Free-cutting copper alloy and method for producing free-cutting copper alloy
This free-cutting copper alloy contains more than 77.0% but less than 81.0% Cu, more than 3.4% but less than 4.1% Si, 0.07% to 0.28% Sn, 0.06% to 0.14% P, and more than 0.02% but less than 0.25% Pb, with the remainder being made up of Zn and unavoidable impurities. The composition satisfies the following relations: 1.0≤f0=100×Sn/(Cu+Si+0.5×Pb+0.5×P−75.5)≤3.7, 78.5≤f1=Cu+0.8×Si−8.5×Sn+P+0.5×Pb≤83.0, 61.8≤f2=Cu−4.2×Si−0.5×Sn−2×P≤63.7. The area ratios (%) of the constituent phases satisfy the following relations, 36≤κ≤72, 0≤γ≤2.0, 0≤β≤0.5, 0≤μ≤2.0, 96.5≤f3=α+κ, 99.4≤f4=α+κ+γ+μ, 0≤f5=γ+μ≤3.0, 38≤f6=κ+6×γ 1/2 +0.5×μ≤80. The long side of the γ phase does not exceed 50 μm, and the long side of the μ phase does not exceed 25 μm.
1. A free-cutting copper alloy comprising:
higher than 77.0 mass % and lower than 81.0 mass % of Cu;
higher than 3.4 mass % and lower than 4.1 mass % of Si;
0.07 mass % to 0.28 mass % of Sn;
0.06 mass % to 0.14 mass % of P;
higher than 0.02 mass % and lower than 0.25 mass % of Pb; and
a balance including Zn and inevitable impurities,
wherein when a Cu content is represented by [Cu] mass %, a Si content is represented by [Si] mass %, a Sn content is represented by [Sn] mass %, a P content is represented by [P] mass %, and a Pb content is represented by [Pb] mass %, the relations of
1.0≤ f 0=100×[Sn]/([Cu]+[Si]+0.5×[Pb]+0.5×[P]−75.5)≤3.7,
78.5≤ f 1=[Cu]+0.8×[Si]−8.5×[Sn]+[P]+0.5×[Pb]≤83.0, and
61.8≤ f 2=[Cu]−4.2×[Si]−0.5×[Sn]−2×[P]≤63.7
are satisfied,
in constituent phases of metallographic structure, when an area ratio of α phase is represented by (α)%, an area ratio of β phase is represented by (β)%, an area ratio of γ phase is represented by (γ)%, an area ratio of κ phase is represented by (κ)%, and an area ratio of μ phase is represented by (μ)%, the relations of
36≤(κ)≤72,
0≤(γ)≤2.0,
0≤(β)≤0.5,
0≤(μ)≤2.0,
96.5≤ f 3=(α)+(κ),
99.4≤ f 4=(α)+(κ)+(γ)+(μ),
0≤ f 5=(γ)+(μ)≤3.0, and
38≤ f 6=(κ)+6×(γ) 1/2 +0.5×(μ)≤80
are satisfied,
the length of the long side of γ phase is 50 μm or less, and
the length of the long side of μ phase is 25 μm or less, wherein an amount of Sn in K phase is 0.08 mass % to 0.45 mass %, and an amount of P in K phase is 0.07 mass % to 0.22 mass %.
2. The free-cutting copper alloy according to claim 1 , further comprising:
one or more element(s) selected from the group consisting of higher than 0.02 mass % and lower than 0.08 mass % of Sb, higher than 0.02 mass % and lower than 0.08 mass % of As, and higher than 0.02 mass % and lower than 0.30 mass % of Bi.
3. A free-cutting copper alloy comprising:
77.5 mass % to 80.0 mass % of Cu;
3.45 mass % to 3.95 mass % of Si;
0.08 mass % to 0.25 mass % of Sn;
0.06 mass % to 0.13 mass % of P;
0.022 mass % to 0.20 mass % of Pb; and
a balance including Zn and inevitable impurities,
wherein when a Cu content is represented by [Cu] mass %, a Si content is represented by [Si] mass %, a Sn content is represented by [Sn] mass %, a P content is represented by [P] mass %, and a Pb content is represented by [Pb] mass %, the relations of
1.1≤ f 0=100×[Sn]/([Cu]+[Si]+0.5×[Pb]+0.5×[P]−75.5)≤3.4,
78.8≤ f 1=[Cu]+0.8×[Si]−8.5×[Sn]+[P]+0.5×[Pb]≤81.7, and
62.0≤ f 2=[Cu]−4.2×[Si]−0.5×[Sn]−2×[P]≤63.5
are satisfied,
in constituent phases of metallographic structure, when an area ratio of a phase is represented by (α)%, an area ratio of β phase is represented by (β)%, an area ratio of γ phase is represented by (γ)%, an area ratio of κ phase is represented by (κ)%, and an area ratio of μ phase is represented by (μ)%, the relations of
40≤(κ)≤67,
0≤(γ)≤1.5,
0≤(β)≤0.5,
0≤(μ)≤1.0,
97.5≤ f 3=(α)+(κ),
99.6≤ f 4=(α)+(κ)+(γ)+(μ),
0≤ f 5=(γ)+(μ)≤2.0, and
42≤ f 6=(κ)+6×(γ) 1/2 +0.5×(μ)≤72
are satisfied,
the length of the long side of γ phase is 40 μm or less, and
the length of the long side of μ phase is 15 μm or less, wherein an amount of Sn in K phase is 0.08 mass % to 0.45 mass %, and an amount of P in K phase is 0.07 mass % to 0.22 mass %.
4. The free-cutting copper alloy according to claim 3 , further comprising:
one or more element(s) selected from the group consisting of higher than 0.02 mass % and lower than 0.07 mass % of Sb, higher than 0.02 mass % and lower than 0.07 mass % of As, and higher than 0.02 mass % and lower than 0.20 mass % of Bi.
5. The free-cutting copper alloy according to claim 1 ,
wherein a total amount of Fe, Mn, Co, and Cr as the inevitable impurities is lower than 0.08 mass %.
6. The free-cutting copper alloy according to claim 1 , that is made into a hot-worked material,
wherein a Charpy impact test value is 12 J/cm 2 or higher,
a tensile strength is 560 N/mm 2 or higher, and
a creep strain after holding the material at 150° C. for 100 hours in a state where a load corresponding to 0.2% proof stress at room temperature is applied is 0.4% or lower.
7. The free-cutting copper alloy according to claim 1 , that is used in a device for water supply, an industrial plumbing member, or a device that comes in contact with liquid.
8. A method of manufacturing the free-cutting copper alloy according to claim 1 , the method comprising:
a hot working step,
wherein the material's temperature during hot working is 600° C. to 740° C., and
the material is cooled in a temperature range from 470° C. to 380° C. at an average cooling rate of 2.5° C./min to 500° C./min.
9. A method of manufacturing the free-cutting copper alloy according to claim 1 , the method comprising:
any one or both of a cold working step and a hot working step; and
a low-temperature annealing step that is performed after the cold working step or the hot working step,
wherein in the low-temperature annealing step, conditions are as follows:
the material's temperature is in a range of 240° C. to 350° C.,
the heating time is in a range of 10 minutes to 300 minutes, and
when the material's temperature is represented by T° C. and the heating time is represented by t min, 150≤(T−220)×(t) 1/2 ≤1200 is satisfied.