Mica-made member, electrochemical reaction unit, and electrochemical reaction cell stack
A mica-made member having a crystal structure exhibiting an intensity peak of KMg 3 (Si 3 Al)O 10 (OH) 2 and an intensity peak of Mg 2 SiO 4 in X-ray diffractometry (XRD). Also disclosed is an electrochemical reaction unit including a structural member formed of the mica-made member and an electrochemical reaction cell stack.
1. An electrochemical reaction cell stack comprising a plurality of electrochemical reaction units arrayed in a first direction,
wherein at least one of the electrochemical reaction units is an electrochemical reaction unit,
the electrochemical reaction unit includes:
a unit cell including an electrolyte layer, and a cathode and an anode that face each other in a first direction with the electrolyte layer intervening therebetween; and
a structural member that faces a cathode chamber facing the cathode or an anode chamber facing the anode,
wherein the structural member is formed of a mica-made member that has been subjected to a heat treatment of 1,000° C. or higher for four or more hours so as to exhibit an intensity peak of KMg 3 (Si 3 Al)O 10 (OH) 2 and an intensity peak of Mg 2 SiO 4 in X-ray diffractometry (XRD), prior to assembling the structural member into the electrochemical reaction unit.
2. The electrochemical reaction cell stack according to claim 1 , wherein the ratio of the intensity of a peak of the (120) plane of Mg 2 SiO 4 to the intensity of a peak of the (003) plane of KMg 3 (Si 3 Al)O 10 (OH) 2 is 0.001 or more.
3. The electrochemical reaction cell stack according to claim 1 , wherein the ratio of the intensity of the peak of the (120) plane of Mg 2 SiO 4 to the intensity of the peak of the (003) plane of KMg 3 (Si 3 Al)O 10 (OH) 2 is 0.15 or less.
4. The electrochemical reaction cell stack according to claim 1 , wherein the ratio of the intensity of the peak of the (120) plane of Mg 2 SiO 4 to the intensity of the peak of the (003) plane of KMg 3 (Si 3 Al)O 10 (OH) 2 is 0.003 or more.
5. The electrochemical reaction cell stack according to claim 1 , wherein the ratio of the intensity of the peak of the (120) plane of Mg 2 SiO 4 to the intensity of the peak of the (003) plane of KMg 3 (Si 3 Al)O 10 (OH) 2 is 0.029 or less.
6. The electrochemical cell stack according to claim 1 , wherein the structural member formed of a mica-made member is subjected to heat treatment prior to assembly so as to reduce Si scattering of the mica upon operation of the assembled electrochemical reaction unit.