Steel material for hot stamping, hot stamping process and hot stamped component
The present invention relates to a steel material for hot stamping with ultra-fine grains and a process of making the same, a hot stamping process and a hot stamped component. The steel material for hot stamping comprises the following components by weight: 0.27 to 0.40% of C; 0.2 to 3.0% of Mn; 0.11 to 0.4% of V; 0 to 0.8% of Si; 0 to 0.5% of Al; 0 to 2% of Cr; 0 to 0.15% of Ti; 0 to 0.15% of Nb; 0 to 0.004% B; a total of less than 2% of Mo, Ni, Cu and other alloying elements that are beneficial to improving the hardenability, and other impurity elements. After hot stamping or equivalent heat treatment, the steel material or the formed component of the present invention can achieve a yield strength of 1300 MPa to 1700 MPa, a tensile strength of 1800 to 2200 MPa, and an elongation of 6 to 9% after direct hot stamping quenching and without tempering, which properties cannot be achieved by a material with a composition in the prior art in the situation of direct quenching (no tempering). After the tempering treatment of the present invention, preferably 1500 MPa-1900 MPa-8%, and 1600 MPa-2100 MPa-7% can be reached.
1. A hot stamped component produced with a steel material for hot stamping, wherein the steel material for hot stamping comprises the following components by weight:
iron;
0.27 to 0.40% of C;
0.2 to 3.0% of Mn;
0.11 to 0.4% of V;
0 to 0.8% of Si;
0 to 0.5% of Al;
0 to 2% of Cr;
0 to 0.15% of Ti;
0 to 0.15 of Nb;
0 to 0.004% of B;
a total of less than 2% of Mo, Ni, Cu; and
inevitable impurity elements,
after a hot stamping process, the hot stamped component achieves a yield strength of 1300 MPa to 1700 MPa, a tensile strength of 1800 to 2200 MPa, and an elongation of 6 to 9% without tempering;
wherein the hot stamped component comprises precipitated carbide of VC and/or composite carbide of V with Ti, Nb within austenite grains, a carbide size within the austenite grains being 0.1 to 20 nm, a total volume fraction of carbide of VC and/or composite carbide of V with Ti, Nb in the hot stamped component is more than 0.1%.
2. The hot stamped component according to claim 1 , wherein the hot stamped component is austenitized at a temperature range of 800 to 920° C. during a hot stamping process, and has a composite carbide of VC and/or V with Ti, Nb at an austenite grain boundary during an austenitizing process.
3. The hot stamped component according to claim 2 , wherein in the austenitizing process of the hot stamped component, a precipitated particle size of the composited carbide of VC and/or V with Ti, Nb at the austenite grain boundary is from 1 to 80 nm.
4. The hot stamped component according to claim 2 , wherein in the hot stamping process, the hot stamped component precipitates a certain amount of carbide of VC and/or composite carbide of V with Ti, Nb within the austenite grains precipitating during the austenitizing process or during a cooling process after austenitizing, and a carbide size within the austenite grains is 0.1 to 20 nm.
5. The hot stamped component according claim 2 , wherein after the hot stamping, the hot stamped component is subjected to a tempering heat treatment and achieves a yield strength of 1350 to 1800 MPa, a tensile strength of 1700 to 2150 MPa, and an elongation of 7 to 10% after tempering heat treatment.
6. The hot stamped component according to claim 1 , wherein the steel material for hot stamping includes a hot-rolled steel sheet, a hot-rolled pickled steel sheet, a cold-rolled steel sheet, or a steel sheet with a coating layer.
7. The hot stamped component according to claim 6 , wherein the steel sheet with a coating layer is a zinc-coated steel sheet which is a hot-rolled steel sheet or a cold-rolled steel sheet on which a metal zinc layer is formed, wherein the zinc-coated steel sheet includes at least one selected from hot-dip galvanizing, galvanizing annealing, zinc plating, or zinc-iron plating.
8. The hot stamped component according to claim 6 , wherein the steel sheet with a coating layer is a hot-rolled steel sheet or a cold-rolled steel sheet on which an aluminum-silicon layer is formed, or a steel sheet with an organic coating layer.
9. A hot stamping process, comprising the following procedures:
(a) steel material austenitizing: providing a steel material for hot stamping according to claim 1 or a preformed member thereof, heating it to 800 to 920° C. and maintaining the temperature for 1 to 10000 s;
(b) steel material transferring: transferring the above heated steel material to a die for hot stamping while ensuring that the steel material has a temperature of above 550° C. when being transferred to the die;
(c) hot stamping: setting a reasonable press tonnage according to the above-mentioned steel blank size, the stamping pressure being 1 to 40 MPa, determining a dwell time according to a thickness of the plate, which is controlled at 4 to 40 s, and controlling a die surface temperature below 200° C. through a cooling system of the die, so that the steel material in the die is rapidly cooled to below 250° C. at an average cooling rate of not less than 10° C./s.
10. The hot stamping process according to claim 9 , wherein a heating method in the procedure (a) comprises a roller hearth furnace, a chamber furnace, induction heating, and resistance heating.
11. A tempering process, comprising the steps of:
(a) obtaining a formed component by the hot stamping process of claim 9 ;
(b) heating the formed component to 150 to 200° C. and maintaining the temperature for 10 to 40 minutes by the baking process during carbody assembly; or heating the formed component to 150 to 280° C. at a heating rate of 0.001 to 100° C./s and maintaining the temperature for 0.5 to 120 minutes, and then cooling it in any way.
12. The hot stamped component according to claim 1 , wherein properties thereof reach a yield strength of 1300 MPa to 1800 MPa, a tensile strength of 1700 to 2150 MPa, and an elongation of 7 to 10%.
13. The hot stamped component according to claim 1 , wherein the hot stamped component can be used for automotive high-strength members including an A-pillar, a B-pillar, a bumper, a roof frame, an underbody frame, and a door bumper bar of an automobile.
14. The hot stamped component according to claim 1 , wherein the hot stamped component is made of a blank of steel for hot stamping having a thickness of 1.2-1.8 mm.