IP Library › Granted Patent US 11,040,561
Granted Patent B2
US 11,040,561 · App. 16/351,588 · Granted Jun 22, 2021

Ink and processing liquid set, image forming method, and image forming device

Inventors: Takashi Tamai (Kanagawa, JP); Dongsik Jang (Tokyo, JP); Atsufumi Hanazawa (Tokyo, JP); Satoshi Takahashi (Kanagawa, JP); Yoshiki Yanagawa (Telford, GB); Tsutomu Maekawa (Ibaraki, JP); Yukitaka Watarai (Ebina, JP)
Assignee: Ricoh Company, Ltd.
B41M5/0023B41J11/0015C09D11/102C09D11/107C09D11/54
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Quick Facts
Patent No.
US 11,040,561
App. No.
16/351,588
Granted
Jun 22, 2021
Kind
B2
Abstract

An ink and processing liquid set contains a processing liquid to be applied to a recording medium, the processing liquid including a multivalent metal salt and an ink to be applied to an area of the recording medium where the processing liquid has been applied, the ink including a urethane resin, a styrene-acrylic resin, and a pigment, wherein the following relations are satisfied: 0.5≤B/C≤0.7, where B represents a static surface tension of the ink and C represents a static surface tension of the processing liquid; and 0.5≤E/D≤0.9, and 35 (mN/m)≤E≤55 (mN/m), where D represents a dynamic surface tension at 15 ms of the processing liquid and E represents a dynamic surface tension at 1500 ms of the processing liquid.

Claims (41)

1. An ink and processing liquid set comprising:

a processing liquid to be applied to a recording medium, the processing liquid comprising a multivalent metal salt; and

an ink to be applied to an area of the recording medium where the processing liquid has been applied, the ink comprising a urethane resin, a styrene-acrylic resin, and a pigment,

wherein the following relations are satisfied:

0.5≤B/C≤0.7, where B represents a static surface tension of the ink and C represents a static surface tension of the processing liquid; and

0.5≤E/D≤0.9, and 35 (mN/m) ≤E≤55 (mN/m), where D represents a dynamic surface tension at 15 ms of the processing liquid and E represents a dynamic surface tension at 1500 ms of the processing liquid.

2. The set according to claim 1 , wherein the urethane resin has a volume average particle diameter of from 10 to 30 nm.

3. The set according to claim 1 , wherein the styrene-acrylic resin has a volume average particle diameter of from 40 to 60 nm.

4. The set according to claim 1 , wherein the multivalent metal salt comprises at least one member selected from the group consisting of magnesium salts and calcium salts.

5. The set according to claim 1 , wherein the multivalent metal salt accounts for 10 to 40 percent by mass of the processing liquid.

6. The set according to claim 1 , wherein the urethane resin accounts for 1.0 to 5.0 percent by mass of the ink.

7. The set according to claim 1 , wherein the styrene-acrylic resin accounts for 1.0 to 10.0 percent by mass of the ink.

8. The set according to claim 1 , wherein the ink comprises a surfactant represented by the following Chemical formula 1,

C 6 F 13 —CH 2 CH 2 O(CH 2 CH 2 O) n H  Chemical formula 1

where n represents an integer of from 1 to 40.

9. The set according to claim 1 , wherein the urethane resin has a glass transition temperature Tg of 60 degrees C. or lower.

10. The set according to claim 1 , wherein the following relation is satisfied: 1.5≤A/B≤2, where A represents a dynamic surface tension at 15 ms of the ink.

11. The set according to claim 1 , wherein the following relation is satisfied: 1.5≤Y/X≤4, where X represents an initial viscosity of the processing liquid and Y represents a viscosity of the processing liquid at 10 percent moisture evaporation.

12. The set according to claim 1 , wherein the ink comprises black ink, cyan ink, and yellow ink.

13. An image forming method, comprising:

applying a processing liquid to a recording medium; and

applying ink to an area of the recording medium where the processing liquid has been applied,

wherein the processing liquid comprises a multivalent metal salt and the ink comprises a urethane resin, a styrene-acrylic resin, and a pigment, and

wherein the following relations are satisfied:

0.5≤B/C≤0.7, where B represents a static surface tension of the ink and C represents a static surface tension of the processing liquid; and

0.5≤E/D≤0.9, and 35 (mN/m)≤E≤55 (mN/m), where D represents a dynamic surface tension at 15 ms of the processing liquid and E represents a dynamic surface tension at 1500 ms of the processing liquid.

14. The image forming method according to claim 13 , wherein the urethane resin has a volume average particle diameter of from 10 to 30 nm.

15. The image forming method according to claim 13 , wherein the styrene-acrylic resin has a volume average particle diameter of from 40 to 60 nm.

16. The image forming method according to claim 13 , wherein the multivalent metal salt comprises at least one member selected from the group consisting of magnesium salts and calcium salts.

17. The image forming method according to claim 13 , wherein the multivalent metal salt accounts for 10 to 40 percent by mass of the processing liquid.

18. The image forming method according to claim 13 , wherein the urethane resin accounts for 1.0 to 5.0 percent by mass of the ink.

19. The image forming method according to claim 13 , wherein the styrene-acrylic resin accounts for 1.0 to 10.0 percent by mass of the ink.

20. A image forming device, comprising:

a processing liquid;

an ink;

a processing liquid application device configured to apply the processing liquid to a recording medium; and

an ink application device configured to apply the ink to an area of the recording medium where the processing liquid has been applied,

wherein the processing liquid comprises a multivalent metal salt and the ink comprises a urethane resin, a styrene-acrylic resin, and a pigment, and

wherein the following relations are satisfied:

0.5≤B/C≤0.7, where B represents a static surface tension of the ink and C represents a static surface tension of the processing liquid; and

0.5≤E/D≤0.9, and 35 (mN/m) ≤E≤55 (mN/m), where D represents a dynamic surface tension at 15 ms of the processing liquid and E represents a dynamic surface tension at 1500 ms of the processing liquid.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 13, 2019
From: TAMAI, TAKASHI; JANG, DONGSIK; HANAZAWA, ATSUFUMI; TAKAHASHI, SATOSHI; YANAGAWA, YOSHIKI; MAEKAWA, TSUTOMU; WATARAI, YUKITAKA
To: RICOH COMPANY, LTD.
Reel/Frame 048580/0604 →
Priority Claims (2)
JP JP2018-048211 · Mar 15, 2018 · national
JP JP2018-230085 · Dec 7, 2018 · national
Continuity (1)
Related Publication 20190283479A1 · Sep 19, 2019