Magnesium oxide-containing spinel powder and method for producing same
Provided is a magnesium oxide-containing spinel powder capable of producing a ceramic sintered body having high strength and excellent strength stability. In the magnesium oxide-containing spinel powder, a 50% particle diameter (D50) is 0.30 to 10.00 μm, a ratio (D90-D50)/(D50-D10) of a difference between a 90% particle diameter (D90) and the 50% particle diameter (D50) and a difference between the 50% particle diameter (D50) and a 10% particle diameter (D10) is 1.0 to 5.0, and a composition ratio of Mg and Al in terms of an oxide equivalent content is 50 to 90% by weight of MgO and 10 to 50% by weight of Al 2 O 3 .
1. A magnesium oxide-comprising oxide containing spinel powder, which has a volume-based cumulative 50% particle diameter (D50) in a range of from 0.30 to 10.00 μm,
a ratio (D90-D50)/(D50-D10) of a difference between a volume-based cumulative 90% particle diameter (D90) and D50 to a difference between D50 and a volume-based cumulative 10% particle diameter (D10) in a range of from 1.0 to 5.0, and
a composition ratio of Mg and Al, in terms of an oxide equivalent content, of 50 to 90% by weight of MgO and 10 to 50% by weight of Al 2 O 3 , based on 100% by weight of both of MgO and Al 2 O 3
wherein D50, D90, and D10 are measured by a laser diffraction scattering particle size distribution measurement.
2. The magnesium oxide-comprising spinel powder of claim 1 , which has a loose bulk density in a range of from 0.20 to 1.50 g/cm 3 , and a tight bulk density in a range of from 0.30 to 2.50 g/cm 3 .
3. The magnesium oxide-comprising spinel powder of claim 1 , wherein a ceramic sintered body obtained by firing a molded product of the magnesium oxide-comprising spinel powder has a three-point bending strength of 150 MPa or more and a Weibull coefficient of 13.0 or more.
4. A method for producing the magnesium oxide-comprising spinel powder of claim 1 , the method comprising:
(i) mixing at least one kind of magnesium source particles selected from magnesium hydroxide particles, magnesium oxide particles, magnesium carbonate particles, basic magnesium carbonate particles, magnesium nitrate particles, magnesium acetate particles and magnesium sulfate particles, with at least one kind of aluminum source particles selected from aluminum hydroxide particles, aluminum oxide particles, aluminum carbonate particles, aluminum nitrate particles, aluminum acetate particles and aluminum sulfate particles, to obtain a mixture,
wherein the at least one kind of magnesium sources particles has a D50 in a range of from 0.50 to 100.00 μm, and
the at least one kind of aluminum source particles has a D50 in a range of from 0.30 to 15.00 μm;
(ii) calcining the mixture at a temperature in a range of from 900 to 1400° C. for 0.1 to 10.0 hours, to obtain a product; and
(iii) grinding the product.
5. A ceramic sintered body, obtained by firing a molded product of the magnesium oxide-comprising spinel powder of claim 1 and which has a three-point bending strength of 150 MPa or more and a Weibull coefficient of 13.0 or more.