Thermally conductive composite silicone rubber sheet and method for manufacturing same
Provided is a thermally conductive composite silicone rubber sheet formed by laminating an acrylic pressure-sensitive adhesive layer on one side of a non-pressure-sensitive adhesive/high-hardness thermally conductive silicone rubber sheet, wherein the acrylic pressure-sensitive adhesive layer is a cured product of an acrylic pressure-sensitive adhesive composition containing: an acrylic pressure-sensitive adhesive made of a polymer of a monomer mixture in which 5-50 mol % of hydroxyl group-containing monomers are contained in all of the constituent monomers; and 0.05-5 parts by mass of a chelate-based curing agent with respect to 100 parts by mass of the acrylic pressure-sensitive adhesive, and the thermally conductive silicone rubber sheet has a thermally conductive silicone rubber layer which, as a cured product of a thermally conductive silicone composition containing a thermally conductive filler, has a durometer A hardness of 60-96.
1. A method for preparing a heat-conductive composite silicone rubber sheet,
the heat-conductive composite silicone rubber sheet comprising a non-adhesive high hardness heat-conductive silicone rubber sheet and an acrylic pressure-sensitive adhesive layer laid on one surface of the silicone rubber sheet,
the non-adhesive high hardness heat-conductive silicone rubber sheet including
a heat-conductive silicone rubber layer which is a cured product of a heat-conductive silicone composition containing a heat conductive filler, the cured product having a hardness of 60 to 96 on Durometer A scale and
an intermediate reinforcing layer, and
the acrylic pressure-sensitive adhesive layer being a cured product of an acrylic pressure-sensitive adhesive composition comprising 100 parts by weight of an acrylic pressure-sensitive adhesive composed of a polymer obtained from a monomer mixture containing 5 to 50 mol % of a hydroxyl-containing monomer, and 0.05 to 5 parts by weight of a chelate curing agent,
the method comprising the steps of:
applying the heat-conductive silicone composition onto front surface and back surface of the intermediate reinforcing layer, and heat curing the heat-conductive silicone composition to obtain the non-adhesive high-hardness heat-conductive silicone rubber, and
directly applying the acrylic pressure-sensitive adhesive composition comprising an acrylic pressure-sensitive adhesive and a chelate curing agent onto one surface of the obtained non-adhesive high-hardness heat-conductive silicone rubber sheet, and heat curing the acrylic pressure-sensitive adhesive composition for shaping.
2. The method of claim 1 , wherein the acrylic pressure-sensitive adhesive composition further comprises 0.05 to 5 parts by weight of a tackifier resin.