Cathode active material for lithium secondary battery, method for preparing same, and lithium secondary battery comprising same
Provided are a cathode active material for a lithium secondary battery, a method for preparing the same, and a lithium secondary battery comprising the same. The cathode active material for a lithium secondary battery comprises: a lithium metal compound; and a lithium compound disposed on the surface of the lithium metal compound, wherein the content of lithium contained in the lithium compound is 0.25 parts by weight or less with respect to 100 parts by weight of the lithium metal compound, wherein the specific surface area of the lithium compound is between 0.5 m 2 /g and 2.0 m 2 /g, and the pH of the lithium compound is between 11.5 and 12.3.
1. A cathode active material for a lithium secondary battery, the cathode active material comprising:
a lithium metal compound and a lithium compound on a surface of the lithium metal compound,
wherein the lithium metal compound is different from the lithium compound,
the content of lithium contained in the lithium compound is 0.25 parts by weight or less with respect to 100 parts by weight of the lithium metal compound,
a specific surface area of the cathode active material is 0.5 m 2 /g to 2.0 m 2 /g, and
a pH of the cathode active material is 11.5 to 12.1.
2. The cathode active material of claim 1 , wherein the content of lithium contained in the lithium compound is 0.05 parts by weight to 0.25 parts by weight with respect to 100 parts by weight of the lithium metal compound.
3. The cathode active material of claim 1 , wherein the specific surface area of the cathode active material is 0.5 m 2 /g to 1.90 m 2 /g.
4. The cathode active material of claim 1 , wherein the pH of the cathode active material is 11.5 to 11.8.
5. The cathode active material of claim 1 , wherein the lithium metal compound comprises a nickel-based oxide represented by Chemical Formula 1:
Li a (Ni x M′ y M″ z )O 2 [Chemical Formula 1]
wherein, in Chemical Formula 1,
M′ is at least one selected from Co, Mn, Ni, Al, Mg, and Ti, M″ is at least one selected from Ca, Mg, Al, Ti, Sr, Fe, Co, Mn, Ni, Cu, Zn, Y, Zr, Nb, and B, 0.8<a≤1.2, 0.6≤x≤1, 0≤y≤0.4, 0≤z≤0.4, and x+y+z=1.
6. The cathode active material of claim 5 , wherein Chemical Formula 1 is a lithium nickel-based oxide represented by Chemical Formula 2:
Li a (Ni x CO y M″ z )O 2 [Chemical Formula 2]
wherein, in Chemical Formula 2,
M″ is at least one element selected from Al and Mn,
0.8<a≤1.2, 0.6≤x≤1, 0≤y≤0.4, 0≤z≤0.4, and x+y+z=1.
7. The cathode active material of claim 1 , wherein the lithium compound comprises Li 2 CO 3 , LiOH, or a combination thereof.
8. A lithium secondary battery comprising a cathode comprising the cathode active material of claim 1 .
9. A method for preparing a cathode active material for a lithium secondary battery, the method comprising
washing a first active material with ammonia water to obtain a second active material, the second active material comprising a lithium metal compound and a lithium compound on a surface of the lithium metal compound,
wherein the lithium metal compound is different from the lithium compound,
the content of lithium contained in the lithium compound is 0.25 parts by weight or less with respect to 100 parts by weight of the lithium metal compound,
a specific surface area of the cathode active material is 0.5 m 2 /g to 2.0 m 2 /g, and
a pH of the cathode active material is 11.5 to 12.1.
10. The method of claim 9 , wherein the ammonia water comprises water and ammonia in a weight ratio of 50:50 to 99:5.
11. The method of claim 9 , wherein pH of the ammonia water is 11 to 13.