Mixed catalyst systems for producing multimodal elastomers
Embodiments of the present disclosure are directed to multimodal elastomers produced by olefin polymerization with a mixed catalyst system, specifically, a constrained geometry catalyst and a biphenyl phenol catalyst. The multimodal elastomers may be incorporated as impact modifiers in thermoplastic olefins.
1. A multimodal elastomer comprising a copolymer of ethylene and at least one α-olefin monomer, wherein the multimodal elastomer comprises:
20 to 90% by weight of a high molecular weight (HMW) fraction, wherein the HMW fraction has a number average molecular weight (Mn) of at least 50 kg/mol, when measured according to gel permeation chromatography (GPC), and wherein the HMW fraction comprises at least 35% by weight ethylene and at least 30% by weight α-olefin comonomer; and
a low molecular weight fraction (LMW) fraction, wherein the LMW fraction has an Mn of 4 to 25 kg/mol, and wherein the LMW fraction comprises at least 50% by weight ethylene and at least 29% by weight α-olefin comonomer, and wherein the ratio of the Mn of HMW fraction to the Mn of the LMW fraction is at least 5 to 1;
wherein the multimodal elastomer has a density between 0.853 to 0.875 g/cc, a shear viscosity at 100 rad/s of less than 2,500 Pa-s, and a shear viscosity at 0.1 rad/s of less than 120,000 Pa-s.
2. The multimodal elastomer of claim 1 , wherein the α-olefin monomer includes one or more α-olefins selected from C 3 -C 12 α-olefins.
3. The multimodal elastomer of claim 1 , wherein the α-olefin monomer is 1-octene.
4. The multimodal elastomer of claim 1 , wherein the percent by weight of the α-olefin monomer incorporated in the HMW fraction is greater than the percent by weight of the α-olefin monomer incorporated in the LMW fraction.
5. The multimodal elastomer of claim 1 , wherein the percent by weight of the α-olefin monomer in the HMW fraction is at least 4% by weight greater than the percent by weight of the α-olefin monomer in the LMW fraction.
6. The multimodal elastomer of claim 1 , wherein the multimodal elastomer comprises 50 to 85 wt % of the high HMW fraction.
7. The multimodal elastomer of claim 1 , wherein the multimodal elastomer has a shear viscosity at 0.1 rad/s of less than 60,000 Pa·s.
8. The multimodal elastomer of claim 1 , wherein the ratio of the Mn of HMW fraction to the Mn of the LMW fraction is at least 8 to 1.
9. A thermoplastic olefin comprising:
the multimodal elastomer of claim 1 ; and
polypropylene.
10. The thermoplastic olefin of claim 9 comprising additional elastomers, block composites, fillers, or combinations.
11. A method of making a multimodal elastomer comprising:
adding to a reactor system at least one ethylene monomer, at least one α-olefin comonomer, a first catalyst comprising a biphenyl phenol complex, a second catalyst comprising a constrained geometry complex;
producing the multimodal elastomer via solution polymerization at a temperature of at least 100° C.,
wherein the multimodal elastomer comprises a high molecular weight (HMW) fraction and a low molecular weight (LMW) fraction,
wherein the HMW fraction has a number average molecular weight (Mn) of at least 50 kg/mol, when measured according to gel permeation chromatography (GPC), and wherein the HMW fraction comprises at least 35% by weight ethylene and at least 30% by weight α-olefin comonomer, and wherein the LMW fraction has an Mn of 4 to 25 kg/mol, and wherein the LMW fraction comprises at least 50% by weight ethylene and at least 29% by weight by weight α-olefin comonomer, and
wherein the multimodal elastomer comprises: a ratio of the Mn of the HMW fraction to the Mn of the LMW fraction of at least 5 to 1; a density between 0.853 to 0.875 g/cc; shear viscosity at 100 rad/s of less than 2,500 Pa-s; and a shear viscosity at 0.1 rad/s shear of less than 120,000 Pa·s.
12. The method of claim 11 wherein the multimodal elastomer comprises 20 to 90% by weight of a high molecular weight (HMW) fraction.
13. The method of claim 11 , wherein the % by weight of the α-olefin monomer in the HMW fraction is at least 4% by weight greater than the % by weight of the α-olefin monomer in the LMW fraction.
14. The method of claim 11 , wherein the reactor system comprises a single reactor.
15. The method of claim 11 , wherein the reactor system comprises two reactors.