Dielectric thin film-applied substrate and optical modulation element using the same
A dielectric thin film-applied substrate that suppresses occurrence of cracks when the film thickness of the lithium niobate film is equal to or larger than 1 μm. The dielectric thin film-applied substrate includes a single crystal substrate and a dielectric thin film made of c-axis oriented lithium niobate epitaxially formed on a main surface of the single crystal substrate. The dielectric thin film has a twin crystal structure including first and second crystals 180° apart, centered on the c-axis. In pole figure measurement by X-ray diffraction, the ratio between a first diffraction intensity corresponding to the first crystal and a second diffraction intensity corresponding to the second crystal is equal to or higher than 0.5 and equal to or lower than 2.0, which alleviates distortions accumulated inside the lithium niobate film and supresses occurrences of cracks accompanying increases in the film thickness.
1. A dielectric thin film-applied substrate comprising:
a single crystal substrate; and
a dielectric thin film which is made of c-axis oriented lithium niobate and epitaxially formed on a main surface of the single crystal substrate, wherein
the film thickness of the dielectric thin film is at least 1000 nm,
the dielectric thin film has a twin crystal structure including a first crystal and a second crystal existing at a position obtained by rotating the first crystal 180° centered on the c-axis, and
in pole figure measurement by an X-ray diffraction method, the ratio between a first diffraction intensity corresponding to the first crystal and a second diffraction intensity corresponding to the second crystal is equal to or higher than 0.5 and equal to or lower than 2.0.
2. The dielectric thin film-applied substrate as claimed in claim 1 , wherein in the pole figure measurement by the X-ray diffraction method, the ratio between the first diffraction intensity and the second diffraction intensity is equal to or higher than 0.8 and equal to or lower than 1.25.
3. The dielectric thin film-applied substrate as claimed in claim 1 , wherein the single crystal substrate is a sapphire single crystal substrate whose main surface is a c-surface.
4. The dielectric thin film-applied substrate as claimed in claim 1 , wherein the full width at half maximum of the rocking curve of lithium niobate (006) reflection measured by the X-ray diffraction method is equal to or higher than 0.3° and equal to or lower than 0.6°.
5. The dielectric thin film-applied substrate as claimed in claim 1 , wherein a grain boundary does not exist between the first and second crystals.
6. The dielectric thin film-applied substrate as claimed in claim 1 , wherein the film thickness of the lithium niobate film is at least 1300 nm.
7. An optical modulation element using the dielectric thin film-applied substrate as claimed in claim 1 .
8. A dielectric thin film-applied substrate comprising:
a sapphire single crystal substrate; and
a dielectric thin film which is made of c-axis oriented lithium niobate and epitaxially formed on a main surface of the sapphire single crystal substrate, wherein
the film thickness of the dielectric thin film is equal to or larger than 1000 nm and the percentage of regions where a crack having a length of 10 μm or larger is present to 30% or less,
the dielectric thin film has a twin crystal structure including a first crystal and a second crystal existing at a position obtained by rotating the first crystal 180° centered on the c-axis.
9. The dielectric thin film-applied substrate as claimed in claim 8 , wherein a crack having a length greater than or equal to 10 μm does not exist in the dielectric thin film.