IP Library Granted Patent US 10,923,500
Granted Patent B2
US 10,923,500 · App. 16/360,932 · Granted Feb 16, 2021

Memory device

Inventors: Tsunehiro Ino (Fujisawa Kanagawa, JP); Yuuichi Kamimuta (Yokkaichi Mie, JP)
Assignee: TOSHIBA MEMORY CORPORATION
H01L27/1159H01L27/11507H01L27/11597H01L27/2463
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Quick Facts
Patent No.
US 10,923,500
App. No.
16/360,932
Granted
Feb 16, 2021
Kind
B2
Abstract

A memory device according to an embodiment includes a first conductive layer, a second conductive layer, and a first layer provided between the first conductive layer and the second conductive layer and containing aluminum oxide that contains at least one first element selected from the group consisting of magnesium (Mg), silicon (Si), hafnium (Hf), tungsten (W), and ruthenium (Ru), and the aluminum oxide is a ferroelectric.

Claims (47)

1. A memory device comprising:

a first conductive layer;

a second conductive layer; and

a first layer provided between the first conductive layer and the second conductive layer, the first layer including aluminum oxide, the aluminum oxide containing ruthenium (Ru), and the aluminum oxide being a ferroelectric.

2. The memory device according to claim 1 , wherein a thickness of the first layer is more than or equal to 1 nm and less than or equal to 15 nm.

3. The memory device according to claim 1 , wherein a c-axis direction of the aluminum oxide in the first layer is within a range of ±10° with respect to a direction from the first conductive layer to the second conductive layer.

4. The memory device according to claim 1 , further comprising a second layer provided between the first conductive layer and the first layer, the second layer containing at least one of oxide and oxynitride.

5. The memory device according to claim 1 , wherein the first conductive layer is a semiconductor layer.

6. A memory device comprising:

a first conductive layer;

a second conductive layer; and

a first layer provided between the first conductive layer and the second conductive layer, the first layer including aluminum oxide, the aluminum oxide containing at least one first element selected from the group consisting of magnesium (Mg), silicon (Si), hafnium (Hf), tungsten (W), and ruthenium (Ru), and the aluminum oxide being a ferroelectric,

wherein the aluminum oxide contains at least one second element selected from the group consisting of manganese (Mn), chromium (Cr), and cobalt (Co).

7. The memory device according to claim 6 , wherein the first conductive layer is a semiconductor layer.

8. A memory device comprising:

a first conductive layer;

a second conductive layer; and

a first layer provided between the first conductive layer and the second conductive layer, the first layer including aluminum oxide, the aluminum oxide containing at least one first element selected from the group consisting of magnesium (Mg), silicon (Si), hafnium (Hf), tungsten (W), and ruthenium (Ru), and the aluminum oxide being a ferroelectric,

wherein the aluminum oxide contains at least one second element selected from the group consisting of sulfur (S) and chlorine (Cl).

9. The memory device according to claim 8 , wherein the first conductive layer is a semiconductor layer.

10. A memory device comprising:

a first conductive layer;

a second conductive layer; and

a first layer provided between the first conductive layer and the second conductive layer, the first layer including aluminum oxide, the aluminum oxide containing ruthenium (Ru), and the aluminum oxide being κ (kappa)-aluminum oxide.

11. The memory device according to claim 10 , wherein a thickness of the first layer is more than or equal to 1 nm and less than or equal to 15 nm.

12. The memory device according to claim 10 , wherein a c-axis direction of the aluminum oxide in the first layer is within a range of ±10° with respect to a direction from the first conductive layer to the second conductive layer.

13. The memory device according to claim 10 , further comprising a second layer provided between the first conductive layer and the first layer, the second layer containing at least one of oxide and oxynitride.

14. The memory device according to claim 10 , wherein the first conductive layer is a semiconductor layer.

15. A memory device comprising:

a first conductive layer;

a second conductive layer; and

a first layer provided between the first conductive layer and the second conductive layer, the first layer including aluminum oxide, the aluminum oxide containing at least one first element selected from the group consisting of magnesium (Mg), silicon (Si), hafnium (Hf), tungsten (W), and ruthenium (Ru), the aluminum oxide being κ (kappa)-aluminum oxide,

wherein an a-axis length of the aluminum oxide is 97% or more and 99.5% or less of a standard a-axis length, and a b-axis length of the aluminum oxide is 97% or more and 99.5% or less of a standard b-axis length, the standard a-axis length and the standard b-axis length of the aluminum oxide being an a-axis length and a b-axis length of κ-aluminum oxide described in an International Center for Diffraction Data (ICDD) database.

16. The memory device according to claim 15 , wherein a c-axis direction of the aluminum oxide in the first layer is within a range of ±10° with respect to a direction from the first conductive layer to the second conductive layer.

17. The memory device according to claim 11 , wherein the first conductive layer is a semiconductor layer.

18. A memory device comprising:

a first conductive layer;

a second conductive layer; and

a first layer provided between the first conductive layer and the second conductive layer, the first layer including aluminum oxide, the aluminum oxide containing at least one first element selected from the group consisting of magnesium (Mg), silicon (Si), hafnium (Hf), tungsten (W), and ruthenium (Ru), and the aluminum oxide being κ (kappa)-aluminum oxide,

wherein the aluminum oxide contains at least one second element selected from the group consisting of manganese (Mn), chromium (Cr), and cobalt (Co).

19. The memory device according to claim 12 , wherein the first conductive layer is a semiconductor layer.

20. A memory device comprising:

a first conductive layer;

a second conductive layer; and

a first layer provided between the first conductive layer and the second conductive layer, the first layer including aluminum oxide, the aluminum oxide containing at least one first element selected from the group consisting of magnesium (Mg), silicon (Si), hafnium (Hf), tungsten (W), and ruthenium (Ru), and the aluminum oxide being κ (kappa)-aluminum oxide,

wherein the aluminum oxide contains at least one second element selected from the group consisting of sulfur (S) and chlorine (Cl).

21. The memory device according to claim 20 , wherein the first conductive layer is a semiconductor layer.

Assignments (2)
CHANGE OF NAME AND ADDRESS Recorded Jan 31, 2022
From: TOSHIBA MEMORY CORPORATION
To: KIOXIA CORPORATION
Reel/Frame 058905/0582 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 4, 2019
From: INO, TSUNEHIRO; KAMIMUTA, YUUICHI
To: TOSHIBA MEMORY CORPORATION
Reel/Frame 050267/0691 →
Cited By (2)
US 12,538,495 US 12,550,332