Method and apparatus for applying magnetic fields to an article
Processes for applying magnetic fields to articles such as a layer or layer-coated articles, and more particularly to coatings having graphite particles, preferably for manufacture of negative electrodes having aligned graphite particles, for example for fast-charging lithium-ion batteries. The application of magnetic fields may be continuous. For this, magnetic tools with permanent magnets may be used for applying magnetic fields, wherein an article is moved relative to a magnetic tool. Application of magnetic field is made before the initiation of a drying phase and/or during a drying phase.
1. A method for producing an electrode for a lithium-ion battery, the method comprising the steps of:
coating a homogeneous layer of a slurry mixture including flake graphite particles, deionized water as volatile liquid, a binder mix that includes carboxymethylcellulose and styrene-butadiene rubber (SBR) latex binder, and a thermoresponsive constituent that has mass fraction in the range of 0.1% to 0.4% by weight over a metallic surface of a current collector foil to produce coated current collector foil:
transporting the coated current collector foil as transported, coated current collector foil on a production path;
subjecting the transported, coated current collector foil to a continuously applied time-varying magnetic field to produce, in the layer of slurry mixture, controlled alignment of the Hake graphite particles on their vertical axes; and
continuing to subject the transported, coated current collector foil to a magnetic field to maintain alignment of the flake graphite particles while simultaneously heating the transported, coated current collector foil to induce solidification and drying of the layer of slurry mixture to (a) preserve the alignment of the flake graphite particles and (b) prevent SBR latex binder migration.
2. The method for producing an electrode for a lithium-ion battery as claimed in claim 1 , wherein:
said step of subjecting the transported, coated current collector foil to a continuously applied time-varying magnetic field to produce, in the layer of slurry mixture, controlled alignment of the flake graphite particles on their vertical axes utilizes magnetic field flux density in the range of 0.1 to 0.5 T.
3. The method for producing an electrode for a lithium-ion battery as claimed in claim 1 , wherein:
said step of coating a homogeneous layer of a slurry mixture including flake graphite particles, deionized water as volatile liquid, a binder mix that includes carboxymethylcellulose and SBR latex binder, and a thermoresponsive constituent that has mass fraction in the range of 0.1% to 0.4% by weight over a metallic surface of a current collector foil to produce coated current collector foil utilizes a thermoresponsive constituent including at least one of either substituted or unsubstituted anhydroglucose rings.
4. The method for producing an electrode for a lithium-ion battery as claimed in claim 1 , wherein:
said step of coating a homogeneous layer of a slurry mixture including flake graphite particles, deionized water as volatile liquid, a binder mix that includes carboxymethylcellulose and SBR latex binder, and a thermoresponsive constituent that has mass fraction in the range of 0.1% to 0.4% by weight over a metallic surface of a current collector foil to produce coated current collector foil employs at least one thermoresponsive constituent selected from the group of thermoresponsive constituents consisting of methylcellulose, hydroxypropylcellulose, and Poly(N-Isopropylacrylamide).
5. The method for producing an electrode for a lithium-ion battery as claimed in claim 1 , wherein:
said step of coating a homogeneous layer of a slurry mixture including flake graphite particles, deionized water as volatile liquid, a binder mix that includes carboxymethylcellulose and SBR latex binder, and a thermoresponsive constituent that has mass fraction in the range of 0.1% to 0.4% by weight over a metallic surface of a current collector foil to produce coated current collector foil provides the homogeneous layer as a layer exhibiting a Lower Critical Solution Temperature (LCST) in the range of 30° C. to 60° C.
6. The method for producing an electrode for a lithium-ion battery as claimed in claim 1 , wherein:
said step of continuing to subject the transported, coated current collector foil to a magnetic field to maintain alignment of the flake graphite particles while simultaneously heating the transported, coated current collector foil to induce solidification and drying of the layer of slurry mixture to (a) preserve the alignment of the flake graphite particles and (b) prevent SBR latex binder migration removes less than 50% of the volatile liquid water.
7. The method for producing an electrode for a lithium-ion battery as claimed in claim 6 , wherein:
said step of continuing to subject the transported, coated current collector foil to a magnetic field to maintain alignment of the flake graphite particles while simultaneously heating the transported, coated current collector foil to induce solidification and drying of the layer of slurry mixture to (a) preserve the alignment of the flake graphite particles and (b) prevent SBR latex binder migration removes less than 10% of the volatile liquid water.
8. The method for producing an electrode for a lithium-ion battery as claimed in claim 1 , wherein:
said step of subjecting the transported, coated current collector foil to a continuously applied time-varying magnetic field to produce, in the layer of slurry mixture, controlled alignment of the flake graphite particles on their vertical axes includes subjecting the transported, coated current collector foil to a rotating magnetic field.
9. The method for producing an electrode for a lithium-ion battery as claimed in claim 1 , wherein:
said step of subjecting the transported, coated current collector foil to a continuously applied time-varying magnetic field to produce, in the layer of slurry mixture, controlled alignment of the flake graphite particles on their vertical axes includes moving the current collector foil in a direction parallel to a tangent to a surface of a magnetic tool.
10. The method for producing an electrode for a lithium-ion battery as claimed in claim 1 , wherein:
said step of continuing to subject the transported, coated current collector foil to a magnetic field to maintain alignment of the flake graphite particles while simultaneously heating the transported, coated current collector foil to induce solidification and drying of the layer of slurry mixture to (a) preserve the alignment of the flake graphite particles and (b) prevent SBR latex binder migration includes heating with IR-heaters.