Method for preparing cathode particles and cathode active materials having same

1. A method for preparing cathode particles under a co-precipitation reaction, comprising the following steps:

providing a first vessel and a second vessel connected in parallel, the first vessel and the second vessel where a reaction takes place is defined as a precipitation zone;

feeding stream (ai) solution into one vessel, feeding stream (bi) solution into the other vessel, and feeding stream (di) into either of the vessels;

re-circulating the solutions between the first vessel and the second vessel to cause a reaction;

after reacting between the solutions, concentration gradient precursor particles being formed in both vessel, collecting the concentration gradient precursor particles from both vessels;

filtering, washing and drying the particles;

after drying, mixing the dried particles with a lithium precursor; and

calcining to yield the cathode particles.

2. The method of claim 1 , wherein the first vessel is larger than the second vessel, or both have same volume.

3. The method of claim 1 , wherein a Reynolds number of the vessels is higher than 6400 with a stirring time of 0-1,200 seconds.

4. The method of claim 1 , wherein during reaction, a temperature of the precipitation zone is between 30-800° C.

5. The method of claim 1 , wherein a pH of the precipitation zone is at a range of 7 to 13.

6. The method of claim 1 , wherein the stream (ai) comprises cations for precipitation, and has a concentration of 0.001-6 mol cation/L.

7. The method of claim 1 , wherein steam (a i ) comprises at least one metal cation, the at least one metal cation of stream (a i ) is at least one selected from the group consisting of Mg, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu and Al.

8. The method of claim 7 , wherein anions corresponding to the metal cations are at least one selected from the group consisting of sulfate, carbonate, chloride, nitrate, fluoride, oxide, hydroxide, oxyhydroxide, oxalate, carboxylate, acetate, phosphate and borate.

9. The method of claim 1 , wherein stream (ai) comprises Ni x Mn y Co z Me 1-x-y-z where x+y+z≥0.9, z≤0.4, and Me represents additional elements.

10. The method of claim 1 , wherein stream (b i ) comprises anions for precipitation, and has a concentration at a range of 0.001-14 mol anion/L.

11. The method of claim 10 , wherein the anion in stream (b i ) is at least one selected from the group consisting of OH − , CO 3 2− , HCO 3 − and C 2 O 4 2− .

12. The method of claim 1 , wherein stream (d i ) comprises a chelating agent to the precipitation zone, and has a concentration in a range of 0.001-14 mol chelating agent/L.

13. The method of claim 12 , wherein the chelating agent is at least one selected from the group consisting of ammonia hydroxide, ammonium chloride, ammonium sulfate, ammonium dihydrogen phosphate, ethylene glycol, carboxylic acids, ammonium nitrate, glycerol, 1,3 propane-diol, urea, N,N′-dimethylurea and quaternary ammonia salts.

14. The method of claim 1 , wherein the drying is under vacuum at N 2 , Ar or air atmosphere for 3-24 hours at a temperature between 80° C. and 2000° C.

15. The method of claim 1 , wherein the lithium precursor is at least one selected from the group consisting of LiOH.H 2 O, Li 2 CO 3 , LiNO 3 , lithium acetate, lithium metal and Li 2 O.

16. The method of claim 1 , wherein when mixing with the lithium precursor, a ratio of lithium to metal cation is between 0.5-1.5.

17. The method of claim 1 , wherein the precipitated particles are calcined at a temperature between 300-9500° C. for 2 to 48 hours.

18. The method of claim 1 , wherein a ramp rate during calcining is 0.5 to 10 degrees per minute.