IP Library Granted Patent US 10,851,313
Granted Patent B2
US 10,851,313 · App. 16/318,539 · Granted Dec 1, 2020

Method of producing lower olefin and monocyclic aromatic hydrocarbon having 6 to 8 carbon atoms and device for producing lower olefin and monocyclic aromatic hydrocarbon having 6 to 8 carbon atoms

Inventors: Ryoji Ida (Tokyo, JP); Yasuyuki Iwasa (Tokyo, JP); Masahide Kobayashi (Tokyo, JP); Yukihiro Yoshiwara (Tokyo, JP); Shinichiro Yanagawa (Tokyo, JP); Yasuhiro Watanabe (Yokohama, JP); Takashi Aozasa (Yokohama, JP); Shinji Hyodo (Yokohama, JP)
Assignees: ENEOS CORPORATION; CHIYODA CORPORATION
C10G11/05C10G11/10C10G63/04C10G7/00C10G2300/1051C10G2300/1059C10G2300/4081C10G2400/20C10G2400/30
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Quick Facts
Patent No.
US 10,851,313
App. No.
16/318,539
Granted
Dec 1, 2020
Kind
B2
Abstract

A method of producing a lower olefin and BTX from stock oils selected from at least two kinds of oils is provided. The method includes a first catalytic cracking step of bringing one stock oil A into contact with a catalytic cracking catalyst; a second catalytic cracking step of bringing one stock oil B, having an aromatic component content smaller than that of the stock oil A, into contact with the catalytic cracking catalyst; and a separation and collection step of collecting the lower olefins and BTX from a product generated in the first and second catalytic cracking steps. A contact time A during which the stock oil A is in contact with the catalytic cracking catalyst in the first catalytic cracking step is longer than a contact time B during which the stock oil B is in contact with the catalytic cracking catalyst in the second catalytic cracking step.

Claims (15)

1. A method of producing lower olefins and monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms from stock oils selected from at least two or more kinds of oils, the method comprising:

a first catalytic cracking step of bringing one stock oil A among the stock oils into contact with a catalytic cracking catalyst;

a second catalytic cracking step of bringing one stock oil B into contact with the catalytic cracking catalyst; and

a separation and collection step of collecting the lower olefins and the monocyclic aromatic hydrocarbons having 6 to 8 carbon atoms from a product generated in the first and second catalytic cracking steps,

wherein the first catalytic cracking step and the second catalytic cracking step are conducted in a single reaction tank,

wherein the stock oil A contains 59% by mass or greater of an aromatic component,

wherein the stock oil B contains 15% by mass or greater of a non-aromatic component and 50% by mass or greater of an aromatic component, provided that the content of the aromatic component contained in the stock oil B is 90% or less with respect to the total amount of the aromatic components contained in the stock oil A,

wherein a contact time A during which the stock oil A is in contact with the catalytic cracking catalyst in the first catalytic cracking step is in a range of 15 seconds to 300 seconds, and

wherein a contact time B during which the stock oil B is in contact with the catalytic cracking catalyst in the second catalytic cracking step is in a range of 0.1 seconds to 5.0 seconds.

2. The method according to claim 1 ,

wherein the stock oil A contains heavy fractions having 9 or more carbon atoms collected in the separation and collection step are recycled to the stock oil A.

3. The method according to claim 1 , further comprising:

a step of producing benzene or xylene from toluene after the separation and collection step.

4. The method according to claim 1 ,

wherein the catalytic cracking catalyst is a catalyst containing crystalline aluminosilicates.

Assignments (2)
CHANGE OF NAME Recorded Oct 23, 2020
From: JXTG NIPPON OIL & ENERGY CORPORATION
To: ENEOS CORPORATION
Reel/Frame 054188/0965 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 17, 2019
From: IDA, RYOJI; IWASA, YASUYUKI; KOBAYASHI, MASAHIDE; YOSHIWARA, YUKIHIRO; YANAGAWA, SHINICHIRO; WATANABE, YASUHIRO; AOZASA, TAKASHI; HYODO, SHINJI
To: JXTG NIPPON OIL & ENERGY CORPORATION; CHIYODA CORPORATION
Reel/Frame 048050/0532 →
Priority Claims (1)
JP 2016-142571 · Jul 20, 2016 · national
Continuity (1)
Related Publication 20190316048A1 · Oct 17, 2019