers has a layer thickness distribution in the thickness direction of the film.
7. The film as set forth in claim 1 , having a region in which the total layer thickness of mutually adjacent six layers in the lamination unit 1 decreases gradually from either surface toward the central portion.
8. The film as set forth in claim 1 , having a region in which the total layer thickness of mutually adjacent six layers in the lamination unit 2 decreases gradually from either surface toward the central portion.
9. The film as set forth in claim 1 , having a region in which the total layer thickness of mutually adjacent six layers in the lamination unit 1 decreases gradually from either surface toward the central portion, and having a region in which the total layer thickness of mutually adjacent six layers in the lamination unit 2 decreases gradually from either surface toward the central portion.
10. The film as set forth in claim 1 , containing a layer having a layer thickness of 1 μm or more.
11. The film as set forth in claim 1 , wherein the total thickness d1 (μm) of the lamination unit 1 and the total thickness d2 (μm) of the lamination unit 2 meet the equation (1) or (2) given below:
0.4≤ d 1/( d 1+ d 2)<1 equation (1)
0.01≤ d 1/( d 1+ d 2)<0.4 equation (2).
12. The film as set forth in claim 1 , wherein the film thickness is 100 μm or less.
13. The film as set forth in claim 10 , wherein the average reflectance in the wavelength range of 900 to 1,400 nm is 70% or more at least for incident light coming through either surface.
14. The film as set forth in claim 1 , wherein the average reflectance in the wavelength range of 900 nm to 1,800 nm is 70% or more at least for incident light coming through either surface.
15. A layered body containing the film as set forth in claim 1 , a hard coat layer located in close proximity to at least either side thereof, and a sticking layer attached on the other side thereof.
16. A layered body having the film as set forth in claim 1 and a hard coat layer located in close proximity to at least either side thereof and having visible light transmittance of 70% or more and total solar energy transmittance of 50% or less as specified in ISO9050, wherein the hard coat layer contains a heat ray absorbent.
17. The layered body as set forth in claim 16 , wherein the heat ray absorbent contains a tungsten oxide component.
18. The layered body as set forth in claim 16 , wherein the hard coat layer has a thickness of 0.1 μm or more and 50 μm or less.