Friction stir welding tool member made of silicon nitride sintered body, and friction stir welding apparatus using the same
The friction stir welding tool member according to the present invention is made of a silicon nitride sintered body, wherein the silicon nitride sintered body contains 15% by mass or less of additive components except silicon nitride in such a manner that the additive components include at least one element selected from lanthanoid elements and at least one element selected from Mg, Ti, Hf, and Mo. In addition, it is preferable that the additive components further include at least one element selected from Al, Si, and C. According to the above-described configuration, a friction stir welding tool member having an excellent durability can be provided.
1. A friction stir welding tool member made of a silicon nitride sintered body, wherein the silicon nitride sintered body contains 15% by mass or less of additive components except silicon nitride in such a manner that the additive components include at least one element selected from lanthanoid elements and at least one element selected from Mg, Ti, Hf or Mo;
the lanthanoid element is contained in an amount of 1 to 10% by mass when a lanthanoid element contained in the silicon nitride sintered body is converted into a metal simple substance of the lanthanoid element; and
both β-silicon nitride crystal particles and α-sialon crystal particles exist in the silicon nitride sintered body.
2. The friction stir welding tool member made of a silicon nitride sintered body according to claim 1 , wherein one or more element selected from Al, Si, or C is further included as the additive components.
3. The friction stir welding tool member made of a silicon nitride sintered body according to claim 1 , wherein the lanthanoid element is at least one element selected from Yb, Er, Lu or Ce.
4. The friction stir welding tool member made of a silicon nitride sintered body according to claim 1 , wherein a maximum diameter of a grain boundary phase of the silicon nitride sintered body is 1 μm or less.
5. The friction stir welding tool member made of a silicon nitride sintered body according to claim 1 ,
wherein variation of lanthanoid element concentration of individual grain boundary phases is within ±20% with respect to an average value acquired by concentration values of the lanthanoid elements in individual grain boundary phases that are present in a unit area of 5 μm×5 μm in structure of the silicon nitride sintered body, when concentration distribution of the lanthanoid elements in individual grain boundary phases is analyzed by TEM analysis for the unit area.
6. The friction stir welding tool member made of a silicon nitride sintered body according to claim 1 , wherein an aspect ratio of a grain boundary phase of the silicon nitride sintered body is 1.5 or less.
7. The friction stir welding tool member made of a silicon nitride sintered body according to claim 1 , wherein the silicon nitride sintered body has an oxidation increase of 10×10 −5 wt %/cm 2 or less per 1 cm 2 of a surface area after being held at 1200° C. in atmosphere for 100 hours.
8. The friction stir welding tool member made of a silicon nitride sintered body according to claim 1 , wherein a surface roughness Ra of a friction surface of the silicon nitride sintered body is 5 μm or less.
9. A friction stir welding apparatus on which the friction stir welding tool member made of a silicon nitride sintered body according to claim 1 is mounted.
10. A friction stir welding method in which the friction stir welding apparatus according to claim 9 is used, the friction stir welding method comprising:
superimposing two or more materials to be welded each other; and
pressing the friction stir welding tool member against the materials to be welded while the friction stir welding tool member is being rotated at a rotation speed of 300 rpm or more.
11. The friction stir welding method according to claim 10 , wherein the materials to be welded are steel.
12. The friction stir welding tool member made of a silicon nitride sintered body according to claim 1 , wherein the silicon nitride sintered body has a Vickers hardness of 1590 or more.
13. The friction stir welding tool member made of a silicon nitride sintered body according to claim 1 , wherein
one or more element selected from Al, Si, or C is further included as the additive components,
the lanthanoid element is at least one element selected from Yb, Er, Lu or Ce, and
the silicon nitride sintered body has a Vickers hardness of 1590 or more.
14. The friction stir welding tool member made of a silicon nitride sintered body according to claim 1 , wherein
one or more element selected from Al, Si, or C is further included as the additive components,
the lanthanoid element is at least one element selected from Yb, Er, Lu or Ce,
a maximum diameter of a grain boundary phase of the silicon nitride sintered body is 1 μm or less, and
the silicon nitride sintered body has a Vickers hardness of 1590 or more.