Enzymatically and hydrolytically stable dental preventive and restorative systems

1. A dental composite restorative system, comprising:

a polymerized resin monomer comprising at least one functionalized vinylbenzyl ether component,

wherein the functionalized vinylbenzyl ether component comprises elements chosen from a first group consisting of a hydrogen and one or more functional moieties, and

wherein the functional moieties consist of one or more elements chosen from a second group consisting of: —CH 3 , —C 2 H 5 , —OCH 3 , —CF 3 , —F, —Cl, —Br, —CN, —C 2 H 5 , —C 3 H 7 , —C 4 H 9 , —OC 2 H 5 , —OC 3 H 7 , and —OC 4 H 9 ;

each functionalized vinylbenzyl ether component covalently connected to a functional component;

the functional component is selected from a third group consisting of:

one or more hydroxyl methyl (—CHOH—) moieties and/or derivatives thereof,

one or more ethoxy (—CH 2 —CH 2 —O—) moieties and/or derivatives thereof, and

one or more benzene derivatives; and

one or more of a silane coupling agent, a reinforcing filler, and a surface active monomer.

2. The dental composite restorative system of claim 1 used as laminate veneers, denture repairing materials, dental adhesives, resin reinforce cements, placement of ceramic restorations, and sealants.

3. A dental composite restorative system, comprising:

a polymerized composition formed by polymerization of a monomer composition, the monomer composition, comprising:

one or more functionalized vinylbenzyl components of the formula

wherein n is an integer equal to or greater than 1, and one or more R functional components, and

ether links connecting the one or more functionalized vinylbenzyl components and the one or more R functional components,

wherein the one or more R functional components are selected from a first group consisting of one or more hydroxyl methyl (—CHOH—) moieties and/or derivatives thereof, one or more ethoxy (—CH 2 —CH 2 —O—) moieties and/or derivatives thereof, and one or more benzene derivatives and from a sixth croup consisting of:

N-(2-hydroxypropyl)-N-(p-styryl)glycine,

N-(2-hydroxypropyl)-N-(phenyl)glycine,

N-(2-hydroxypropyl)-N-(p-tolyl)glycine,

N-(2-hydroxypropyl)-N-(3,5-dimethylphenyl)glycine, and

N-(2-hydroxypropyl)-N-(vinylbenzyl)glycine, wherein each member of the sixth group may be acidic, anionic, or a salt of one or more members of a seventh group consisting of sodium, magnesium, calcium and strontium wherein X is chosen from a second group consisting of a hydrogen and one or more functional moieties; wherein the functional moieties consist of one or more elements chosen from a third group consisting of: —CH3, —C2H5, —OCH3, —CFs, —F, —Cl, —Br, —CN, —C2H5, —C3H7, —C4H9, —OC2H5, —OC3H7, and —OC4H9.

4. The dental composite restorative system of claim 3 , wherein the ether links comprise one or more moieties chosen from a second group consisting of alkyl (—CH 2 —, —CH 2 CH 2 —, —C 3 H 6 —, —C(i-propyl) 2 -, and —C 4 H 8 —); alkoxy (—OCH 2 —, —CH 2 CH 2 O—, —OC 3 H 6 —, and —OC 4 H 8 —); —C(CN) 2 —; hydroxyl substituted alkyl (—(CHOH)—); and halide substituted alkyl (—C(CCl 3 ) 2 —, —C(CBr 3 ) 2 —, and —C(CF 3 ) 2 —).

5. The dental composite restorative system of claim 3 , wherein the X components are one of a hydrogen atom and one or more functional moieties to accelerate or slow down the rate of polymerization, the functional moieties being one or more compounds or elements chosen from a third group consisting of —CH 3 , —C 2 H 5 , —OCH 3 , —CF 3 , —F, —Cl, —Br, —CN, —C 2 H 5 , —C 3 H 7 , —C 4 H 9 , —OC 2 H 5 , —OC 3 H 7 , and —OC 4 H 9 .

6. The dental composite restorative system of claim 3 , wherein the R functional components further comprise one or multiple ethoxy (—CH 2 —CH 2 —O—) moieties and their derivatives, and wherein, the ether links are formed through reaction of halide(s) and alcohol(s) in the presence of a strong base.

7. The dental composite restorative system of claim 3 , wherein the R functional components contain hydroxyl methyl (—CHOH—) moieties, and the ether links are formed through reactions of functionalized vinylbenzyl halides and primary hydroxyl moieties of one of the compounds of a fourth group consisting of glycerol, erythritol, xylitol, mannitol, and sorbitol, in the presence of a strong base, and wherein the secondary hydroxyl group(s) are protected by protection groups while the ether links are formed, and the protection groups are removed after the ether links are formed.

8. The dental composite restorative system of claim 3 , wherein the R functional components contain hydroxyl methyl (—CHOH—) moieties and the ether links are formed through reactions of functionalized vinylbenzyl halides and hydroxyl moieties of one of the compounds of a fifth group consisting of glycerol, erythritol, xylitol, mannitol, and sorbitol, in the presence of a strong base, wherein the mole amount(s) of functionalized vinylbenzyl halides is adjusted to be within a range of the mole amount of primary hydroxyls and the mole amount of primary hydroxyls plus secondary hydroxyl methyl (—CHOH—) moieties.

9. The dental composite restorative of claim 3 , wherein the ether link is formed from a reaction of functionalized vinylbenzyl glycidyl ether with members of an eighth group consisting of:

N(H)-(p-styryl) glycine,

N(H)-(phenyl) glycine,

N(H)-(p-tolyl) glycine,

N(H)-(3,5-dimethylphenyl) glycine, and

N(H)-(vinylbenzyl) glycine, wherein each member of the eighth group may be anionic or a salt of one or more members of a ninth group consisting of sodium, magnesium, calcium and strontium.

10. The dental composite restorative of claim 6 , wherein the strong base is sodium hydride.

11. The dental composite restorative of claim 7 , wherein the strong base is sodium hydride.

12. The dental composite restorative of claim 8 , wherein the strong base is sodium hydride.

13. A dental composite restorative system, comprising:

a polymerized composition formed by polymerization of a monomer composition, the monomer composition, comprising:

one or more functionalized vinylbenzyl components of the formula

wherein n is an integer equal to or greater than 1, and one or more R functional components, and

ether links connecting the one or more functionalized vinylbenzyl components and the one or more R functional components,

wherein the one or more R functional components are selected from a first group consisting of one or more hydroxyl methyl (—CHOH—) moieties and/or derivatives thereof, one or more ethoxy (—CH 2 —CH 2 —O—) moieties and/or derivatives thereof, and one or more benzene derivatives; and

wherein the ether link is formed from a reaction of functionalized vinylbenzyl glycidyl ether with members of an eighth group consisting of:

N(H)-(p-styryl) glycine,

N(H)-(phenyl) glycine,

N(H)-(p-tolyl) glycine,

N(H)-(3,5-dimethylphenyl) glycine, and

N(H)-(vinylbenzyl) glycine, wherein each member of the eighth group may be anionic or a salt of one or more members of a ninth group consisting of sodium, magnesium, calcium and strontium wherein X is chosen from a second group consisting of a hydrogen and one or more functional moieties; wherein the functional moieties consist of one or more elements chosen from a third group consisting of: —CH3, —C2H5, —OCH3, —CFs, —F, —Cl, —Br, —CN, —C2H5, —C3H7, —C4H9, —OC2H5, —OC3H7, and —OC4H9.