Adhesive dual-component composition based on polyurethane

1. A two-component polyurethane-based adhesive composition comprising an —NCO component and an —OH component, wherein:

the —NCO component is a composition comprising:

A) at least one polyurethane prepolymer comprising at least two NCO end groups obtained by a polyaddition reaction:

of at least one aliphatic polyisocyanate selected from the group consisting of aliphatic diisocyanate monomer(s) and mixtures of the at least one aliphatic diisocyanate monomer(s) with at least one triisocyanate based on XDI, and

of at least one polyester diol,

B) at least one triisocyanate based on XDI, and

C) at least one organic solvent in an amount ranging from 5% to 55% by weight, and

the —OH component is a composition comprising at least one polyester polyol, wherein the at least one triisocyanate based on XDI is selected from the group consisting of XDI isocyanurates, XDI biurets, adducts of XDI and of triols, and their mixtures, wherein the molar ratio of the number of NCO groups present in the total amount of the aliphatic diisocyanate monomer(s) used to synthesize the at least one polyurethane prepolymer to the number of OH groups present in the total amount of the at least one polyester diol used to synthesize the at least one polyurethane prepolymer, denoted r 1 , ranges from 1.0 to 2.2, and wherein the at least one polyester diol and the at least one polyester polyol exhibits a hydroxyl number (OHN) ranging from 28 to 112 mg KOH/g.

2. The two-component polyurethane-based adhesive composition as claimed in claim 1 , wherein the aliphatic diisocyanate monomer(s) is (are) selected from the group consisting of:

xylylene diisocyanate (XDI),

aliphatic diisocyanate monomers other than XDI, and

mixtures of aliphatic diisocyanate monomers other than XDI and of XDI comprising at least 50% by weight of XDI, with respect to the weight of said mixtures.

3. The two-component polyurethane-based adhesive composition as claimed in claim 1 , wherein the aliphatic diisocyanate monomer(s) is (are) selected from the group consisting of:

Hexamethylene diisocyanate (HDI),

Heptane diisocyanate,

Octane diisocyanate,

Nonane diisocyanate,

Decane diisocyanate,

Undecane diisocyanate,

Dodecane diisocyanate,

HDI allophanate,

Methylenebis(4-cyclohexyl isocyanate) (HMDI),

Isophorone diisocyanate (IPDI),

Norbornane diisocyanate,

Norbornene diisocyanate,

1,4-Cyclohexane diisocyanate (CHDI),

Methylcyclohexane diisocyanate,

Ethylcyclohexane diisocyanate,

Propylcyclohexane diisocyanate,

Methyldiethylcyclohexane diisocyanate,

Cyclohexanedimethylene diisocyanate,

1,5-Diisocyanato-2-methylpentane (MPDI),

1,6-Diisocyanato-2,4,4-trimethylhexane,

1,6-Diisocyanato-2,2,4-trimethylhexane (TMDI),

4-Isocyanatomethyl-1,8-octane diisocyanate (TIN),

2,5-Bis(isocyanatomethyl)bicyclo[2.2.1]heptane (2,5-NBDI),

2,6-Bis(isocyanatomethyl)bicyclo[2.2.1]heptane (2,6-NBDI),

1,3-Bis(isocyanatomethyl)cyclohexane (1,3-H6-XDI),

1,4-Bis(isocyanatomethyl)cyclohexane (1,4-H6-XDI),

Xylylene diisocyanate;

and their mixtures.

4. The two-component polyurethane-based adhesive composition as claimed in claim 1 , wherein the aliphatic diisocyanate monomer(s) comprises XDI or methylenebis(4-cyclohexyl isocyanate) (HMDI).

5. The two-component polyurethane-based adhesive composition as claimed in claim 1 , wherein the molar ratio of the number of NCO groups present in the total amount of the aliphatic diisocyanate monomer(s) used to synthesize the at least one polyurethane prepolymer to the number of NCO groups present in the total amount of the at least one triisocyanate based on XDI, denoted r 2 , ranges from 3 to 11.

6. The two-component polyurethane-based adhesive composition as claimed in claim 1 , wherein the —OH component is the composition comprising a polyester diol or a mixture of polyester diols.

7. The two-component polyurethane-based adhesive composition as claimed in claim 1 , wherein the content of NCO groups in the —NCO component ranges from 40 to 125 milliequivalents of NCO groups per 100 grams of solids content of the —NCO component.

8. The two-component polyurethane-based adhesive composition as claimed in claim 1 , wherein the content of OH groups ranges from 70 to 100 milliequivalents of OH groups per 100 grams of solids content of the —OH component.

9. The two-component polyurethane-based adhesive composition as claimed in claim 1 , wherein the —NCO component and the —OH component, which are intended to be mixed, are in amounts such that the molar ratio of the number of NCO groups present in the total amount of the —NCO component to the number of OH groups present in the total amount of the —OH component, denoted r 3 , ranges from 2 to 15.

10. A multilayer structure comprising at least two layers of material bonded together by an adhesive layer, wherein said adhesive layer comprises the two-component polyurethane-based adhesive composition as defined in claim 1 , obtained by mixing the —NCO component and the —OH component in the crosslinked state.

11. The multilayer structure as claimed in claim 10 , comprising at least one layer of aluminum-based material.

12. A process for manufacturing of the multilayer structure as defined in claim 10 , comprising the following stages:

(i) mixing the —NCO component and the —OH component to form a mixture, then

(ii) coating said mixture over a surface of a first layer of material to form a coated surface, then

(iii) laminating a surface of a second layer of material over said coated surface, then

(iv) crosslinking said mixture.

13. The process as claimed in claim 12 , wherein the mixing of the —NCO component and of the —OH component comprises at least one solvent and in which the process additionally comprises a stage of evaporation of the at least one solvent.