High strength rubber composition

1. A rubber composition comprising at least one resin based on:

(A1) at least one aromatic compound resulting from the reaction between a reactant of formula (α):

where B represents CHO or CH 2 OH, and a reactant of formula (β) or (γ):

and mixtures thereof, in which Ar represents an optionally substituted aromatic ring, and each R 1 and R 2 radical represents, independently of one another, a monovalent hydrocarbon radical or a substituted monovalent hydrocarbon radical; and

(A2) at least one phenolic compound chosen from:

(A21) at least one aromatic polyphenol comprising at least one aromatic ring bearing at least two hydroxyl functional groups in the meta position with respect to one another, the two positions ortho to at least one of the hydroxyl functional groups being unsubstituted;

(A22) at least one aromatic monophenol comprising at least one six-membered aromatic ring bearing a single hydroxyl functional group, the two positions ortho to the hydroxyl functional group being unsubstituted or at least one position ortho to and the position para to the hydroxyl functional group being unsubstituted; and

mixtures thereof.

2. The rubber composition according to claim 1 , wherein the aromatic compound (α) corresponds to general formula (II):

where B represents CHO or CH 2 OH, X represents O, NR 3 , NO, S, SO, SO 2 or SR 4 R 5 , R 3 represents a hydrogen or an alkyl, aryl, arylalkyl, alkylaryl or cycloalkyl group, and R 4 and R 5 each represent, independently of one another, a hydrogen or an alkyl, aryl, arylalkyl, alkylaryl or cycloalkyl group.

3. The rubber composition according to claim 1 , wherein the aromatic compound (α) is selected from the group consisting of 5-(hydroxymethyl)furfural, 2,5-di(hydroxymethyl)furan and mixtures thereof.

4. The rubber composition according to claim 1 , wherein the aromatic ring of the aromatic polyphenol bears three hydroxyl functional groups in the meta position with respect to one another.

5. The rubber composition according to claim 1 , wherein the two positions ortho to each hydroxyl functional group on the aromatic ring of the aromatic polyphenol are unsubstituted.

6. The rubber composition according to claim 1 , wherein at least one of the aromatic rings of the aromatic polyphenol bears three hydroxyl functional groups in the meta position with respect to one another.

7. The rubber composition according to claim 1 , wherein each aromatic ring of the aromatic polyphenol is a benzene ring.

8. The rubber composition according to claim 1 , wherein the aromatic polyphenol is selected from the group consisting of resorcinol, phloroglucinol, 2,2′,4,4′-tetrahydroxydiphenyl sulfide, 2,2′,4,4′-tetrahydroxybenzophenone and mixtures thereof.

9. The rubber composition according to claim 1 , wherein the aromatic polyphenol is a pre-condensed resin based on:

at least one polyphenol comprising at least one aromatic ring bearing at least two hydroxyl functional groups in the meta position with respect to one another, the two positions ortho to at least one of the hydroxyl functional groups being unsubstituted, and

at least one compound capable of reacting with the polyphenol comprising at least one aldehyde functional group and/or one compound capable of reacting with the polyphenol comprising at least two hydroxymethyl functional groups borne by an aromatic ring.

10. The rubber composition according to claim 1 further comprising a diene elastomer selected from the group consisting of polybutadienes, synthetic polyisoprenes, natural rubber, butadiene copolymers, isoprene copolymers and mixtures thereof.

11. The rubber composition according to claim 1 , in the cured state.

12. A rubber composition comprising:

(A1) at least one aromatic compound resulting from the reaction between a reactant of formula (α):

where B represents CHO or CH 2 OH, and a reactant of formula (β) or (γ):

and mixtures thereof, in which Ar represents an optionally substituted aromatic ring, and each R 1 and R 2 radical represents, independently of one another, a monovalent hydrocarbon radical or a substituted monovalent hydrocarbon radical; and

(A2) at least one phenolic compound chosen from:

(A21) at least one aromatic polyphenol comprising at least one aromatic ring bearing at least two hydroxyl functional groups in the meta position with respect to one another, the two positions ortho to at least one of the hydroxyl functional groups being unsubstituted;

(A22) at least one aromatic monophenol comprising at least one six-membered aromatic ring bearing a single hydroxyl functional group, the two positions ortho to the hydroxyl functional group being unsubstituted or at least one position ortho to and the position para to the hydroxyl functional group being unsubstituted; and

mixtures thereof.

13. The rubber composition according to claim 12 , in the raw state.

14. A process for the manufacture of a rubber composition in the raw state comprising the step of:

mixing

at least one aromatic compound (A1) resulting from the reaction between a reactant of formula (α):

where B represents CHO or CH 2 OH, and a reactant of formula (β) or (γ):

and mixtures thereof, in which Ar represents an optionally substituted aromatic ring, and each R 1 and R 2 radical represents, independently of one another, a monovalent hydrocarbon radical or a substituted monovalent hydrocarbon radical; and

at least one phenolic compound (A2) chosen from: (A21) at least one aromatic polyphenol comprising at least one aromatic ring bearing at least two hydroxyl functional groups in the meta position with respect to one another, the two positions ortho to at least one of the hydroxyl functional groups being unsubstituted; (A22) at least one aromatic monophenol comprising at least one six-membered aromatic ring bearing a single hydroxyl functional group, the two positions ortho to the hydroxyl functional group being unsubstituted or at least one position ortho to and the position para to the hydroxyl functional group being unsubstituted; and

mixtures thereof.

15. A process for the manufacture of a rubber composition in the cured state comprising the steps of:

manufacturing a rubber composition in the raw state by mixing:

at least one aromatic compound (A1) resulting from the reaction between a reactant of formula (α)

where B represents CHO or CH 2 OH, and a reactant of formula (β) or (γ):

and mixtures thereof, in which Ar represents an optionally substituted aromatic ring, and each R 1 and R 2 radical represents, independently of one another, a monovalent hydrocarbon radical or a substituted monovalent hydrocarbon radical; and

at least one phenolic compound (A2) chosen from: (A21) at least one aromatic polyphenol comprising at least one aromatic ring bearing at least two hydroxyl functional groups in the meta position with respect to one another, the two positions ortho to at least one of the hydroxyl functional groups being unsubstituted; (A22) at least one aromatic monophenol comprising at least one six-membered aromatic ring bearing a single hydroxyl functional group, the two positions ortho to the hydroxyl functional group being unsubstituted or at least one position ortho to and the position para to the hydroxyl functional group being unsubstituted; and

mixtures thereof;

then shaping the rubber composition in the raw state; and

then crosslinking the rubber composition during which a resin based on the phenolic compound and on the aromatic compound is crosslinked.

16. A rubber composition obtained by the process of claim 15 .

17. A rubber composite reinforced with at least one reinforcing element embedded in a rubber composition of claim 1 .

18. A tire comprising a rubber composition according to claim 1 .