Super absorbent polymer and method for preparing same
The present invention relates to a super absorbent polymer and a method for preparing the same. According to the method for preparing a super absorbent polymer of the present invention, the super absorbent polymer +having improved absorption capacity and permeability can be prepared.
1. A method for preparing a super absorbent polymer comprising:
thermally polymerizing or photo-polymerizing a monomer composition including an acrylic acid-based monomer having an acidic group, of which at least a part is neutralized, and a polymerization initiator to form a hydrogel polymer;
drying the hydrogel polymer;
pulverizing the dried polymer;
mixing the pulverized polymer with a surface crosslinking agent and an aliphatic alcohol of C6 to C20;
heating the polymer obtained by mixing the surface crosslinking agent and the aliphatic alcohol of C6 to C20 to a temperature of 160 to 200° C. to carry out a surface modification.
2. The method for preparing a super absorbent polymer according to claim 1 , wherein the aliphatic alcohol of C6 to C20 includes one or more selected from the group consisting of stearyl alcohol, lauryl alcohol, and cetyl alcohol.
3. The method for preparing a super absorbent polymer according to claim 1 , wherein the aliphatic alcohol of C6 to C20 is mixed in an amount of 0.001 to 2 parts by weight based on 100 parts by weight of the pulverized polymer.
4. The method for preparing a super absorbent polymer according to claim 1 , wherein the aliphatic alcohol of C6 to C20 is added separately before adding the surface crosslinking agent, to the pulverized polymer, or is added together with the surface crosslinking agent.
5. The method for preparing a super absorbent polymer according to claim 1 , wherein the super absorbent polymer has P defined by the following Equation 1 of 0.85 to 1.20:
P =SFC*10 7 /(CRC+AUL) [Equation 1]
in Equation 1,
CRC means a centrifuge retention capacity (unit: g/g) measured according to EDANA method WSP 241.3,
AUL means an absorbency under load (unit: g/g) at 0.7 psi measured according to EDANA method WSP 242.3, and
SFC means a saline flow conductivity (unit: cm 3 *sec/g).
6. A super absorbent polymer comprising a crosslinked polymer obtained by polymerizing and internally crosslinking an acrylic acid-based monomer having an acidic group, of which at least a part is neutralized; and a surface modifying layer formed on the surface of the crosslinked polymer,
wherein a centrifuge retention capacity (CRC) measured according to EDANA method WSP 241.3 is 25 to 35 g/g, an absorbency under load (AUL) at 0.7 psi measured according to EDANA method WSP 242.3 is 20 to 30 g/g, and a surface tension is 65 to 73 mN/m.
7. The super absorbent polymer according to claim 6 , wherein the surface modifying layer includes an alkyl group of C6 to C20.
8. The super absorbent polymer according to claim 6 , wherein the super absorbent polymer has a saline flow conductivity (SFC) of 45×10 −7 to 80×10 −7 cm 3 ×sec/g.
9. The super absorbent polymer according to claim 6 , wherein P defined by the following Equation 1 is 0.85 to 1.20:
P =SFC*10 7 /(CRC+AUL) [Equation 1]
in Equation 1,
CRC means a centrifuge retention capacity (unit: g/g) measured according to EDANA method WSP 241.3,
AUL means an absorbency under load (unit: g/g) at 0.7 psi measured according to EDANA method WSP 242.3, and
SFC means a saline flow conductivity (unit: cm 3 ×sec/g).