Composite film for electronic devices using high frequency band signals, printed wiring board and manufacturing method therefor
A composite film for electronic device using high frequency band signals, which is low in dielectric tangent, excellent in embedding properties relative to unevenness of a circuit, etc., and excellent in surface smoothness, and has high adhesion to plated copper is provided; and a printed wiring board containing a cured material of the composite film for electronic device and a method of producing the printed wiring board are also provided. Specifically, the composite film for electronic device is a composite film for electronic device using high frequency band signals, including a layer A having a minimum melt viscosity at 80 to 150° C. of 100 to 4,000 Pa·s; and a layer B having a minimum melt viscosity at 80 to 150° C. of 50,000 Pa·s or more. The composite film for electronic device is low in thermal expansion properties and excellent in handling properties of film.
1. A composite film for electronic device using high frequency band signals, comprising:
a layer A having a minimum melt viscosity at 80 to 150° C. of 100 to 4,000 Pa·s, wherein the layer A contains a polyimide compound having a structural unit derived from a maleimide compound and a structural unit derived from a diamine compound; and an inorganic filler, and wherein the structural unit derived from a maleimide compound contains a structural unit derived from an aliphatic maleimide compound having a carbon number between imide groups of 6 to 40; and
a layer B having a minimum melt viscosity at 80 to 150° C. of 63,000 Pa·s or more.
2. The composite film for electronic device using high frequency band signals according to claim 1 , wherein a thickness of the layer B is from 1 to 5 μm.
3. The composite film for electronic device using high frequency band signals according to claim 1 , where a total thickness of the layer A and the layer B is from 15 to 50 μm.
4. The composite film for electronic device using high frequency band signals according to claim 1 , wherein the layer B contains a polyfunctional epoxy resin and a phenolic hydroxy group-containing polybutadiene-modified polyamide resin.
5. The composite film for electronic device using high frequency band signals according to claim 1 , which exhibits a dielectric tangent at 5 GHz of 0.005 or less in terms of a cured material thereof.
6. A printed wiring board comprising a cured material of the composite film for electronic device according to claim 1 .
7. The composite film for electronic device using high frequency band signals according to claim 1 , wherein the content of the structural unit derived from an aliphatic maleimide compound relative to the total content of the structural units derived from the maleimide compound is preferably 5 to 50% by mass in the polyimide compound.
8. The composite film for electronic device using high frequency band signals according to claim 1 , wherein the content of the structural unit derived from an aliphatic maleimide compound relative to the total content of the structural units derived from the maleimide compound is preferably 10 to 40% by mass in the polyimide compound.
9. The composite film for electronic device using high frequency band signals according to claim 1 , wherein layer B having a minimum melt viscosity at 80 to 150° C. of 63,000 to 70,000 Pa·s.
10. The composite film for electronic device using high frequency band signals according to claim 1 , wherein the structural unit derived from a maleimide compound contains a structural unit derived from an aliphatic maleimide compound having a carbon number between imide groups of 7 to 30.
11. A method of producing a printed wiring board, comprising:
a step of using the composite film for electronic device according to claim 1 and sticking the side of the layer A of the composite film for electronic device onto a board having a difference in level on a surface thereof due to a circuit or a component, to fill the difference in level;
a step of curing the layer A and the layer B of the composite film for electronic device; and
a step of forming a circuit on a surface on the side of the layer B of the composite film for electronic device by a semi-additive method.
12. A method of producing a printed wiring board, comprising a step of laminating the composite film for electronic device according to claim 1 on one surface or both surfaces of a base material.