Electrochemical hydrogen peroxide generating device
A membrane-free electrochemical reactor and fuel-cell having a collection chamber between a first and second chamber, a mesoporous carbon paper cathode between the first chamber and the collection chamber, a mesoporous carbon paper anode between the second chamber and the collection chamber, the cathode is coated with an oxygen reduction reaction catalyst that imparts a two-electron partial reduction reaction to hydrogen peroxide, the anode is coated with an oxygen evolution reaction coating or a hydrogen oxidation reaction coating, oxygen/air input and output ports connected to the first chamber, KOH/water input and output ports connected to the second chamber that are in an open state under an electrolyzer mode, H 2 /water input and output ports connected to the second chamber that are in an open state under a fuel-cell mode, a second KOH/water input port connected to the collection chamber, and a hydrogen peroxide/KOH/water output port connected to the collection chamber.
1. A membrane-free electrochemical reactor, comprising:
a) a collection chamber disposed between a cathode chamber and an anode chamber, wherein said cathode chamber and said anode chamber are sealably connected to said collection chamber;
b) a mesoporous carbon paper cathode, and a mesoporous carbon paper anode, wherein said mesoporous carbon paper cathode is disposed between said cathode chamber and said collection chamber, wherein said mesoporous carbon paper anode is disposed between said anode chamber and said collection chamber, wherein said mesoporous carbon paper cathode is coated with an Oxygen Reduction Reaction (ORR) catalyst; wherein the ORR catalyst is positioned on a side of the mesoporous carbon paper cathode facing the collection chamber, wherein said ORR catalyst imparts a two-electron partial reduction reaction to hydrogen peroxide, wherein said mesoporous carbon paper anode is coated with an Oxygen Evolution Reaction (OER) coating; wherein the OER coating is positioned on a side of the mesoporous carbon paper anode facing the anode chamber;
c) an oxygen input port, and an oxygen output port, wherein said oxygen input port is connected to said cathode chamber, wherein said oxygen output port is connected to said cathode chamber;
d) a water input port, and a water output port, wherein said water input port is connected to said anode chamber, wherein said water output port is connected to said anode chamber, wherein said water input port and said water output port are in an open state;
e) a second water input port connected to said collection chamber; and
f) a hydrogen peroxide output port connected to said collection chamber.
2. The membrane-free electrochemical reactor of claim 1 , wherein said Oxygen Evolution Reaction (OER) coating is stable during operation of said electrochemical reactor.
3. The membrane-free electrochemical reactor of claim 1 , wherein said mesoporous carbon paper cathode is coated with a conductive layer comprising a high surface area catalyst support material.
4. The membrane-free electrochemical reactor of claim 3 , wherein said mesoporous carbon paper cathode is coated with CMK-3.