Paperless transfer printing method
View Patent ↗A paperless transfer printing method includes the following steps: (a) printing, by a printing machine, aqueous ink onto a transfer printing temporary carrier in a set pattern, wherein a surface of the transfer printing temporary carrier is made of an elastic polymer material and a surface tension of the aqueous ink is less than the critical surface tension of the transfer printing temporary carrier; (b) drying the to-be-transferred pattern on the transfer printing temporary carrier; (c) wetting the transfer printing temporary carrier by using an aqueous surface tension increasing liquid; and (d) separating the aqueous solution or the aqueous dispersion liquid from the transfer printing temporary carrier at a tight-contact position between the transfer printing temporary carrier and the fabric, so that an aqueous ink dye is transferred onto the fiber of the fabric.
1. A paperless transfer printing method, comprising:
(a) printing, by a printing machine, aqueous ink onto a transfer printing temporary carrier in a set pattern, wherein a surface of the transfer printing temporary carrier is made of an elastic polymer material, a critical surface tension of the surface of the transfer printing temporary carrier is between 25 mN/m and 45 mN/m, and a surface tension of the aqueous ink is less than the critical surface tension of the transfer printing temporary carrier;
(b) drying the to-be-transferred pattern on the transfer printing temporary carrier;
(c) wetting the transfer printing temporary carrier by using an aqueous surface tension increasing liquid, so that when the transfer printing temporary carrier is in tight contact with a fabric in a transfer printing device to transfer a pattern, the aqueous ink printed on the transfer printing temporary carrier is dissolved or dispersed into the aqueous surface tension increasing liquid to form an aqueous solution or an aqueous dispersion liquid, wherein a surface tension of the aqueous solution or the aqueous dispersion liquid is greater than the critical surface tension of the transfer printing temporary carrier and less than a surface tension of fiber of the fabric; and
(d) separating the aqueous solution or the aqueous dispersion liquid from the transfer printing temporary carrier at a tight-contact position between the transfer printing temporary carrier and the fabric, so that an aqueous ink dye is transferred onto the fiber of the fabric.
2. The paperless transfer printing method according to claim 1 , wherein in the step (a), the surface tension of the aqueous ink is less than the critical surface tension of the transfer printing temporary carrier by 1-4 mN/m.
3. The paperless transfer printing method according to claim 1 , wherein in the step (c), the transfer printing temporary carrier is wetted by using the aqueous surface tension increasing liquid carried in the fiber of the fabric by using an anilox roller or is directly wetted by using a quantitative humidification system, or is wetted by sizing the fabric with the aqueous surface tension increasing liquid by spraying.
4. The paperless transfer printing method according to claim 1 , wherein the transfer printing temporary carrier is a seamless blanket belt or a roller externally wrapped by the elastic polymer material layer.
5. The paperless transfer printing method according to claim 1 , wherein the elastic polymer material is a polyurethane rubber or a polybutyl rubber, and critical surface tensions of the polyurethane rubber and the polybutyl rubber are 29 mN/m and 27 mN/m respectively.
6. The paperless transfer printing method according to claim 1 , wherein a Shore Hardness of the transfer printing temporary carrier is 85 to 95.
7. The paperless transfer printing method according to claim 1 , wherein the aqueous surface tension increasing liquid is deionized water, or distilled water, or an aqueous solution into which a printing and dyeing auxiliary having a concentration below 5% is added, and does not comprise a surface active agent.
8. The paperless transfer printing method according to claim 7 , wherein the printing and dyeing auxiliary is a color fixing agent and/or a thickening agent.
9. The paperless transfer printing method according to claim 1 , wherein a formula of the aqueous surface tension increasing liquid comprises components of: 0.5-1% of acetic acid, 0.5-1% of pH conditioning agent, 1-1.5% of chelating agent, 2-5% of hygroscopic agent, 1-3% of color fixing agent, and 0.05-0.5% of paste, wherein a sum of proportions of the components is adjusted to 100% by using water.
10. The paperless transfer printing method according to claim 1 , wherein a formula of the aqueous surface tension increasing liquid comprises components of: 10-20% of binder, 0.6-0.9% of slip agent, 3-5% of emulsifying agent, and 0.5% of defoaming agent, wherein a sum of proportions of the components is adjusted to 100% by using deionized water.
11. The paperless transfer printing method according to claim 1 , wherein the printing machine is a gravure printing machine, a flexo printing machine or a screen printing machine.
12. The paperless transfer printing method according to claim 1 , wherein the aqueous ink is water-soluble reactive dye ink, water-soluble acid dye ink or water-dispersible disperse dye ink.
13. The paperless transfer printing method according to claim 12 , wherein a formula of the water-soluble reactive dye ink comprises components of: 5-15% of printing paste, 15-40% of dye, 0.5-1% of anti-staining salt S, 5-8% of cosolvent, and 0.5-2% of leveling agent, wherein a sum of proportions of the components is adjusted to 100% by using water.
14. The aqueous ink paperless transfer printing method according to claim 12 , wherein a formula of the water-soluble acid dye ink comprises components of: 20-40% of acid dye, 2-5% of urea, 2-5% of cosolvent, 1-1.5% of chelating agent, 0-0.8% of ammonium sulfate, and 2-5% of surface tension conditioning agent, wherein a sum of proportions of the components is adjusted to 100% by using water.
15. The paperless transfer printing method according to claim 12 , wherein a formula of the water-dispersible disperse dye ink comprises components of: 15% to 45% of macromolecule disperse dye, 4% to 12% of paste, and 3% to 5% of dispersant, wherein a sum of proportions of the components is adjusted to 100% by using deionized water.
16. The paperless transfer printing method according to claim 1 , wherein the fabric is a cellulose fiber fabric, and the surface tension of the aqueous solution or the aqueous dispersion liquid formed by wetting the transfer printing temporary carrier satisfies: 50 mN/m≤the surface tension of the aqueous solution or the aqueous dispersion liquid<70 mN/m.
17. The paperless transfer printing method according to claim 1 , wherein the fabric is a polyester fabric, and the surface tension of the aqueous solution or the aqueous dispersion liquid formed by wetting the transfer printing temporary carrier satisfies: 35 mN/m≤the surface tension of the aqueous solution or the aqueous dispersion liquid<43 mN/m.
18. The paperless transfer printing method according to claim 1 , wherein the fabric is a polyamide fabric, and the surface tension of the aqueous solution or the aqueous dispersion liquid formed by wetting the transfer printing temporary carrier satisfies: 35 mN/m≤the surface tension of the aqueous solution or the aqueous dispersion liquid<42 mN/m.
19. The paperless transfer printing method according to claim 1 , wherein the fabric is a pure silk fabric, and the surface tension of the aqueous solution or the aqueous dispersion liquid formed by wetting the transfer printing temporary carrier satisfies: 40 mN/m≤the surface tension of the aqueous solution<49 mN/m.
20. The paperless transfer printing method according to claim 1 , further comprising: performing color fixing, washing, and shaping to obtain a transfer printing-finished product after separating the fabric from the transfer printing temporary carrier.