Quantum dot and preparation method thereof
The present disclosure discloses a quantum dot and a preparation method thereof, the method comprises a plurality of following steps: preparing a quantum dot solution; preparing an ion-containing organic ligand precursor; adding the ion-containing organic ligand precursor into the quantum dot solution, and making a surface-modification to the quantum dots, before obtaining the quantum dots having the surfaces modified; or providing a quantum dot solution; providing an ion-containing organic ligand precursor; mixing the ion-containing organic ligand precursor and the quantum dot solution, to make a ligand exchanging, before centrifuging and obtaining the quantum dots having the ligand exchanged.
1. A preparation method of a quantum dot (QD), comprising:
preparing a QD solution;
mixing an ionic precursor and an organic ligand for a reaction in which ions in the ionic precursor are combined with the organic ligand, to prepare an ion-containing organic ligand precursor, wherein the organic ligand in the ion-containing organic ligand precursor is at least one of an organic phosphine, an organic amine, and an alkyl mercaptan;
obtaining the ion-containing organic ligand precursor from the reaction;
adding the ion-containing organic ligand precursor into the QD solution, and making a surface-modification to the QDs using the ligand precursor, before obtaining the QDs having the surfaces modified,
wherein the ion-containing organic ligand precursor is at least one cation-containing organic ligand precursor, the cation in the cation-containing organic ligand precursor is at least a cation of a group IIB metal, a cation of a group IIIA element, a cation of a group IB meta or a rare-earth metal cation.
2. The preparation method of the QD according to claim 1 , wherein the QDs in the QD solution are at least one QD in groups of II-VI, groups of III-V, and groups of IV-VI.
3. The preparation method of the QD according to claim 1 , wherein a structure of the QDs in the QD solution is at least one of a homogenous multi-alloy component mononuclear structure, a multi-alloy component gradient mononuclear structure, a multi-alloy component discrete core-shell structure, a multi-alloy component gradient core-shell structure.
4. The preparation method of the QD according to claim 1 , wherein the ionic precursor and the organic ligand are mixed at a molar ratio of an ionic element to the organic ligand of 1:0.1 to 1:10 for the reaction; a temperature of the reaction is 20-400° C. a time is 5 minutes to 10 hours, and an atmosphere of the reaction is one of an inert atmosphere, an air atmosphere, and a vacuum.
5. The preparation method of the QD according to claim 1 , wherein the ion-containing organic ligand precursor and the QD are mixed at a mass ratio of (0.01-100):1 to make the surface-modification; a temperature of a reaction of the surface-modification is 10-400° C., a time is 5 minutes to 10 hours; and an atmosphere of the reaction of the surface-modification is one of an inert atmosphere, an air atmosphere, and a vacuum.
6. The preparation method of the QD according to claim 1 , wherein an atmosphere of the reaction of mixing the ionic precursor and the organic ligand is one of an air atmosphere and a vacuum.
7. A preparation method of a QD, comprising:
providing a QD solution;
mixing an ionic precursor and an organic ligand for a reaction in which ions in the ionic precursor are combined with the organic ligand, to prepare an ion-containing organic ligand precursor, wherein the organic ligand in the ion-containing organic ligand precursor is at least one of an organic phosphine, an organic amine, and an alkyl mercaptan;
obtaining the ion-containing organic ligand precursor prepared from the reaction;
mixing the ion-containing organic ligand precursor and the QD solution to make a ligand exchanging, obtaining the ligand exchanged QDs,
wherein the ion-containing organic ligand precursor is at least one cation-containing organic ligand precursor, the cation in the cation-containing organic ligand precursor is at least a cation of a group IIB metal, a cation of a group IIIA element, a cation of a group IB metal, or a rare-earth metal cation.
8. The preparation method of the QD according to claim 7 , wherein the QDs in the QD solution are at least one QD in groups of groups of III-V, and groups of IV-VI.
9. The preparation method of the QD according to claim 7 , wherein the ion-containing organic ligand precursor and the QD are mixed at a mass ratio of (0.01-100):1 to make the ligand exchanging; a reaction temperature of the ligand exchanging is 10-400° C., a time is 5 minutes to 10 hours; and an atmosphere of the ligand exchanging is one of an inert atmosphere, an air atmosphere, and a vacuum.
10. The preparation method of the QD according to claim 7 , further comprising:
carrying out a centrifugation after mixing the ion-containing organic ligand precursor and the QD solution, to obtain the ligand exchanged QDs.
11. A QD, wherein the QD comprises a QD core and an ion-containing organic ligand, and an exposed dangling bond on the surfaces of the QD core is combined with an ion in the ion-containing organic ligand,
wherein the QD includes a ligand exchanged QD obtained from an ion-containing organic ligand precursor; and the ion-containing organic ligand precursor is at least one cation-containing organic ligand precursor, the cation in the cation-containing organic ligand precursor is at least a cation of a group IIB metal, a cation of a group IIIA element, a cation of a group IB metal, or a rare-earth metal cation,
wherein the ion-containing organic ligand precursor is prepared by mixing an ionic precursor and the organic ligand for a reaction in which the ions in the ionic precursor are combined with the organic ligand, and the organic ligand in the ion-containing organic ligand precursor is at least one of an organic phosphine, an organic amine, and an alkyl mercaptan.