Phosphor, illumination device and use of an illumination device
View Patent ↗A luminescent material may include the formula (MB) (TA) 3−2x (TC) 1+2x O 4−4x N 4x :E where 0<x<0.875. —TA may be selected from a group of monovalent metals, such as Li, Na, Cu, Ag, and combinations thereof. —MB may be selected from a group of divalent metals including Mg, Ca, Sr, Ba, Zn, and combinations thereof. —TC may be selected from a group of trivalent metals including B, Al, Ga, In, Y, Fe, Cr, Sc, rare earth metals, and combinations thereof. —E may be selected from a group including Eu, Mn, Ce, Yb, and combinations thereof.
1. A phosphor having the formula (MB)Li 2 Al 2 O 2 N 2 :E where MB is selected from a group of divalent metals consisting of Mg, Ca, Sr, Ba, Zn, and combinations thereof; and wherein E is selected from a group consisting of Eu, Mn, Ce, Yb, and combinations thereof.
2. The phosphor as claimed in claim 1 ,
which emits electromagnetic radiation in the red spectral region.
3. The phosphor as claimed in claim 1 ,
which has an emission spectrum having a maximum peak wavelength of 614 nm+/−10 nm and/or a half-height width of less than 60 nm.
4. The phosphor as claimed in claim 3 ,
wherein the half-height width is less than 55 nm.
5. The phosphor as claimed in claim 1 ,
wherein the phosphor does not crystallize in the crystal structure of the UCr 4 C 4 type.
6. The phosphor as claimed in claim 1 ,
wherein MB is Ca, Sr, Ba, or a combination thereof.
7. The phosphor as claimed in claim 1 ,
wherein MB is Sr.
8. The phosphor as claimed in claim 1 ,
wherein E is Eu.
9. The phosphor as claimed in claim 1 ,
wherein the phosphor is excitable at least with radiation from the UV and/or blue spectral region.
10. A lighting device comprising a phosphor as claimed in claim 1 .
11. The lighting device as claimed in claim 10 further comprising:
a semiconductor layer sequence set up to emit electromagnetic primary radiation; and
a conversion element which comprises the phosphor and at least partly converts the electromagnetic primary radiation to electromagnetic secondary radiation.
12. The lighting device as claimed in claim 11 ,
wherein the phosphor fully converts the electromagnetic primary radiation to electromagnetic secondary radiation, such that the overall radiation from the lighting device is selected from the red wavelength range.
13. The lighting device as claimed in claim 11 , wherein the conversion element comprises a second phosphor configured to emit radiation from the green spectral region, and a third phosphor configured to emit radiation from the red spectral region.
14. The lighting device as claimed in claim 11 ,
in the form of a lamp for a motor vehicle.
15. The lighting device as claimed in claim 11 ,
wherein the overall radiation from the lighting device is white mixed radiation.
16. A method for backlighting of display devices comprising the lighting device of claim 11 .
17. The phosphor as claimed in claim 1 ,
wherein the phosphor crystallizes in the tetragonal P4 2 /m space group.
18. The phosphor as claimed in claim 1 ,
wherein MB is Sr and E is Eu such that the phosphor has the formula SrLi 2 Al 2 O 2 N 2 :Eu.