Micromachined electrolyte sheet
The disclosure relates to ceramic lithium ion electrolyte membranes and processes for forming them. The ceramic lithium electrolyte membrane may comprise at least one ablative edge. Exemplary processes for forming the ceramic lithium ion electrolyte membranes comprise fabricating a lithium ion electrolyte sheet and cutting at least one edge of the fabricated electrolyte sheet with an ablative laser.
1. A ceramic lithium-ion electrolyte membrane comprising
at least one ablative edge, wherein the at least one ablative edge is an outer edge;
grains having an average grain size of less than about 5 μm;
a relative density greater than about 90%; and
a thickness of up to about 200 μm; and
wherein the membrane has a 2-point strength greater than about 50MPa.
2. The ceramic lithium-ion electrolyte membrane of claim 1 , wherein the at least one ablative edge is enriched with lithium, relative to a bulk of the membrane.
3. The ceramic lithium-ion electrolyte membrane of claim 1 , wherein the ablative edge has an amorphous surface.
4. The ceramic lithium-ion electrolyte membrane of claim 1 , wherein the thickness is less than about 100 μm.
5. The ceramic lithium-ion electrolyte membrane of claim 4 , wherein the thickness is at least about 40 μm.
6. The ceramic lithium-ion electrolyte membrane of claim 1 , wherein within the electrolyte membrane there is substantially no interconnected porosity such that the electrolyte membrane is hermetic.
7. The ceramic lithium-ion electrolyte membrane of claim 1 , wherein the membrane is unsupported mechanically, not integrated into a multi-layer structure.
8. A ceramic lithium-ion electrolyte membrane comprising
at least one ablative edge, wherein the at least one ablative edge is an outer edge;
grains having an average grain size of less than about 5 μm;
a relative density greater than about 90%; and
a thickness of up to about 200 μm, and
wherein the outer edge has no height variations greater than 1 mm from baseline in a perimeter trace.
9. The ceramic lithium-ion electrolyte membrane of claim 8 , wherein the at least one ablative edge is enriched with lithium, relative to a bulk of the membrane.
10. The ceramic lithium-ion electrolyte membrane of claim 8 , wherein the ablative edge has an amorphous surface.
11. The ceramic lithium-ion electrolyte membrane of claim 8 , wherein the thickness is less than about 100 μm.
12. The ceramic lithium-ion electrolyte membrane of claim 11 , wherein the thickness is at least about 40 μm.
13. The ceramic lithium-ion electrolyte membrane of claim 8 , wherein within the electrolyte membrane there is substantially no interconnected porosity such that the electrolyte membrane is hermetic.
14. The ceramic lithium-ion electrolyte membrane of claim 8 , wherein the membrane is unsupported mechanically, not integrated into a multi-layer structure.
15. A ceramic lithium-ion electrolyte membrane comprising
at least one ablative edge, wherein the at least one ablative edge is an outer edge;
grains having an average grain size of less than about 5 μm;
a relative density greater than about 90%; and
a thickness of up to about 200 μm; and
wherein microstructural features of the ablative edge introduced from cutting are no greater than about ⅓ the thickness of the membrane.
16. The ceramic lithium-ion electrolyte membrane of claim 15 , wherein the at least one ablative edge is enriched with lithium, relative to a bulk of the membrane.
17. The ceramic lithium-ion electrolyte membrane of claim 15 , wherein the ablative edge has an amorphous surface.
18. The ceramic lithium-ion electrolyte membrane of claim 15 , wherein the thickness is less than about 100 μm.
19. The ceramic lithium-ion electrolyte membrane of claim 18 , wherein the thickness is at least about 40 μm.
20. The ceramic lithium-ion electrolyte membrane of claim 15 , wherein within the electrolyte membrane there is substantially no interconnected porosity such that the electrolyte membrane is hermetic.
21. The ceramic lithium-ion electrolyte membrane of claim 15 , wherein the membrane is unsupported mechanically, not integrated into a multi-layer structure.