Method for producing electrode catalyst, and electrode catalyst
This method for producing an electrode catalyst includes: a dispersion liquid preparation step wherein a dispersion liquid is prepared by mixing (i) at least one solvent selected from the group consisting of sulfoxide compounds and amide compounds, (ii) a catalyst carrier powder composed of a metal oxide, (iii) a platinum compound, (iv) a transition metal compound and (v) an aromatic compound that contains a carboxyl group; a loading step wherein the dispersion liquid is heated so that a platinum alloy of platinum and a transition metal is loaded on the surface of the catalyst carrier powder; a solid-liquid separation step wherein a dispersoid is separated from the dispersion liquid after the loading step, thereby obtaining a catalyst powder wherein the catalyst carrier powder is loaded with the platinum alloy; and a heat treatment step wherein the catalyst powder is heated under vacuum or in a reducing gas atmosphere.
1. A method for producing an electrode catalyst, the method comprising:
a dispersion preparation step of mixing (i) at least one solvent selected from the group consisting of sulfoxide compounds and amide compounds, (ii) a catalyst support powder comprising a metal oxide, (iii) a platinum compound, and (iv) a transition metal compound, to thereby prepare a dispersion;
a supporting step of heating the dispersion, to thereby support a platinum alloy of platinum and the transition metal on the catalyst support powder;
a solid-liquid separation step of separating a dispersoid from the dispersion after the supporting step, to thereby obtain a catalyst powder comprising the catalyst support powder and the platinum alloy supported thereon; and
a heat treatment step of heating the catalyst powder under vacuum or in a reducing gas atmosphere,
wherein the at least one solvent has a formamide group and the transition metal compound includes water of crystallization, and the dispersion is heated such that a formic acid species is formed by reacting the at least one solvent with the water of crystallization in the supporting step,
wherein water or a water-containing compound is added in the dispersion preparation step in an amount such that the amount of water in the dispersion is from 1×10 −2 to 5×10 −1 mol/L inclusive with respect to the volume of the solvent in the dispersion.
2. The method for producing an electrode catalyst as set forth in claim 1 , wherein the heat treatment step is performed under vacuum at a temperature equal to or higher than the heating temperature of the supporting step.
3. The method for producing an electrode catalyst as set forth in claim 2 , wherein the heating temperature of the supporting step is from 120° C. to 175° C. inclusive.
4. The method for producing an electrode catalyst as set forth in claim 2 , wherein, in the dispersion preparation step, an aromatic compound having a carboxyl group is further mixed.
5. The method for producing an electrode catalyst as set forth in claim 1 , wherein the heat treatment step is performed in a reducing gas atmosphere at a temperature below 200° C.
6. The method for producing an electrode catalyst as set forth in claim 5 , wherein the heating temperature of the supporting step is from 120° C. to 175° C. inclusive.
7. The method for producing an electrode catalyst as set forth in claim 5 , wherein, in the dispersion preparation step, an aromatic compound having a carboxyl group is further mixed.
8. The method for producing an electrode catalyst as set forth in claim 1 , wherein the heating temperature of the supporting step is from 120° C. to 175° C. inclusive.
9. The method for producing an electrode catalyst as set forth in claim 8 , wherein, in the dispersion preparation step, an aromatic compound having a carboxyl group is further mixed.
10. The method for producing an electrode catalyst as set forth in claim 1 , wherein, in the dispersion preparation step, an aromatic compound having a carboxyl group is further mixed.
11. The method for producing an electrode catalyst as set forth in claim 1 , wherein a total concentration of formic acid species present in the dispersion is from 1×10 −5 to 1 mol/L inclusive with respect to the volume of the solvent in the dispersion.