IP Library Granted Patent US 11,148,114
Granted Patent B2
US 11,148,114 · App. 16/380,648 · Granted Oct 19, 2021

Composite 3D-printed reactors for gas absorption, purification, and reaction

Inventors: Du T. Nguyen (Fremont, CA); Roger D. Aines (Livermore, CA); Sarah E. Baker (Dublin, CA); William L. Bourcier (Livermore, CA); Eric B. Duoss (Dublin, CA); James S. Oakdale (Castro Valley, CA); Megan M. Smith (Livermore, CA); William L. Smith (Oakland, CA); Joshuah K. Stolaroff (Oakland, CA); Congwang Ye (San Ramon, CA)
Assignee: Lawrence Livermore National Security, LLC
B01J13/206B01D53/0407B01D53/1475B01D53/1493B01J13/14B01J20/2805B33Y80/00B01D2252/202B01D2252/20405B01D2252/20421B01D2252/20484B01D2257/504Y02C20/40
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Quick Facts
Patent No.
US 11,148,114
App. No.
16/380,648
Granted
Oct 19, 2021
Kind
B2
Abstract

A composite material for gas capture, notably CO 2 capture and storage. The composite material includes a mixture of a solid or liquid reactive filler and a gas-permeable polymer such that the reactive filler forms micron-scale domains in the polymer matrix.

Claims (16)

1. A reactor for removing carbon dioxide from a gas containing the carbon dioxide, comprising:

units of sorbent material;

a gas-permeable polymer;

a 3-D ink produced by mixing said units of sorbent material and said gas-permeable polymer;

a surface;

a 3-D print head that extrudes said 3-D ink onto said surface; and

a controller that controls said 3-D print head to extrude said 3-D ink onto said surface to form the reactor.

2. The reactor for removing carbon dioxide from a gas containing the carbon dioxide of claim 1 wherein said units of sorbent material are particles of carbon dioxide stripping material.

3. The reactor for removing carbon dioxide from a gas containing the carbon dioxide of claim 1 wherein said units of sorbent material are solid particle precursors to liquid units of carbon dioxide stripping material.

4. The reactor for removing carbon dioxide from a gas containing the carbon dioxide of claim 1 wherein said units of sorbent material are particles of carbon dioxide stripping material encapsulated in capsules.

5. The reactor for removing carbon dioxide from a gas containing the carbon dioxide of claim 1 wherein said units of sorbent material are particles of carbon dioxide stripping material encapsulated in spherical capsules that have a gas-permeable polymer surface layer encapsulating said particles of carbon dioxide stripping material.

6. The reactor for removing carbon dioxide from a gas containing the carbon dioxide of claim 1 wherein said units of sorbent material are liquid units of carbon dioxide stripping material.

7. The reactor for removing carbon dioxide from a gas containing the carbon dioxide of claim 1 wherein said units of sorbent material are liquid droplets of carbon dioxide stripping material encapsulated in capsules.

8. The reactor for removing carbon dioxide from a gas containing the carbon dioxide of claim 1 wherein said units of sorbent material are liquid droplets of carbon dioxide stripping material encapsulated in spherical capsules that have a gas-permeable polymer surface layer encapsulating said liquid droplets of carbon dioxide stripping material.

9. The reactor for removing carbon dioxide from a gas containing the carbon dioxide of claim 1 wherein said gas-permeable polymer comprises uncured silicone.

10. The reactor for removing carbon dioxide from a gas containing the carbon dioxide of claim 1 further comprising a device for curing said reactor after the said 3-D print head extrudes said 3-D ink onto said surface to form the reactor.

Assignments (2)
CONFIRMATORY LICENSE Recorded Jun 18, 2019
From: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 049499/0754 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 10, 2019
From: NGUYEN, DU T.; AINES, ROGER D.; BAKER, SARAH E.; BOURCIER, WILLIAM L.; DUOSS, ERIC B.; OAKDALE, JAMES S.; SMITH, MEGAN M.; SMITH, WILLIAM L.; STOLAROFF, JOSHUAH K.; YE, CONGWANG
To: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
Reel/Frame 048850/0618 →
Continuity (2)
Division 15468297 · Mar 24, 2017
Related Publication 20190232247A1 · Aug 1, 2019