Method for preparing superabsorbent polymer
The present invention relates to a method for preparing a superabsorbent polymer having excellent absorption performance, and more specifically, to a method for preparing a superabsorbent polymer that can effectively inhibit the initiation of a polymerization reaction in a pipe, before being introduced into a polymerization reactor, thus preventing process trouble.
1. A method for preparing a superabsorbent polymer comprising:
A) introducing an oxygen-containing gas into an aqueous monomer mixture comprising water soluble ethylenically unsaturated monomers having acid groups of which at least a part are neutralized, a crosslinking agent, and a polymerization inhibitor that inhibits polymerization of the water soluble ethylenically unsaturated monomers in the presence of oxygen to form the aqueous monomer mixture into which the oxygen-containing gas is introduced;
B) transferring the aqueous monomer mixture into which the oxygen-containing gas is introduced to a polymerization reactor;
C) removing oxygen from the aqueous monomer mixture into which the oxygen-containing gas is introduced immediately before the aqueous monomer mixture into which the oxygen-containing gas is introduced is introduced into the polymerization reactor; and
D) progressing crosslinking polymerization of the water soluble ethylenically unsaturated monomers in the polymerization reactor, to form a hydrogel polymer comprising a first crosslinked polymer.
2. The method for preparing a superabsorbent polymer according to claim 1 , further comprising:
E) drying, grinding, and sieving the hydrogel polymer to form a base polymer powder; and
F) in the presence of a surface crosslinking solution, heat treating the base polymer powder to progress surface crosslinking, thus forming superabsorbent polymer particles.
3. The method for preparing a superabsorbent polymer according to claim 1 , wherein the aqueous monomer mixture is transferred and introduced into the polymerization reactor at a temperature of 40° C. to 90° C.
4. The method for preparing a superabsorbent polymer according to claim 1 , wherein the oxygen-containing gas is introduced into the aqueous monomer mixture such that a dissolved oxygen rate represented by Mathematical Formula 1 is greater than 1.0 and equal to or less than 2.5:
DO2/DO1 [Mathematical Formula 1]
wherein, in Mathematical Formula 1,
DO1 is the amount of dissolved oxygen in mg/L in the aqueous monomer mixture, measured immediately before introducing an oxygen-containing gas into the aqueous monomer mixture, and
DO2 is the amount of dissolved oxygen in Mg/L in the aqueous monomer mixture, measured immediately after introducing an oxygen-containing gas into the aqueous monomer mixture.
5. The method for preparing a superabsorbent polymer according to claim 1 , wherein during C) removing oxygen from the aqueous monomer mixture, an inert gas is introduced into the aqueous monomer mixture to remove oxygen.
6. The method for preparing a superabsorbent polymer according to claim 1 , wherein C) removing oxygen from the aqueous monomer mixture is progressed such that a dissolved oxygen rate represented by the following Mathematical Formula 2 is 0.01 to 0.5:
DO3/DO2 [Mathematical Formula 2]
wherein, in the Mathematical Formula 2,
DO2 is the amount of dissolved oxygen in mg/L in the aqueous monomer mixture, measured immediately after introducing an oxygen-containing gas into the aqueous monomer mixture, and
DO3 is the amount of dissolved oxygen in mg/L in the aqueous monomer mixture, measured immediately after removing oxygen from the aqueous monomer mixture.
7. The method for preparing a superabsorbent polymer according to claim 1 , further comprising introducing a thermal polymerization initiator into the aqueous monomer mixture, after removing oxygen from the aqueous monomer mixture and before progressing crosslinking polymerization of the water soluble ethylenically unsaturated monomers in the polymerization reactor.
8. The method for preparing a superabsorbent polymer according to claim 1 , wherein the polymerization inhibitor is included in a content of 10 ppmw to 300 ppmw, based on a weight of the water soluble ethylenically unsaturated monomers having acid groups of which at least a part are neutralized.
9. The method for preparing a superabsorbent polymer according to claim 1 , wherein the superabsorbent polymer has centrifuge retention capacity (CRC) of 30 g/g or more, and absorbency under pressure of 0.7 psi of 15 g/g or more.
10. The method for preparing a superabsorbent polymer according to claim 1 , wherein the water soluble ethylenically unsaturated monomers are added in an amount of 20 to 90 wt % based on the aqueous monomer mixture.
11. The method for preparing a superabsorbent polymer according to claim 1 , wherein the crosslinking agent is added in an amount of about 0.001 to about 1 part by weight, based on 100 parts by weight of the water soluble ethylenically unsaturated monomers.
12. The method for preparing a superabsorbent polymer according to claim 7 , wherein the thermal polymerization initiator is introduced in an amount of about 0.05 to about 0.5 parts by weight, based on 100 parts by weight of the ethylenically unsaturated monomers.