Process for obtaining thermoplastic composite pellets reinforced with cellulose pulp and additive cellulose pulp
The present invention refers to a process for obtaining thermoplastic composite pellets reinforced with cellulose pulp or additive cellulose pulp, cellulose fibers, and/or hydrophilic material from renewable source, and/or natural source material comprising the steps of cellulose pulp dry processing carried out in a binder mill, and/or plastic agglomerator and/or densifier, and preparation of the masterbach comprising the steps of drying the pulp and the thermoplastic materials, preparing the compositions of polymer and cellulose fiber, milling the masterbatch produced, drying the product, extruding the polymer and the masterbatch, and injecting the obtained material.
1. Process for obtaining thermoplastic composite pellets reinforced with cellulose pulp comprising the steps of:
a) cellulose pulp milling carried out in a knife mill consisting of a tube in which the cellulose pulp is milled by an axle with knives comprised within said tube;
b) preparing a masterbatch consisting of the mixture of the milled cellulose pulp of step a) and a thermoplastic polymer in a mixing chamber at a temperature ranging from about 90° C. to about 300° C. by:
b.1) adding and melting the thermoplastic polymer in the mixing chamber; and
b.2) after complete melting of the thermoplastic polymer, adding the milled cellulose pulp of step a) into the mixing chamber;
wherein the masterbatch comprises a thermoplastic polymer and the milled cellulose pulp of step a) at a ratio of 10/90 to 90/10;
c) milling the masterbatch of step b) into the knife mill;
d) drying the milled masterbatch produced in step c) for 1 to 48 hours at 30° C. to 100° C.; and
e) obtaining the thermoplastic composite pellets reinforced with cellulose pulp by means of the extrusion of the dried masterbatch of step e) and an additional thermoplastic polymer through a twin screw extruder using two gravimetric feeders, one for each product, with speeds ranging from 10 to 400 rpm and temperatures from about 90° C. to about 300° C.
2. Process, according to claim 1 , wherein the mixing chamber of step b) is coupled to a torque rheometer.
3. Process, according to claim 2 , wherein in step b.2), the milled cellulose pulp is added in steps into the mixing chamber in line with the torque variation of the torque rheometer in order to achieve clarity of dispersion and homogeneity of the masterbatch.
4. Process, according to claim 1 , wherein step b) further includes the addition of at least one compatibilizer for preparing the masterbatch, and wherein said at least one compatibilizer is selected from the group consisting of maleic anhydride and additives.
5. Process, according to claim 4 , wherein the at least one compatibilizer is lignin or nanocellulose.
6. Process, according to claim 1 , further including addition of at least one pigment for preparing the masterbatch.
7. Process, according to claim 1 , further comprising prior to step b) a step of separately drying the milled cellulose pulp of step a) and the thermoplastic polymer for 1 to 48 hours at 30° C. to 100° C.