IP Library Granted Patent US 11,161,996
Granted Patent B2
US 11,161,996 · App. 16/345,089 · Granted Nov 2, 2021

Printed electronics

Inventors: Xiangyang Liu (Nepean, CA); Olga Mozenson (Ottawa, CA); Bhavana Deore (Ottawa, CA); Chantal Paquet (Ottawa, CA); Arnold Kell (Ottawa, CA); Patrick Malenfant (Orleans, CA); Julie Ferrigno (Montreal, CA); Olivier Ferrand (Montreal, CA); Jian Xiong Hu (Saint-Laurent, CA); Sylvie Lafreniere (Montreal, CA); Reza Chaharmir (Kanata, CA); Jonathan Ethier (Carlsbad Springs, CA); Khelifa Hettak (Ottawa, CA); Jafar Shaker (Ottawa, CA); Adrian Momciu (Ottawa, CA)
Assignees: E2IP TECHNOLOGIES INC.; NATIONAL RESEARCH COUNCIL OF CANADA; HER MAJESTY THE QUEEN IN RIGHT OF CANADA (...)
C09D11/52B64D15/12C09D11/037C09D11/10H01L23/4985H01L23/49883H01L31/022466H01M10/052H01M10/615H01M10/625H05B3/26H05B33/06H05K1/0283H05K1/095H05K1/16H05K1/162H05K1/165G06F3/045G06F3/0443G06F3/0446G06F2203/04102H01M2220/20H05K2201/10113H05K2201/10143H05K2201/10151
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Quick Facts
Patent No.
US 11,161,996
App. No.
16/345,089
Granted
Nov 2, 2021
Kind
B2
Abstract

The present invention relates to an electronic device comprising a printed substrate comprising a trace of molecular ink thereon, the molecular ink being sintered to form a conductive metal trace forming the electronic device, wherein the molecular ink is chosen from a) a flake-less printable composition of 30-60 wt % of a C 8 -C 12 silver carboxylate, 0.1-10 wt % of a polymeric binder and balance of at least one organic solvent, all weights based on total weight of the composition; or b) a flake-less printable composition of 5-75 wt % of bis(2-ethyl-1-hexylamine) copper (II) formate, bis(octylamine) copper (II) formate or tris(octylamine) copper (II) formate, 0.25-10 wt % of a polymeric binder and balance of at least one organic solvent, all weights based on total weight of the composition.

Claims (31)

1. An electronic device comprising a printed substrate comprising a trace of molecular ink thereon, the molecular ink being sintered to form a conductive metal trace forming the electronic device, wherein the molecular ink is chosen from:

a) a flake-less printable composition of 30-60 wt % of a C 8 -C 12 silver carboxylate, 0.1-10 wt % of a polymeric binder and balance of at least one organic solvent, all weights based on total weight of the composition; or

b) a flake-less printable composition of 5-75 wt % of bis(2-ethyl-1-hexylamine) copper (II) formate, bis(octylamine) copper (II) formate or tris(octylamine) copper (II) formate, 0.25-10 wt % of a polymeric binder and balance of at least one organic solvent, all weights based on total weight of the composition,

wherein the molecular ink is stretchable and thermoformable, and

wherein the molecular ink is printed as an in-mold electronic device.

2. The electronic device of claim 1 , wherein the electronic device comprises an inductor.

3. The electronic device of claim 1 , wherein the electronic device comprises a capacitor.

4. The electronic device of claim 1 , wherein the electronic device is printed as a solar cell.

5. The electronic device of claim 1 , wherein the electronic device is printed as a transparent electrode.

6. The electronic device of claim 1 , wherein the electronic device is printed as an electroluminescent lamp.

7. The electronic device of claim 1 , wherein the electronic device is printed as a wearable electronic device.

8. The electronic device of claim 1 , wherein the electronic device is printed as one of a physicochemical and an electromechanical sensor.

9. The electronic device of claim 1 , wherein the electronic device is printed as an in-mold resistive electrical circuit.

10. The electronic device of claim 1 , wherein the electronic device is installed on a portion of an aircraft.

11. The electronic device of claim 1 , wherein the electronic device is installed on a wing of an aircraft to heat the wing.

12. The electronic device of claim 1 , wherein the trace of molecular ink is stretchable and thermoformable.

13. The electronic device of claim 1 , wherein the molecular ink is sintered to form the conductive metal trace with the conductive metal trace forming a part of the in-mold electronic device.

14. A heater comprising an electronic device comprising a printed substrate with a trace of molecular ink thereon, the molecular ink being sintered to form a conductive metal trace forming the electronic device, wherein the molecular ink is chosen from:

a) a flake-less printable composition of 30-60 wt % of a C 8 -C 12 silver carboxylate, 0.1-10 wt % of a polymeric binder and balance of at least one organic solvent, all weights based on total weight of the composition; or

b) a flake-less printable composition of 5-75 wt % of bis(2-ethyl-1-hexylamine) copper (II) formate, bis(octylamine) copper (II) formate or tris(octylamine) copper (II) formate, 0.25-10 wt % of a polymeric binder and balance of at least one organic solvent, all weights based on total weight of the composition,

wherein the trace of molecular ink is stretchable and thermoformable, and

wherein the molecular ink is printed as an in-mold electronic device.

15. The heater of claim 14 , wherein the molecular ink is sintered to form the conductive metal trace with the conductive metal trace forming a part of the in-mold electronic device.

16. A touch interface comprising a printed substrate comprising a trace of molecular ink thereon, the molecular ink being sintered to form a conductive metal trace forming a transparent conductive film, wherein the molecular ink is chosen from:

a) a flake-less printable composition of 30-60 wt % of a C 8 -C 12 silver carboxylate, 0.1-10 wt % of a polymeric binder and balance of at least one organic solvent, all weights based on total weight of the composition; or

b) a flake-less printable composition of 5-75 wt % of bis(2-ethyl-1-hexylamine) copper (II) formate, bis(octylamine) copper (II) formate or tris(octylamine) copper (II) formate, 0.25-10 wt % of a polymeric binder and balance of at least one organic solvent, all weights based on total weight of the composition,

wherein the trace of molecular ink is stretchable, thermoformable, and is able to undergo elongation greater than 50% without significant decrease in electric performance, and

wherein the molecular ink is printed as an in-mold electronic device.

17. The touch interface of claim 16 , further comprising printed capacitive or resistive elements.

18. The touch interface of claim 16 , further comprising a capacitive micro-wire, wherein the capacitive micro-wire comprises a grid or pattern of printed silver electrodes and the substrate is flexible.

19. The touch interface of claim 16 , wherein the molecular ink is sintered to form the conductive metal trace with the conductive metal trace forming a part of the in-mold electronic device.

Assignments (5)
CHANGE OF NAME Recorded May 27, 2021
From: GROUPE GRAHAM INTERNATIONAL INC.
To: E2IP TECHNOLOGIES INC.
Reel/Frame 056408/0451 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 16, 2020
From: LIU, XIANGYANG; KELL, ARNOLD J.; DEORE, BHAVANA; PAQUET, CHANTAL; MOZENSON, OLGA; MALENFANT, PATRICK ROLAND LUCIEN
To: NATIONAL RESEARCH COUNCIL OF CANADA
Reel/Frame 052419/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 29, 2019
From: LIU, XIANGYANG; MOZENSON, OLGA; DEORE, BHAVANA; PAQUET, CHANTAL; KELL, ARNOLD; MALENFANT, PATRICK
To: NATIONAL RESEARCH COUNCIL OF CANADA
Reel/Frame 049016/0251 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 29, 2019
From: CHAHARMIR, REZA; ETHIER, JONATHAN; HETTAK, KHELIFA; MOMCIU, ADRIAN
To: HER MAJESTY THE QUEEN IN RIGHT OF CANADA, AS REPRESENTED BY THE MINISTER OF INDUSTRY, THROUGH THE COMMUNICATIONS RESEARCH CENTRE CANADA
Reel/Frame 049016/0314 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 29, 2019
From: FERRIGNO, JULIE; FERRAND, OLIVIER; HU, JIAN XIONG; LAFRENIERE, SYLVIE
To: GGI INTERNATIONAL
Reel/Frame 049016/0400 →
Continuity (2)
Provisional Application 62412536 · Oct 25, 2016
Related Publication 20190284422A1 · Sep 19, 2019